Synthesis and characterization of layered perovskite-type organic-inorganic hybrids (R-NH3)2(CH3NH3)Pb2I7

Layered organic-inorganic hybrids containing bilayer perovsikte (R-NH3)2(CH3NH3)Pb2I7 (where R=C12H25,C6H5C2H4) were synthesized by reactions in solution. The influences of the solvents and the reactant ratio on the structures of the products were investigated. The structures and the properties of the hybrids were characterized using X-ray diffraction (XRD) and ultraviolet and visible (UV) adsorption spectra. For comparing with the bilayer perovskite hybrids in structure and band gap magnitude, the hybrids containing monolayer perovskite (R-NH3)2PbI4 were also synthesized and characterized. The results demonstrate that the thickness of inorganic layer has obvious effect on the tunneling magnitude of the band gap but the organic part can be micro actuator of band gap.     

移动台车栏板辅助浇筑系统的设计与应用

蒲石河工程下水库大坝顶部混凝土护栏位于坝顶临空边沿,钢筋绑扎和模板支立作业难度大,施工时存在安全隐患。为此,蒲石河工程设计了移动台车栏板辅助浇筑系统并成功应用。实践表明,作业台车设计可靠、安全稳定、操作简便、定位准确、移动方便,保障了施工人员人身安全,节约了成本,加快了工期,提高了模板支立质量,值得类似工程借鉴并推广使用。     

基于水管理对象的数字流域顶层设计技术方法研究

水利信息化是实现水利现代化的基础和重要标志。以水管理对象为基础,利用现代信息技术构造数字流域,集中管理流域内的水事问题,是实现流域现代化管理的有效途径。从数字流域体系架构、水管理对象构造及全息化描述、基础平台构建、业务系统的构件化开发、数字功能流域等方面详细介绍了基于水管理对象的数字流域构造技术方法。     

“双转移”背景下的河源产业集群内企业竞争力研究

河源若想抓住＂双转移＂这个契机加速发展,就势必要结合河源的产业发展现状及资源状况,选择有优势的产业重点培育,发展壮大一些龙头企业,进而带动中小企业的发展,提高区域竞争力。区域竞争力的不断增强,也势必会促进更多、更优秀的企业来河源发展。同时,集群内企业也要充分利用这一机遇,利用企业内外资源,加快提升自身的竞争力。     

考虑互动特性的水火电力系统优化调度策略

针对水火电联合运行的电力系统,首次利用优化的方法分析水电和火电间的相互作用规律和负荷的空间分布特性对电力系统节能运行的影响规律,揭示了其联合运行时的水电和火电的运行特征.以此为基础,构建了可充分发挥梯级水电站互动特性的优化调度模型.以一个含有梯级水电站的水火电力系统为例进行分析,结果表明可通过充分发挥水电能源的互补作用,实现非可再生能源的节约和促进能源的可持续高效利用.     

Microwave permeability of single cobalt nanotube studied by micromagnetics simulations and generalized Snoek’s law

Microwave permeability spectra of single Co nanotube under equilibrium state have been studied by micromagnetics simulation.More than four obvious resonance peaks have been found(11.72,24.20,33.18 and 39.55 GHz).Such large resonance frequency cannot be found in other traditional magnetic materials.The configurations of magnetic moments along the nanotube have been simulated.The results show that the top end of nanotube has a"flow-out"pattern of magnetic moments configuration.The bottom end has a"flow-in"pattern of magnetic moments configuration.The magnetic moments within the main body of nanotube are aligned perfectly along the length of nanotube.The magnitude of natural resonance peak is strongly related to the volume fraction of a zone,which has the same orientation of magnetic moments.Large microwave permeability values have been found for single nanotube.The generalized Snoek’s law has been used to validate the micromagnetics simulations in this paper.     

Heterogeneous acid catalytic esterification by porous polyoxometalate-tantalum pentoxide nanocomposites

Polyoxometalates (POMs) are useful catalysts in both redox and acid catalysis reactions since its catalytic features can be controlled at a molecular level. We investigated POM (POM = H₃PW₁₂O₄₀) on tantalum pentoxide (Ta₂O₅) via hydrolysis of tantalum pentachloride (TaCl₅) in the presence of POM using the sol-gel method for acid catalytic reaction. All obtained amorphous materials have been characterized by inductively coupled plasma atomic emission spectroscopy (ICP-AES), Fourier transform infrared (FT-IR) spectra, Raman scattering spectroscopy, ³¹P magic-angle spinning (MAS) NMR, field emission scanning electron microscopy (FESEM), and nitrogen adsorption/desorption analysis, in order to confirm the structure integrity of the Keggin unit in as-prepared composites and investigate the morphology and surface textural property of the composites. Catalytic activity of the catalysts has been evaluated for esterification of acetic acid with ethanol as a model reaction with different catalytic reaction parameters such as POM loading, reaction time, catalyst dose, molar ratio of the reactants, etc. The conversion of ethanol reached 87.4 % and the turnover frequency (TOF) was 2.9×10³.Meanwhile, it is easy to separate and recover POM/Ta₂O₅ from the reaction system.