Dual pH‐Induced Reversible Self‐Assembly of Gold Nanoparticles by Surface Functionalization with Zwitterionic Ligands

The dual pH‐induced reversible self‐assembly (PIRSA) of Au‐nanoparticles (Au NPs) is reported, based on their decoration with the self‐complementary guanidiniocarbonyl pyrrole carboxylate zwitterion (GCPZ). The assembly of such functionalized Au NPs is found at neutral pH, based on supramolecular pairing of the GCPZ groups. The resulting self‐assembled system can be switched back to the disassembled state by addition of base or acid. Two predominant effects that contribute to the dual‐PIRSA of Au NPs are identified, namely the ionic hydrogen bonding between the GCPZ groups, but also a strong hydrophobic effect. The contribution of each interaction is depending on the concentration of GCPZ on NPs, which allows to control the self‐assembly state over a wide range of different water/solvent ratios.     

Einfluss der elastischen Nachgiebigkeit auf die Kraft beim tauchenden Kegelradschleifen

Forschung im Ingenieurwesen - Aufgrund steigender Anforderungen an den Wirkungsgrad und die Geräuschanregung von Zahnradgetrieben ist die Hartbearbeitung von Zahnrädern für viele...     

Flow Pattern and Heat Transfer in a Cylindrical Annulus Under 1 g and Low-g Conditions: Experiments

We investigate the thermal convection in an annular cavity, with differentially heated inner and outer cylinders, under the influence of a dielectrophoretic (DEP) force. Applying a temperature gradient to a liquid creates buoyancy driven thermal convection. When additionally a radially acting DEP-force is applied by means of an alternating electric field, the pattern of this convective flow changes which also leads to a change in the heat transfer. Depending on the parameters, e.g. an axisymmetric structure with toroidal vortices appears. Another possible structure are columnar vortices, which extend through the annulus. To isolate the effect of the DEP-force, this experiment is not only conducted in the laboratory, but also in microgravity conditions during parabolic flights. By using DEP-induced convective flows in microgravity a comparable heat transfer as with buoyancy convection under Earth’s condition can be obtained. A better understanding of the heat transport mechanisms inside a dielectric liquid confined between two concentric cylinders can deliver solutions for the improvement of the heat transport in many technical applications.     

Fluorescent Diarylethene Photoswitches—A Universal Tool for Super‐Resolution Microscopy in Nanostructured Materials

Super‐resolution fluorescence microscopy allows for unprecedented in situ visualization of biological structures, but its application to materials science has so far been comparatively limited. One of the main reasons is the lack of powerful dyes that allow for labeling and photoswitching in materials science systems. In this study it is shown that appropriate substitution of diarylethenes bearing a fluorescent closed and dark open form paves the way for imaging nanostructured materials with three of the most popular super‐resolution fluorescence microscopy methods that are based on different concepts to achieve imaging beyond the diffraction limit of light. The key to obtain optimal resolution lies in a proper control over the photochemistry of the photoswitches and its adaption to the system to be imaged. It is hoped that the present work will provide researchers with a guide to choose the best photoswitch derivative for super‐resolution microscopy in materials science, just like the correct choice of a Swiss Army Knife's tool is essential to fulfill a given task.     

Smart‐Dust‐Nanorice for Enhancement of Endogenous Raman Signal,Contrast in Photoacoustic Imaging,and T2‐Shortening in Magnetic Resonance Imaging

Raman microspectroscopy provides chemo‐selective image contrast, sub‐micrometer resolution, and multiplexing capabilities. However, it suffers from weak signals resulting in image‐acquisition times of up to several hours. Surface‐enhanced Raman scattering (SERS) can dramatically enhance signals of molecules in close vicinity of metallic surfaces and overcome this limitation. Multimodal, SERS‐active nanoparticles are usually labeled with Raman marker molecules, limiting SERS to the coating material. In order to realize multimodal imaging while acquiring the rich endogenous vibronic information of the specimen, a core–shell particle based on “Nanorice”, where a spindle‐shaped iron oxide core is encapsulated by a closed gold shell, is developed. An ultrathin layer of silica prevents agglomeration and unwanted chemical interaction with the specimen. This approach provides Raman signal enhancement due to plasmon resonance effects of the shell while the optical absorption in the near‐infrared spectral region provides contrast in photoacoustic tomography. Finally, T2‐relaxation of a magnetic resonance imaging (MRI) experiment is altered by taking advantage of the iron oxide core. The feasibility for Raman imaging is evaluated by nearfield simulations and experimental studies on the primate cell line COS1. MRI and photoacoustics are demonstrated in agarose phantoms illustrating the promising translational nature of this strategy for clinical applications in radiology.     

Redundant configuration of robotic assembly lines with stochastic failures

One of the main challenges in the operation of robotic assembly lines is the occurrence of failures. Due to the connection of the stations via a material handling system, failures at one station often result in throughput losses. To some extent, these throughput losses can be reduced by installing buffers between the stations. However, the installation of buffers requires considerable investments and scarce factory space. Due to the advances of manufacturing technologies that form the foundation of ‘Industry 4.0’, new solutions to reduce failure-related throughput losses open up. One solution is a redundant configuration, in which downstream (backup) stations automatically take over the operations of failed stations during repair time. The throughput loss in these situations depends on the allocation of operations and the assignment of backup stations. Existing approaches in the literature that consider redundancies in the configuration of automated lines neglect the resulting production rate. Instead, the lines’ level of redundancy is used as a surrogate measure for optimisation. We present a genetic algorithm for the redundant configuration of robotic assembly lines with stochastic failures to maximise the production rate of the line. In a numerical analysis, it is demonstrated that this approach allows for productivity improvements.     

Nanodroplet‐Containing Polymers for Efficient Low‐Power Light Upconversion

Sensitized triplet–triplet‐annihilation‐based photon upconversion (TTA‐UC) permits the conversion of light into radiation of higher energy and involves a sequence of photophysical processes between two dyes. In contrast to other upconversion schemes, TTA‐UC allows the frequency shifting of low‐intensity light, which makes it particularly suitable for solar‐energy harvesting technologies. High upconversion yields can be observed for low viscosity solutions of dyes; but, in solid materials, which are better suited for integration in devices, the process is usually less efficient. Here, it is shown that this problem can be solved by using transparent nanodroplet‐containing polymers that consist of a continuous polymer matrix and a dispersed liquid phase containing the upconverting dyes. These materials can be accessed by a simple one‐step procedure that involves the free‐radical polymerization of a microemulsion of hydrophilic monomers, a lipophilic solvent, the upconverting dyes, and a surfactant. Several glassy and rubbery materials are explored and a range of dyes that enable TTA‐UC in different spectral regions are utilized. The materials display upconversion efficiencies of up to ≈15%, approaching the performance of optimized oxygen‐free reference solutions. The data suggest that the matrix not only serves as mechanically coherent carrier for the upconverting liquid phase, but also provides good protection from atmospheric oxygen.