Rapid sensing of trace ionic substances with the novel porous monolith type ion exchanger

Biological and chemical sensor with a rapid response in microlevel test is required for health and environmental monitor. A novel sensing due to porous ion exchanger with three-dimensional acceptor has been first attempted to develop a high-performance sensor. This porous monolith type ion exchanger has an open-cellular monolith structure with 5–50-μm diameter pores. The trace amount of inorganic ions dissolved in aqueous solutions can be quantitatively determined with the impedance given by the monolith, which attracts and adsorbs the ions rapidly. We have succeeded in detecting ions with a concentration as low as 10⁻⁷ mol. The porous ion exchanger has a potentiality as a high-performance device for biological and chemical sensing. POLYM. ENG. SCI., 47:1666–1670, 2007. © 2007 Society of Plastics Engineers     

Optical Amplification at 1.3 μm in a Praseodymium-Doped Sulfide-Glass Fiber

Praseodymium-doped glasses were prepared in the Ga-Na-S (GNS) system and their optical properties were studied. A single-mode fiber with an attenuation loss of 1.2 dB/m at a wavelength of 1.31 μm was fabricated using an extrusion method, and the amplification characteristics were measured in the bidirectional pumping configuration. We demonstrated a gain coefficient of 0.81 dB/mW at a wavelength of 1.34 μm, which is the highest we have ever reported, and achieved a net gain of 32 dB for a pump power of 90 mW. Highly efficient optical amplification at a wavelength of 1.3 μm was demonstrated in the praseodymium-doped GNS fiber.     

Newly structured expandable 52-Mbit/s, 48-channel time-division switching LSI with 2.4 Gbit/s throughput

An expandable Si bipolar 2.4 Gbit/s throughput, 52 Mbit/s 48-channel time-division switching LSI system is described. A high-throughput of 2.4 Gbit/s and a power-dissipation of 5.3 W are achieved by adopting a low-voltage swing four-serial-gated differential bipolar circuit design and super self-aligned process (SST-1A) logic-in-memory LSI technology. This LSI is applicable to the digital video time-division switching and digital crossconnect systems of future B-ISDN.<>     

Oxidative coupling of methane applying a solid oxide fuel cell system

A fuel cell system using yttria-stabilized zirconia as a solid electrolyte was applied to the oxidative coupling of methane. The most active and selective catalyst was BaCO₃ deposited on Au-electrode (anode). Optimum conditions for the reaction were examined. The pressure of methane at the anode and that of oxygen at the cathode should be high as much as possible. The optimum temperature was 1073 K. Several advantages of the method are described.     

Biomechanical Evaluation of Ti-Nb-Sn Alloy Implants with a Low Young’s Modulus

Dental implants are widely used and are a predictable treatment in various edentulous cases. Occlusal overload may be causally related to implant bone loss and a loss of integration. Stress concentrations may be diminished using a mechanobiologically integrated implant with bone tissue. The purpose of this study was to investigate the biomechanical behavior, biocompatibility and bioactivity of a Ti-Nb-Sn alloy as a dental implant material. It was compared with cpTi. Cell proliferation and alkaline phosphatase (ALP) activity were quantified. To assess the degree of osseointegration, a push-in test was carried out. Cell proliferation and ALP activity in the cells grown on prepared surfaces were similar for the Ti-Nb-Sn alloy and for cpTi in all the experiments. A comparison between the Ti-Nb-Sn alloy implant and the cpTi implant revealed that no significant difference was apparent for the push-in test values. These results suggest that implants fabricated using Ti-Nb-Sn have a similar biological potential as cpTi and are capable of excellent osseointegration.     

Disorders and oxygen vacancies in p-type Sn2B2O7 (B = Nb,Ta): Role of the B-site element

Sn₂Nb_2−xTa_xO₇ (x = 0.0–2.0) with pyrochlore structure is a promising material for p-type oxide semiconductors. A systematic study of its Nb/Ta ratio indicated that the hole–generation efficiency of the Nb end (Sn₂Nb₂O₇) was an order of magnitude lower than that of the Ta end (Sn₂Ta₂O₇). Although this occurs due to differences in oxygen-vacancy formation, the origins of the hole–generation efficiencies remain unclear due to limited information on local and global crystal-structure disorders in pyrochlore Sn₂Nb₂O₇ and Sn₂Ta₂O₇. In this study, the crystal structures of Sn₂B₂O₇ (B = Nb, Ta), composed of BO₆ octahedra and Sn₄O tetrahedra, were investigated using X-ray absorption spectroscopy and X-ray diffraction. A detailed investigation of the local and global crystal structures indicated a larger amount of disorder in the Sn₄O tetrahedra in Sn₂Nb₂O₇ compared to Sn₂Ta₂O₇; disorder in the BO₆ octahedra occurred only in Sn₂Ta₂O₇. This study indicates that an appropriate selection of the B-site element is vital for suppressing defect and disorder formation in Sn₄O tetrahedra and subsequently improving the hole–carrier–generation efficiency.     

Identification of yeast strains isolated from marcha in Sikkim, a microbial starter for amylolytic fermentation

Marcha or murcha is a traditional amylolytic starter used to produce sweet-sour alcoholic drinks, commonly called jaanr in the Himalayan regions of India, Nepal, Bhutan, and Tibet (China). The aim of this study was to examine the microflora of marcha collected from Sikkim in India, focusing on yeast flora and their roles. Twenty yeast strains were isolated from six samples of marcha and identified by genetic and phenotypic methods. They were first classified into four groups (Group I, II, III, and IV) based on physiological features using an API test. Phylogenetic, morphological, and physiological characterization identified the isolates as Saccharomyces bayanus (Group I); Candida glabrata (Group II); Pichia anomala (Group III); and Saccharomycopsis fibuligera, Saccharomycopsis capsularis, and Pichia burtonii (Group IV). Among them, the Group I, II, and III strains produced ethanol. The isolates of Group IV had high amylolytic activity. Because all marcha samples tested contained both starch degraders and ethanol producers, it was hypothesized that all four groups of yeast (Group I, II, III, and IV) contribute to starch-based alcohol fermentation.     

Study on cracking in electron beam welding of A6061 (Al‐Si‐Mg alloy)

Electron beam surfacing in an electron accelerator using powder mixtures of chromium carbides with boron carbide in different weight ratios and with different radiation parameters was used to produce wear- and corrosion-resisting coatings. It is shown that there are compositions of the surfacing mixtures and conditions of electron beam effect ensuring maximum values of wear and corrosion resistance.     

Observation of metal on Si(0 0 1) by STM/STS and its consideration based on the first principles calculations

Local density of states (LDOS) is obtained by the first principles calculation based on the density functional theory on the Si(0 0 1)2 × 1 surface and on the surface with an Al dimer. At an Al dimer, LDOS has a high intensity in the conduction band region, which cannot be seen on the Si(0 0 1)2 × 1 surface. This tendency is observed in STS measurements as well. The possibility for a microelementary analysis is presented by applying this method to other metal atoms on the Si surface. Furthermore, it is pointed out that STS measurements should be always performed at the same tip-sample separation to obtain reproducible STS spectrums.