Studies on Hg(II) ion retention properties of cross-linked graft copolymer of acrylic acid and its analytical application

The effects of different parameters such as time, concentration, pH and temperature, on metal ion retention properties of the polymer have been investigated. Metal ion adsorption kinetics, isotherms and thermodynamics have been studied. A plausible mechanism for mercury ion retention has been suggested. Mercuric ion has been isolated quantitatively from various synthetic mixture containing metal ions (Ni²⁺, Cd²⁺, Pb²⁺ and Zn²⁺).     

Analysis of the effects of weak floor strata on longwall face stability using finite element modeling

Higher production, better safety standard, and potential for automation are some of the benefits of Iongwall mining. Today, Iongwall face advances at a faster rate exposing many diversifted rock layers in a short period of time. It is now a serious challenge to cope with ground control problems such as roof falls, face and floor failure, and excessive shield loading as fast as possible to minimize production and monetary losses. In Illinois Coal Mines, the existence of weak floor strata blow the coal seam may pose additional problems related to floor heaving, shield base punching, and associated roof and face falls. In this study, the effects of weak floor on Iongwall ground control are analyzed using two-dimensional finite element models. A two-leg 635.6 ton (700-short-ton) yielding capacity shield is included in the models to evaluate the effects of different thickness and material properties of the weak floor. The study indicates that the thickness and material properties of weak floor have significant effects on shield loading, the distribution and intensity of front abutment stress, failure zones in the surrounding strata, roof-to-floor convergence, and floor punching by the shieldbase.     

Durability issues and service lifetime prediction of electrochromic windows for buildings applications

In general, the purposes of this paper are to elucidate the crucial importance of durability and service lifetime prediction (SLP) for electrochromic windows (ECWs) and to present an outline for developing a SLP methodology for ECWs. The specific objectives are (a) to illustrate the generic nature of SLP for several types of solar energy conversion or energy conservation devices, (b) to summarize the major durability issues associated with ECWs, (c) to justify using SLP in the triad of cost, performance, and durability rather than just durability, (d) to define and explain the seven major elements that constitute a generic SLP methodology, (e) to provide background for implementing the SLP methodology for ECWs, including the complexity of the potential degradation mechanisms, and (f) to provide an outline of studies using ECWs for improving the durability of ECW materials and predicting a service lifetime for ECWs using the SLP methodology outlined in objective (d). Our major conclusions are that substantial R&Dis necessary to understand the factors that limit ECW durability, and that it is possible to predict the service lifetime of ECWs.     

Recent developments in high eficiency photovoltaic cells

Enormous progress has been made in recent years on a number of photovoltaic materials and devices in terms of conversion efficiencies. Efficiencies in the range of 18%–24% have been achieved in traditional silicon-based devices fabricated from both multicrystalline and single-crystal materials. Ultrahigh-efficiency (>30%) photovoltaic (PV) cells have been fabricated from gallium arsenide (GaAs) and its ternary alloys like gallium indium phosphide (GaInP₂). The high-efficiency GaAs-based solar cells are being produced on a commercial scale, particularly for space applications. Major advances in efficiency have also been made on various thin-film solar cells based on amorphous silicon (aSi:H), copper gallium indium diselenide (CIGS), and cadmium telluride materials. This paper gives a brief overview of the recent progress in PV cell efficiencies based on these materials and devices.     

The differential induction machine: Theory and performance

This paper presents the theory and performance of a differential induction machine, which is a special type of induction machine having two shafts projected from the two ends of a single stator. Application of a differential load on the two shafts cause them to run at different speed as a motor, which permits true differential movement and thus can meet the requirements of a differential drive in an electric vehicle. The machine is also capable of regeneration in the differential mode. This paper presents the construction of the above machine and performance of the same based on experimental results from a laboratory prototype. The equivalent circuit of the motor has been presented and verified experimentally.     

《通过对改造前后建筑物数据进行聚类分析确定影响办公建筑能源消耗的关键变量》

本研究旨在确定影响空调办公建筑能耗的关键建筑设计变量。本研究基于热带气候条件下的新加坡进行。结合56个办公楼改造前后能源审计报告数据进行评估分析。从这些报告中提取的14个建筑变量的列表构成了超集。对这些数据进行系统分析,得出影响能耗和改造决策的关键变量。为此,利用k均值聚类确定了一个稳健的迭代过程。该过程对14个变量的所有组合进行了测试,以应对改造前后条件下的能源使用强度(EUI,kW·h/m~2·a)的变化。结果表明,最佳变量包括:1)总建筑面积(GFA);2)非空调能耗;3)冷却装置的平均效率;4)冷却装置的装机容量。这些信息可以用来探索需要改造的办公楼的节能潜力。由此产生的集群还可以用来根据改造前的条件和节能潜力来对建筑物进行基准测试。     

