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81.
S. V. Sysoev A. O. Kolontaeva L. D. Nikulina M. L. Kosinova F. A. Kuznetsov V. I. Rakhlin A. V. Lis M. G. Voronkov 《Glass Physics and Chemistry》2012,38(1):8-14
The characterization of bis(trimethylsilyl)ethylamine was carried out using a combination of IR, UV, 1H, 13C, 29Si, and 15N NMR spectroscopy, as well as elemental analysis. The spectral characteristics of the compound were determined. The temperature
dependence of the saturated vapor pressure was established by tensimetric studies, and the thermodynamic characteristics of
vaporization were calculated. Thermodynamic simulation of the chemical vapor deposition was performed and was used as a basis
for predicting the composition of the deposited phase complexes depending on the type of reagent and the process conditions. 相似文献
82.
83.
Climate change will entail new conditions for the construction industry. Knowledge about the implications of climate change on the built environment will be of the utmost importance to the industry in years to come. A building is a ‘long lasting’ durable asset that is changed over time due to exogenously imposed strains and by actions. The built environment has an expected lifetime varying from 60 to more than 100 years. Hence, the building economics of climate change should be treated within a dynamic analytical framework that explicitly allows for changes in the information sets over time. The building stock of the future consists of the building stock of today and of new construction. In the future, parts of the present building stock will be adapted to changes in the environment, while some parts will be kept as they are. Analysis of how building stock is affected by future climate change should handle this diversity. This can be done through the use of a putty-clay model. Uncertainty of what kind of climate regimes will prevail in the future enhances the profitability of actions that increase future flexibility. Hence, the real option approach to building economics is utilized. 相似文献
84.
承包商对工程的具体掌控力要远高于业主方,业主方面对工程实施中的各种问题往往鞭长莫及。为了帮助业主方从源头上实现项目的成功管理,就要发挥工程咨询机构的作用。本文论述了工程咨询机构在招标阶段项目管理的核心内容,指明了其在招标阶段的关键工作,在一定程度上实现了项目资源的优化配置,为业主节约了成本和效益最大化。同时,也分析了我国目前项目管理发展中存在的问题,并参照国内外先进管理思想和管理模式提出了我国工程咨询机构的发展方向及相应对策,对我国工程咨询业的发展有一定的参考价值。 相似文献
85.
G. L. Myronchuk O. V. Zamurueva O. V. