全文获取类型
收费全文 | 627582篇 |
免费 | 10193篇 |
国内免费 | 2928篇 |
专业分类
电工技术 | 12139篇 |
技术理论 | 5篇 |
综合类 | 1473篇 |
化学工业 | 97156篇 |
金属工艺 | 25007篇 |
机械仪表 | 19653篇 |
建筑科学 | 14450篇 |
矿业工程 | 3593篇 |
能源动力 | 16248篇 |
轻工业 | 52199篇 |
水利工程 | 6716篇 |
石油天然气 | 12359篇 |
武器工业 | 264篇 |
无线电 | 70957篇 |
一般工业技术 | 123378篇 |
冶金工业 | 118298篇 |
原子能技术 | 13112篇 |
自动化技术 | 53696篇 |
出版年
2022年 | 3987篇 |
2021年 | 6359篇 |
2020年 | 4725篇 |
2019年 | 5905篇 |
2018年 | 9837篇 |
2017年 | 9720篇 |
2016年 | 10518篇 |
2015年 | 7231篇 |
2014年 | 11405篇 |
2013年 | 30674篇 |
2012年 | 18502篇 |
2011年 | 24163篇 |
2010年 | 19469篇 |
2009年 | 21252篇 |
2008年 | 22125篇 |
2007年 | 21973篇 |
2006年 | 19422篇 |
2005年 | 17148篇 |
2004年 | 15933篇 |
2003年 | 15396篇 |
2002年 | 14877篇 |
2001年 | 14743篇 |
2000年 | 13887篇 |
1999年 | 14305篇 |
1998年 | 35722篇 |
1997年 | 25148篇 |
1996年 | 19204篇 |
1995年 | 14250篇 |
1994年 | 12655篇 |
1993年 | 12686篇 |
1992年 | 9236篇 |
1991年 | 8693篇 |
1990年 | 8732篇 |
1989年 | 8444篇 |
1988年 | 7936篇 |
1987年 | 6924篇 |
1986年 | 6865篇 |
1985年 | 7657篇 |
1984年 | 7153篇 |
1983年 | 6518篇 |
1982年 | 5929篇 |
1981年 | 6193篇 |
1980年 | 5702篇 |
1979年 | 5724篇 |
1978年 | 5581篇 |
1977年 | 6276篇 |
1976年 | 8367篇 |
1975年 | 4865篇 |
1974年 | 4550篇 |
1973年 | 4642篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
31.
Bosyakova N. A. Pomortsev S. A. Gizatullin R. G. Klyosov Yu. L. Laptov S. V. Kashcheev I. D. Zemlyanoi K. G. 《Refractories and Industrial Ceramics》2021,62(4):381-383
Refractories and Industrial Ceramics - Technology for producing alumina-periclase-carbon refractories of the brands APUK-D and APU-D is developed and implemented. Use of complex antioxidant and... 相似文献
32.
Khammatova V. V. Gainutdinov R. F. Khammatova E. A. Titova L. V. 《Fibre Chemistry》2021,53(3):204-207
Fibre Chemistry - An analysis of the aramid fiber market including the range of industrial textile materials containing chemical fibers for specialized protective clothing of metallurgical workers,... 相似文献
33.
Tallison O. Abreu Roterdan F. Abreu Felipe F. do Carmo Wellington V. de Sousa Helenilson de O. Barros José E.V. de Morais João P.C. do Nascimento Marcelo A.S. da Silva Sergei Trukhanov Alex Trukhanov Larissa Panina Charanjeet Singh Antonio S.B. Sombra 《Ceramics International》2021,47(11):15424-15432
This work presents the dielectric properties of YNbO4 (YNO)–TiO2 composites in the microwave range. X-ray diffraction analysis demonstrates that the addition of TiO2 to YNO results in the formation of a Y(Nb0.5Ti0.5)2O6 phase. In the microwave range, the values of permittivity and dielectric loss did not present major changes with the increment of TiO2. Moreover, the addition of TiO2 results in an improvement in the thermal stability of YNO, with YNO63 demonstrating a resonant frequency of ?8.96 ppm.°C?1. We utilised numerical simulations to evaluate the behaviour of these materials as dielectric resonator antennae and it is found that they exhibit a reflection coefficient below ?10 dB at the resonant frequency, with a realised gain of 4.94 – 5.76 dBi, a bandwidth of 665–1050 MHz and a radiation efficiency above 84%. Our results indicate that YNO–TiO2 composites are interesting candidates for microwave operating devices. 相似文献
34.
35.
Lucas Portela Oliveira Camila Cristina de Foggi Bruna Natália Alves da Silva Pimentel Marcelo Assis Juan Andrés Elson Longo Carlos Eduardo Vergani 《Ceramics International》2021,47(16):22604-22614
The present study reports for the first time the performance of silver phosphate (Ag3PO4) microcrystals as photocatalyst (degradation of Rodamine B-RhB) and antifungal agent (against Candida albicans–C. albicans) under visible-light irradiation (455 nm). Ag3PO4 microcrystals were synthesized by a simple co-precipitation (CP) method at room temperature. The structural and electronic properties of the as-synthetized Ag3PO4 have been investigated before and after 4 cycles of RhB degradation under visible light using X-ray diffraction (XRD), micro-Raman spectroscopy, UV–Vis spectrophotometer and field emission scanning electron microscopy (FE-SEM) images. The antifungal activity was analyzed in planktonic cells and 48h-biofilm of C. albicans by colony forming units (CFU) counting, confocal laser and FE-SE microscopies. Statistical analysis was carried out using SPSS software. Morphological and structural modifications of Ag3PO4 were observed upon recycling. After 4 recycles, the material maintained its photodegradation property; an eightfold increase in the efficiency of Ag3PO4 was observed in planktonic cells and a two fold increase in biofilm when irradiated under visible light. Thus, higher antifungal effectiveness against C. albicans was obtained when associated with visible-light irradiation. 相似文献
36.
Liangtao Yang Liang-Yin Kuo Juan Miguel López del Amo Prasant Kumar Nayak Katherine A. Mazzio Sebastian Maletti Daria Mikhailova Lars Giebeler Payam Kaghazchi Teófilo Rojo Philipp Adelhelm 《Advanced functional materials》2021,31(38):2102939
A known strategy for improving the properties of layered oxide electrodes in sodium-ion batteries is the partial substitution of transition metals by Li. Herein, the role of Li as a defect and its impact on sodium storage in P2-Na0.67Mn0.6Ni0.2Li0.2O2 is discussed. In tandem with electrochemical studies, the electronic and atomic structure are studied using solid-state NMR, operando XRD, and density functional theory (DFT). For the as-synthesized material, Li is located in comparable amounts within the sodium and the transition metal oxide (TMO) layers. Desodiation leads to a redistribution of Li ions within the crystal lattice. During charging, Li ions from the Na layer first migrate to the TMO layer before reversing their course at low Na contents. There is little change in the lattice parameters during charging/discharging, indicating stabilization of the P2 structure. This leads to a solid-solution type storage mechanism (sloping voltage profile) and hence excellent cycle life with a capacity of 110 mAh g-1 after 100 cycles. In contrast, the Li-free compositions Na0.67Mn0.6Ni0.4O2 and Na0.67Mn0.8Ni0.2O2 show phase transitions and a stair-case voltage profile. The capacity is found to originate from mainly Ni3+/Ni4+ and O2-/O2-δ redox processes by DFT, although a small contribution from Mn4+/Mn5+ to the capacity cannot be excluded. 相似文献
37.
Kruglikov S. S. Zagorskii D. L. Kolesnikov V. A. Doludenko I. M. Bedin S. A. 《Theoretical Foundations of Chemical Engineering》2021,55(5):942-951
Theoretical Foundations of Chemical Engineering - The effect of the electrolyte composition, mass-transfer conditions, pore diameter, interpore distance, and electric parameters on the formation of... 相似文献
38.
