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11.
A theoretical model proposed for simulation of the injection molding of partially crystalline thermoplastics can predict fill time, velocity, temperature and pressure distributions, the distribution of shear and normal stresses, crystallinity, amorphous birefringence, and tensile moduli. In this paper, experimental data will be compared to the predictions of the model. 相似文献
12.
Super-resolution: a comprehensive survey 总被引:3,自引:0,他引:3
Super-resolution, the process of obtaining one or more high-resolution images from one or more low-resolution observations, has been a very attractive research topic over the last two decades. It has found practical applications in many real-world problems in different fields, from satellite and aerial imaging to medical image processing, to facial image analysis, text image analysis, sign and number plates reading, and biometrics recognition, to name a few. This has resulted in many research papers, each developing a new super-resolution algorithm for a specific purpose. The current comprehensive survey provides an overview of most of these published works by grouping them in a broad taxonomy. For each of the groups in the taxonomy, the basic concepts of the algorithms are first explained and then the paths through which each of these groups have evolved are given in detail, by mentioning the contributions of different authors to the basic concepts of each group. Furthermore, common issues in super-resolution algorithms, such as imaging models and registration algorithms, optimization of the cost functions employed, dealing with color information, improvement factors, assessment of super-resolution algorithms, and the most commonly employed databases are discussed. 相似文献
13.
A novel mechanism to form binary polymer blends is through phase separation by spinodal decomposition in the unstable region of the phase diagram. The present work investigates the effects of thermally‐induced phase separation by spinodal decomposition on the morphology development of liquid crystalline polymer/polycarbonate blends. Moreover, a thermodynamic binary phase diagram is obtained using a twin‐screw extruder at various processing melt temperatures. Differential scanning calorimetry and scanning electron microscopy were used to study the miscibility of the blends and the resulting morphology. A thermodynamic binary phase diagram exhibiting a lower critical solution temperature was obtained. The droplet size distribution of the blend was also obtained and discussed in light of the Cahn‐Hilliard theory. 相似文献
14.
Mohamed M. Abd-Alla Maher F. El-Zohry Kamal I. Aly Mohamed M. M. Abd-El-Wahab 《应用聚合物科学杂志》1993,47(2):323-329
A new interesting category of organometallic polyesters based on diarylidenecycloalkanones containing ferrocene derivatives in the polymer main chain has been prepared by interfacial polycondensation of 1,1′-dichlorocarbonyl ferrocene or 1,1′-dichlorocarbonyl-4,4′-diiodoferrocene with 2,5-bis(p-hydroxybenzylidene)cyclopentanone, 2,5-divanillylidenecyclopentanone, 2,6-bis(p-hydroxybenzylidene)cyclohexanone, 2,6-divanillylidenecyclohexanone, and 2,7-bis(p-hydroxybenzylidene) cycloheptanone. The resulting polyesters were characterized by elemental analyses, infrared spectroscopy, solubility, and viscometry measurements. The thermal behavior of the synthesized polymers was evaluated by thermal gravimetric analysis and correlated with their structures. The crystallinity of all polymers were examined by x-ray diffraction analysis. Moreover, the electrical conductivity of a selected example of polymer was investigated above the temperature range (300–500 K) and showed that it followed an Arrhenius-type equation with activation energy 2.09 eV. © 1993 John Wiley & Sons, Inc. 相似文献
15.
Some commonly used empirical equations of state for polymers are considered: the Spencer-Gilmore equation with two and three adjustable parameters, the Whitaker-Griskey equation, and the Rehage-Breuer equation. Also, a new equation is proposed: the Inverse Volume equation. These equations are evaluated with regard to fitting experimental P-V-T data and agreement with experimental data on isothermal compressibility and thermal expansion coefficient. The adjustable parameters for each equation are determined with the help of Rosenbrock's optimum-seeking technique. Analysis of the residuals on specific volume for a variety of materials suggests that the Spencer-Gilmore equation with three adjustable parameters, the Rehage-Breuer and the Inverse Volume equations yield the smallest and most random residuals and thus the least systematic error. The same three equations mentioned above yield results in good agreement with experimental isothermal compressibility data. However, among all the equations considered in this study, the Inverse Volume equation yields the best agreement with experimental thermal expansion coefficient data. Furthermore, it is the only equation to correctly predict the rise in thermal expansion coefficient with increasing temperature. 相似文献
16.
An experimental program has been carried out on a reciprocating screw injection molding machine in order to establish the validity of a proposed mathematical model for the filling stage of injection molding. A cavity of complex shape with an insert and variable thickness was constructed and used in these experiments. Good agreement between predicted (through computer simulation) and observed (through short-shot experiments and transducer response) results is obtained for free surface shapes and free surface locations with time. The theoretical pressure predictions are in fairly good agreement with experiments, with the maximum deviations occurring towards the end of filling and for longer filling times. This points towards the possibility that wall solidification during filling interacts with the flow processes across the gap of the cavity and makes necessary a more detailed characterization of the heat transfer at the melt/mold interface. 相似文献
17.
Recently, IS researchers have focused on the assessment of Web-based information system (WBIS) at the individual level as it highly contributes to the organizations’ employees. The evaluation and development of WBIS is significantly needed because the top management is in need of justifying their costly IT investment in terms of its impacts on employee performance. For this purpose, this study is primarily concerned with the development and validation of new multidimensional instrument, and also a theoretical framework for assessing the impacts of user interface quality, online communication quality, and user satisfaction on the effectiveness of Web employee portals. The effectiveness is assessed in terms of contextual performance. In a large-scale study, a sample of 384 United Nations Relief and Works Agency for Palestine Refugees respondents are gathered in order to validate and check the reliability of the adapted study instrument. The results of validity and reliability analysis provide enough confidence to proceed toward validating the proposed theoretical framework. The results of multiple-regression analysis indicate that there is a positive significant relationship between user interface quality, communication quality, user satisfaction, and effectiveness at significance level (sig. < 0.01). As another important point, the results of hierarchical regression showed that user satisfaction has a mediating role on the relationship between user interface quality, communication quality, and contextual employee performance. The findings and implications of this research are discussed. Finally, it is expected that this study would contribute to empirical studies in the fields of IS and user behavior assessment. 相似文献
18.
M. R. Kamal N. R. Demarquette R. A. Lai-Fook T. A. Price 《Polymer Engineering and Science》1997,37(5):813-825
The commonly used thermodynamic theories (mean field theory and the square gradient theory) to predict interfacial tension between polymers have been modified. The results of these theoretical developments have not yet been fully tested and compared to experimental data. In this paper, experimental data for the effects of temperature, molecular weight, and molecular weight dispersity on interfacial tension for polypropylene/polystyrene polymer pairs are compared with the predictions of the new versions of the above theories. To evaluate these theories, it is necessary to know the Flory-Huggins interaction parameter for the polymer pairs studied. The relation correlating the Flory-Huggins interaction parameter to the Hildebrand solubility parameter was not suitable for evaluating the theoretical predictions of interfacial tension. Instead, the Flory Huggins interaction parameter was expressed as the sum of an enthalpic contribution, χH, and entropic contribution, χs. In the absence of reliable experimental values, a method was developed to evaluate the two contributions, based on interfacial tension data. The procedure provided an interaction parameter that is allowed to depend on molecular weight. When this approach was used, the predictions of only the new version of the square gradient theory were in good agreement with the experimental data for the influence of temperature and molecular weight on interfacial tension. However, the theory predicted the effect of polydispersity on interfacial tension only at high temperatures. 相似文献
19.
A mathematical model of the dynamics and heat transfer of the film embossing process has been developed. The thermal analysis around the preheat roll is determined from an unsteady, two-dimensional heat conduction equation along with appropriate boundary conditions by neglecting the curvature of the preheat roll and choosing a Lagrangian reference frame. The heat transfer occurring between the preheat roll and the embossing rolls is based on a one-dimensional analysis, including both convective and radiative effects. The deformation occurring in the nip region is analyzed for two different situations. For the case where the surface features are small in comparison with the film thickness, a modified one-dimennsional calendering analysis is given, accounting for the irregular geometry of the embossing roll surface. For the case where the polymer does not make complete contact with the surface of the engraved channel, the local deformation is determined by means of a simple one-dimensional cavity filling model. The required pressure distribution is determined by means of a simple one-dimensional cavity filling model, The required pressure distribution is determined by means of a conventional calendering analysis. The analysis for the case of a Newtonian and power-law model is presented in detail. The model yields qualitatively correct results and is computationally simple. 相似文献
20.
Melting curves, obtained by differential scanning calorimetry, are used to estimate crystal size distributions. The proposed theoretical analysis is applied to different types of polyethylene, including high‐density polyethylene (HDPE), metallocene catalyzed linear low‐density polyethylenes (m‐LLDPE), blends of m‐LLDPEs, and Ziegler‐Natta catalyzed LLDPEs (ZN‐LLDPE). Theoretical predictions are in agreement with experimental results. A generalized melting temperature equation successfully predicts the melting temperatures of all the LLDPEs, although it was initially proposed for homogeneous copolymers with excluded comonomers. A new definition of the heat of fusion for pure crystals is proposed. This heat of fusion can be calculated from the average crystal size or the crystal size number distribution. 相似文献