Oriented Lead Titanate Film Growth at Lower Temperatures by the Sol-Gel Method on Particle-Seeded Substrates

An approach to fabricate lead titanate (PbTiO₃) films with preferred orientation on arbitrary substrates by a sol-gel method was developed. To ensure a preferred crystallographic orientation on the substrates with different crystal structure, well-defined platelet PbTiO₃ particles were used as seeds. Because the basal plane of the platelet-shaped particles was the (001) plane, the particles aligned with the c-axis perpendicular to the substrates. During crystallization of the sol-gel PbTiO₃ films on the particle-seeded substrate, preferential nucleation occurred on seeded particles with the same crystallographic orientation as the particles at a much lower temperature. In the current study, (100) and (001) textured PbTiO₃ films have been produced on various substrate materials such as silicon, silicate glass, indium tin oxide (ITO) glass, and titanium metal at temperatures as low as 275°C. The microstructure of the films was examined by scanning electron microscopy and atomic force microscopy. Limited ferroelectric properties also were determined, to underscore the preferred orientation that was produced in these materials.     

Making decisions about hazardous waste remediation when even considering a remediation technology is controversial

This paper investigates the circumstances under which proposed hazardous waste remediation technologies are socially acceptable, that is, considered seriously as options in a public arena. First, it summarizes a conceptual framework that guides investigation and interpretation of site-specific remediation decision-making. Second, it describes an initial application of that framework to the public participation venue of U.S. DOE Site-Specific Advisory Boards. Investigating the attributes of involved parties and of site context highlights technology acceptability as social decision-making that involves technical and technological issues rather than as a process driven by the technology itself.