L.J. Espinoza-Pérez S. Esquivel-Medina E. López-Honorato 《Ceramics International》2021,47(11):15527-15532
The influence of the microstructure on the corrosion rate of three monolithic SiC samples in FLiNaK salt at 900 °C for 250 h was studied. The SiC samples, labeled as SiC-1, SiC-2, and SiC-3, had corrosion rates of 0.137, 0.020, and 0.043 mg/cm2h, respectively. Compared with grain size and the presence of special grain boundaries (i.e., Σ3), the content of high-angle grain boundaries (HAGBs) appeared to have the strongest influence on the corrosion rate of SiC in FLiNaK salt, since the corrosion rate increased six times as the concentration of high-angle grain boundaries increased from 19 to 32% for SiC-2 and SiC-1, respectively. These results stress the importance of controlling the content of HAGBs during the production process of SiC. 相似文献
39.
T.V. Vakalova L.P. Devyashina Sh.M. Sharafeev N.P. Sergeev 《Ceramics International》2021,47(11):15282-15292
One of the drawbacks of fusible clays is the narrow sintering interval due to a sharp increase in the amount of iron-silicate melt at a temperature of 1000–1100 °C, which hardens in the form of a glass phase upon cooling. This leads to a relatively low mechanical strength of the calcined samples and causes the danger of melting the granular material surface from such clays during the firing process. To increase the strength of samples of fusible clays, the influence of diabase and granitoid rocks was considered. It was found that the strengthening effect of diabase and granitoid rock additives in an amount of 20–50% in a mixture with fusible clay is due to an increase of total content of the crystalline phase (mullite, cristobalite and residual quartz) from 18–20% in clays without additives to 22–28 % - in mixtures with diabase and to 28–34% - with granitoid additives) at a temperature of 1050–1100 °C. This increase is due to the activation of synthesis processes of secondary mullite and crystallization from alkali-rich feldspar melt of amorphous silica, released from the structure of clay minerals. The established influence of the igneous rocks used made it possible to develop compositions and propose process flow sheet for producing aluminosilicate proppants based on fusible clays. The use of granitoid and diabase rocks in an amount of 20–70% with fusible clays produces lightweight aluminosilicate proppants with bulk density of 1.40–1.46 g/cm3 at temperature range of 1050–1100 °C, which can endure destructive pressures up to 34.5–52 MPa. 相似文献
40.
The calcium pump (sarco/endoplasmic reticulum Ca2+-ATPase, SERCA) plays a major role in calcium homeostasis in muscle cells by clearing cytosolic Ca2+ during muscle relaxation. Active Ca2+ transport by SERCA involves the structural transition from a low-Ca2+ affinity E2 state toward a high-Ca2+ affinity E1 state of the pump. This structural transition is accompanied by the countertransport of protons to stabilize the negative charge and maintain the structural integrity of the transport sites and partially compensate for the positive charges of the two Ca2+ ions passing through the membrane. X-ray crystallography studies have suggested that a hydrated pore located at the C-terminal domain of SERCA serves as a conduit for proton countertransport, but the existence and function of this pathway have not yet been fully characterized. We used atomistic simulations to demonstrate that in the protonated E2 state and the absence of initially bound water molecules, the C-terminal pore becomes hydrated in the nanosecond timescale. Hydration of the C-terminal pore is accompanied by the formation of water wires that connect the transport sites with the cytosol. Water wires are known as ubiquitous proton-transport devices in biological systems, thus supporting the notion that the C-terminal domain serves as a conduit for proton release. Additional simulations showed that the release of a single proton from the transport sites induces bending of transmembrane helix M5 and the interaction between residues Arg762 and Ser915. These structural changes create a physical barrier against full hydration of the pore and prevent the formation of hydrogen-bonded water wires once proton transport has occurred through this pore. Together, these findings support the notion that the C-terminal proton release pathway is a functional element of SERCA and also provide a mechanistic model for its operation in the catalytic cycle of the pump. 相似文献