High‐strength biodegradable poly(vinyl alcohol)/fly ash composite films

We prepared biodegradable composite films of poly(vinyl alcohol) (PVA) and fly ash (FA) spanning 5, 10, 15, 20, and 25 wt % concentrations by casting aqueous solutions. The tensile strengths of the composite films were increased proportionally via the addition of FA. The strength of the film was enhanced by 193% with 20% FA compared to the neat PVA control. Further addition of FA deviated from the linear trend. The moduli of the composites also increased proportionally with FA addition to 212% at 20 wt % FA addition compared to the control. The percentage strain at break exponentially decreased with the addition of FA. In the dynamic mechanical behavior, the storage and loss moduli both increased with FA content. The tan δ peaks corresponding to the glass‐transition temperature shifted 5–10°C higher above the control sample (73°C). This shift was attributed to a reduction in the mobility of PVA segments because they were anchored by the FA surface. The reductions in mobility manifested in strong interfacial interactions were indicative of hydrogen bonding. Broadening and reduction in the intensities of the stretching and bending peaks of ? OH, ? CH and ? C?O of PVA in the Fourier transform infrared spectra were observed. This suggested that hydrogen bonding was active between the functional groups in the FA and PVA chains. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Kinetic analysis of microbial reduction of Fe(III) in nontronite

Microbial reduction of structural Fe(III) in nontronite (NAu-2) was studied in batch cultures under non-growth condition using Shewanella putrefaciens strain CN32. The rate and extent of structural Fe(III) reduction was examined as a function of electron acceptor [Fe(III)] and bacterial concentration. Fe(ll) sorption onto NAu-2 and CN32 surfaces was independently measured and described by the Langmuir expression with the affinity constant (log K) of 3.21 and 3.30 for NAu-2 and bacteria, respectively. The Fe(II) sorption capacity of NAu-2 decreased with increasing NAu-2 concentration, suggesting a particle aggregation effect. An empirical equation for maximum sorption capacity was derived from the sorption isotherms as a function of NAu-2 concentration. The total reactive surface concentration of Fe(III) was proposed as a proxy for the "effective" or bioaccessible Fe(III) concentration. The initial rate of microbial reduction was first-order with respect to the effective Fe-(III) concentration. A kinetic biogeochemical model was assembled that incorporated the first-order rate expression with respect to the effective Fe(III) concentration, Fe(II) sorption to cell and NAu-2 surfaces, and the empirical equation for maximum sorption capacity. The model successfully described the experimental results with variable NAu-2 concentration. The initial rate of microbial reduction of Fe(III) in NAu-2 increased with increasing cell concentration from 10(2) up to approximately 10(8) cells/mL, and then leveled off with further increase. A saturation-type kinetics with respect to cell concentration was required to describe microbial reduction of Fe(III) in NAu-2 as a function of cell concentration. Overall, our results indicated that the kinetics of microbial reduction of Fe(III) in NAu-2 can be modeled at variable concentration of key variables (clay and cell concentration) by considering the surface saturation, Fe(II) production, and its sorption to NAu-2 and cell surfaces.     

Experimental and economic analysis of energy storage-based single-slope solar still with hollow-finned absorber basin

The paucity of drinking water is an alarming glitch across the globe. The conversion of available seawater into drinking water by utilizing renewable energy is the best way to surmount this challenge. Desalination through solar still is one of the notable, monetary, and viable processes among various desalination approaches. The current research aims to augment the potable water yield of single-slope solar still by using a hollow-finned absorber basin inserted into paraffin wax—phase change material (PCM). The effect of hollow-finned absorber basin on the yield of solar still is investigated separately, with and without PCM, and compared with the results of conventional solar still (CSS). In the first set of experiments, the CSS and solar still with a hollow-finned absorber basin without PCM (SSHF) are investigated. In the second set of experiments, the CSS and solar still with a hollow-finned absorber basin inserted into PCM (SSHFP) are investigated. The experimental results reported that the CSS is having almost the same yield on the 2 days of testing. The yield of SSHF and SSHFP is increased by 15.7% and 52.4%, respectively, when compared with CSS. The results of the economic analysis proved that the payback period and cost per liter of freshwater produced from SSHFP are comparatively better than SSHF and CSS.     

On self-adaptive features in real-parameter evolutionary algorithms

Due to the flexibility in adapting to different fitness landscapes, self-adaptive evolutionary algorithms (SA-EAs) have been gaining popularity in the recent past. In this paper, we postulate the properties that SA-EA operators should have for successful applications in real-valued search spaces. Specifically, population mean and variance of a number of SA-EA operators such as various real-parameter crossover operators and self-adaptive evolution strategies are calculated for this purpose. Simulation results are shown to verify the theoretical calculations. The postulations and population variance calculations explain why self-adaptive genetic algorithms and evolution strategies have shown similar performance in the past and also suggest appropriate strategy parameter values, which must be chosen while applying and comparing different SA-EAs