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991.
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993.
Wenfeng Guo Yingzi Wang Adan Li Tifeng Jiao Faming Gao 《Journal of Electronic Materials》2013,42(6):939-943
Perovskite-type La0.8Ca0.2CrO3 complex oxides were synthesized by a combustion method. Microstructural evolution, electrical properties, and thermal expansion behavior of the ceramics were investigated in the sintering temperature range of 1250°C to 1450°C. It was found that the electrical conductivity (σ e) remarkably improved with increasing sintering temperature from 1250°C to 1400°C, ascribed to the development of microstructural densification, whereas it declined slightly above 1400°C due to generation of excessive liquid. The specimen sintered at 1400°C had a maximum conductivity of 31.6 S cm?1 at 800°C, and lowest activation energy of 0.148 eV. The improvement of the thermal expansion coefficient (TEC) with increasing sintering temperature was monotonic as a result of the microstructural densification of the materials. The TEC of La0.8Ca0.2CrO3 sintered at 1400°C was about 10.5 × 10?6 K?1, being consistent with other components as high-temperature conductors. With respect to microstructure, electrical properties, and thermal expansion, the preferable sintering temperature was ascertained to be about 1400°C, which is much lower than for the traditional solid-state reaction method. 相似文献
994.
995.
针对电机叠频试验容易产生较大的有功功率低频波动,在弱电网条件下对电网造成污染导致电网上其他设备无法正常工作,提出了一种新型共直流母线的高压变频器。其整流侧采用移相变压器加二极管整流方案,通过电容串联建立高压直流母线,直流母线储存能量使其不回馈至电网,特别适用于弱电网下的电机叠频试验;逆变侧采用MMC逆变器(Modular Multilevel Converter),通过平衡控制策略达到模块电压平衡,环流抑制的效果。最后应用PSCAD/EMTDC搭建系统的仿真模型,证实了方案的可行性。 相似文献
996.
针对远红外探测器衬底制造对高品质碲锌镉单晶材料的需求,为了满足高品质碲锌镉单晶生长对高纯度原材料的需要,基于区熔提纯原理与工艺实现方法设计出一种由区熔炉炉体、移动加热装置、气路系统和电气控制系统等组成的分布式碲锌镉晶体制备材料区熔提纯炉。采用氢气除杂、氮气保护和伺服机构控制加热温度场移动的方法来实现区熔提纯。在区熔窄区宽度为15 mm和倾斜角度为7°的条件下,开展了碲、锌和镉等原材料的区熔提纯实验。结果表明,当加热温度高于材料熔点50 K且移动速度为0.006 mm·s-1时,区熔加热装置往复移动10次以上,可将碲锌镉晶体制备所需的原材料纯度由6N (99.9999%)提高到7N (99.99999%);分布式碲锌镉晶体制备材料区熔提纯炉的加热温度、加热装置移动速度和移动稳定性较好。 相似文献
997.
“Regioselective Deposition” Method to Pattern Silver Electrodes Facilely and Efficiently with High Resolution: Towards All‐Solution‐Processed,High‐Performance,Bottom‐Contacted,Flexible, Polymer‐Based Electronics 下载免费PDF全文
Deyang Ji Lang Jiang Yunlong Guo Huanli Dong Jianpu Wang Huajie Chen Qing Meng Xiaolong Fu Guofeng Tian Dezhen Wu Gui Yu Yunqi Liu Wenping Hu 《Advanced functional materials》2014,24(24):3783-3789
“Regioselectivity deposition” method is developed to pattern silver electrodes facilely and efficiently by solution‐process with high resolution (down to 2 μm) on different substrates in A4 paper size. With the help of this method, large‐area, flexible, high‐performance polymer field‐effect transistors based on the silver electrodes and polyimide insulator are fabricated with bottom‐contact configuration by all‐solution processes. The polymer devices exhibit high performance with average field‐effect mobility over 1.0 cm2 V?1 s?1 (the highest mobility up to 1.5 cm2 V?1 s?1) and excellent environmental stability and flexibility, indicating the cost effectiveness of this method for practical applications in organic electronics. 相似文献
998.
Qing‐Qiang Kong Zhuo Liu Jian‐Guo Gao Cheng‐Meng Chen Qiang Zhang Guangmin Zhou Ze‐Chao Tao Xing‐Hua Zhang Mao‐Zhang Wang Feng Li Rong Cai 《Advanced functional materials》2014,24(27):4222-4228
As a low dimensional crystal, graphene attracts great attention as heat dissipation material due to its unique thermal transfer property exceeding the limit of bulk graphite. In this contribution, flexible graphene–carbon fiber composite paper is fabricated by depositing graphene oxide into the carbon fiber precursor followed by carbonization. In this full‐carbon architecture, scaffold of one‐dimensional carbon fiber is employed as the structural component to reinforce the mechanical strength, while the hierarchically arranged two‐dimensional graphene in the framework provides a convenient pathway for in‐plane acoustic phonon transmission. The as‐obtained hierarchical carbon/carbon composite paper possesses ultra‐high in‐plane thermal conductivity of 977 W m?1 K?1 and favorable tensile strength of 15.3 MPa. The combined mechanical and thermal performances make the material highly desirable as lateral heat spreader for next‐generation commercial portable electronics. 相似文献
999.
Bio‐Inspired Preparation of Fibrin‐Boned Bionanocomposites of Biomacromolecules and Nanomaterials for Biosensing 下载免费PDF全文
Fangfang Han Xin Qi Lingyan Li Lijuan Bu Yingchun Fu Qingji Xie Manli Guo Yanbin Li Yibin Ying Shouzhuo Yao 《Advanced functional materials》2014,24(31):5011-5018
Learning from nature is one of the most promising ways to develop advanced functional materials. Here, inspired by blood coagulation, novel fibrin‐boned bionanocomposites are reported as efficient immobilization matrices of biomacromolecules and nanomaterials for biosensing. Glucose oxidase (GOx), Au nanoparticles (AuNPs), and Fe3O4 magnetic nanoparticles (MNPs) are adopted as the model biomacromolecules and nanomaterials. By integrating the thrombin‐triggered coagulation of fibrin with advanced surficial modification techniques, four kinds of immobilization strategies are developed and evaluated. Digital imaging, UV‐vis spectroscopy, scanning/transmission electron microscopy, electrochemical methods, and N2 adsorption‐desorption isotherms are used to investigate the formation, immobilization efficiency, and performance of various bionanocomposites. The fibrin‐boned networks show inherent biocompatibility, excellent adsorbability, porosity, and functionalization ability, endowing the bionanocomposites with high efficiencies in capturing AuNPs, MNPs and GOx (99%, 98%, and 57% captured under the given conditions, respectively), as well as significant mass‐transfer and biocatalysis efficiencies. Therefore, the fibrin‐boned bionanocomposites show great potential for biosensing, for example, a fibrin‐AuNPs‐GOx‐glutaraldehyde bionanocomposites modified Au electrode is highly sensitive to glucose (145 μA cm?2 mM?1) allowing for a limit of detection down to 25 nM, being much superior to those of the reported analogues. The presented experimental platform/strategy may find wide applications in the development of other bio/nano‐materials/devices. 相似文献
1000.
Ultrasmall Graphene Oxide Supported Gold Nanoparticles as Adjuvants Improve Humoral and Cellular Immunity in Mice 下载免费PDF全文
Yuhua Cao Yufei Ma Mengxin Zhang Haiming Wang Xiaolong Tu He Shen Jianwu Dai Huichen Guo Zhijun Zhang 《Advanced functional materials》2014,24(44):6963-6971
Adjuvants play an important role in vaccines. Alum and MF59 are two dominant kinds of adjuvants used in humans. Both of them, however, have limited capacity to generate the cellular immune response required for vaccines against cancers and viral diseases. It is desirable to develop new and efficient adjuvants with the aim of improving the cellular immune response against the antigen. Here, the feasibility and efficiency of ultrasmall graphene oxide supported gold nanoparticles (usGO‐Au) as a new immune adjuvant to improve immune responses are explored. usGO‐Au is obtained from reduction of chloroauric acid using usGO and then decorated with ovalbumin (OVA, a model antigen) through physical adsorption to construct usGO‐Au@OVA. As the results show, the as‐synthesized usGO‐Au@OVA can efficiently stimulate RAW264.7 cells to secrete tumor necrosis factor‐α (TNF‐α), a mediator for cellular immune response. In vivo studies demonstrate that usGO‐Au@OVA can also promote robust OVA specific antibody response, CD8+ T cells proliferation, and different cytokines secretion. The results indicate that using usGO‐Au as an adjuvant can stimulate potent humoral and cellular immune responses against antigens, which may promote better understanding of cellular immune response and facilitate potential applications for cancer and viral vaccines. 相似文献