发生炉炉况综合量化制度的建立与应用

从全面质量管理工序控制的角度出发 ,借鉴焦炉加热管理的方法 ,首次对混合煤气发生炉生产中的主要工序——炉况控制制定了综合量化考评标准 ,并在我厂 17台 CG- 3型混合煤气发生炉的生产工艺管理中进行了实践应用 ,取得了显著效果     

热压2％（mol）Y_2O_3－ZrO_2陶瓷中t－m相等温转变

用热膨胀分析、Ｘ射线衍射研究了热压２％（ｍｏｌ）Ｙ＿２Ｏ＿３－ＺｒＯ＿２陶瓷中ｔ－ｍ等温转变动力学。结果表明：经过快速冷却而得到的四方相（ｔ）在随后２００～４００℃区间保温时发生了四方相（ｔ）到单斜相（ｍ）的转变。该转变的时间－温度－转变量（ＴＴＴ）曲线呈Ｃ形，鼻子温度为３００℃。高于或低于上述温度范围，未出现ｍ相，可用Ａｖｒａｍｉ方程的一般形式来描述动力学曲线。该相变的形核与长大均是时间的函数，相变激活能为２８．６７ｋＪ／ｍｏｌ。ｔ相的亚稳性不仅与稳定剂分布及晶粒尺寸有关，而且还受冷却速度所控制。     

高顺式丁二烯-异戊二烯共聚橡胶研究进展

综合评述了国内外高顺式丁二烯-异戊二烯共聚橡胶的研究进展，包括合成方法、结构与性能及其应用；并对其发展趋势进行了评述。     

Synthesis and characterization of poly(vinyl chloride‐co‐vinyl acetate)‐graft‐poly[(meth)acrylates] by atom transfer radical polymerization

The graft polymerization of methyl methacrylate and butyl acrylate onto poly(vinyl chloride‐co‐vinyl acetate) with atom transfer radical polymerization (ATRP) was successfully carried out with copper(I) thiocyanate/N,N,N′,N′,N″‐pentamethyldiethylenetriamine and copper(I) chloride/2,2′‐bipyridine as catalysts in the solvent N,N‐dimethylformamide. For methyl methacrylate, a kinetic plot of ln([M]₀/[M]) (where [M]₀ is the initial monomer concentration and [M] is the monomer concentration) versus time for the graft polymerization was almost linear, and the molecular weight of the graft copolymer increased with increasing conversion, this being typical for ATRP. The formation of the graft polymer was confirmed with gel permeation chromatography, ¹H‐NMR, and Fourier transform infrared spectroscopy. The glass‐transition temperature of the copolymer increased with the concentration of methyl methacrylate. The graft copolymer was hydrolyzed, and its swelling capacity was measured. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 183–189, 2005     

TuLP: A Family of Lightweight Message Authentication Codes for Body Sensor Networks简

A wireless sensor network （WSN） commonly whilst a body sensor network （BSN） must be secured with requires lower level security for public information gathering, strong authenticity to protect personal health information. In this paper, some practical problems with the message authentication codes （MACs）, which were proposed in the popular security architectures for WSNs, are reconsidered. The analysis shows that the recommended MACs for WSNs, e.g., CBC- MAC （TinySec）, OCB-MAC （MiniSec）, and XCBC-MAC （SenSee）, might not be exactly suitable for BSNs. Particularly an existential forgery attack is elaborated on XCBC-MAC. Considering the hardware limitations of BSNs, we propose a new family of tunable lightweight MAC based on the PRESENT block cipher. The first scheme, which is named TukP, is a new lightweight MAC with 64-bit output range. The second scheme, which is named TuLP-128, is a 128-bit variant which provides a higher resistance against internal collisions. Compared with the existing schemes, our lightweight MACs are both time and resource efficient on hardware-constrained devices.     

基于PSK声通信的无线传感器网络节点设计

可用于无线传感器网络的声信号通信方式,不占用无线电通信频率带宽,无射频干扰,在诸如环境监测、军事侦测等领域有广泛的应用前景。研究了一种基于相移键控(PSK)调制声通信的无线传感器网络节点系统。节点系统采用ARM+FPGA的结构,核心控制器为具有低功耗休眠模式的STM32型ARM芯片,FPGA用于进行数据缓存和部分数据处理,采用PZT型扬声器实现声信号的收发。测试表明:节点系统可以在10m范围内进行数据通信,数据码率300bps,误码率小于10-3,系统最大功耗小于0.1 W,最低休眠功耗小于10μW。     

（NH2）2CO-NH4H2PO4-H2O三元系10 ℃相平衡研究

采用等温溶解平衡法研究了三元系（NH₂）₂CO-NH₄H₂PO₄-H₂O在10 ℃时的相平衡,并采用湿渣法与X射线衍射相结合的方法鉴定了平衡固相的组成与结构。结果表明,该体系为简单共饱和型,无复盐或固溶体生成,共饱点的质量组成（以质量分数计）：尿素,40.03%;磷酸一铵,13.92%;水,46.05%。相图中有2条单变量曲线,相图被划分为4个区域：不饱和区、（NH₂）₂CO结晶区、NH₄H₂PO₄结晶区和（NH₂）₂CO-NH₄H₂PO₄混合结晶区。用Wilson方程与NRTL方程对实验数据关联计算,实验值与计算值吻合度较高,2个热力学模型计算值与实验值的RAD分别为0.37%和0.71%,RMSD分别为0.20和0.29。     

Exploring the Interactions of Storylines from Informative News Events

Today＇s news readers can be easily overwhelmed by the numerous news articles online. To cope with information overload, online news media publishes timelines for continuously developing news topics. However, the timeline summary does not show the relationship of storylines, and is not intuitive for readers to comprehend the development of a complex news topic. In this paper, we study a novel problem of exploring the interactions of storylines in a news topic. An interaction of two storylines is signified by informative news events that play a key role in both storylines. Storyline interactions can indicate key phases of a news topic, and reveal the latent connections among various aspects of the story. We address the coherence between news articles which is not considered in traditional similarity-based methods, and discover salient storyline interactions to form a clear, global picture of the news topic. User preference can be naturally integrated into our method to generate query-specific results. Comprehensive experiments on ten news topics show the effectiveness of our method over alternative approaches.     

高温下煤焦气化反应特性(Ⅰ)灰分熔融对煤焦气化反应的影响

在900～1500℃灰分的熔融温度范围内和常压下,研究了煤焦与二氧化碳的气化反应。实验研究发现,活化能随气化过程而变化,除反应初期外,气化反应严重受内扩散过程的影响。高温下的煤焦气化存在一个特性温度,在该温度下,反应中、后期气化速率显著降低,其影响范围在特性温度上下约200～300℃。特性温度与煤种及灰分性质等因素有关,一般低于其相应灰分的软化点温度。     

突发GMSK混和信号混合位置估计迭代算法

针对GMSK混合信号的混合位置估计问题,提出了一种基于参数估计与混合位置估计的迭代算法。混合信号混合部位和未混合部位在幅度和频率上存在明显差异,通过混合部位信号过零点和极值点得到混合的信号和幅度估计后,可以对采样点是否混合进行判断,同时混合起点对应着相对时延,当混合信号的相对时延较大时,利用未混合部位信号来进行迭代时,其估计精度更高。对混合起点估计的克拉美罗界进行了推导,仿真表明,本文算法估计精度高,所需的数据量小,适用于突发通信,且对参数变化不敏感,具有较强的鲁棒性,在高信噪比下混合位置估计精度接近克拉美罗界。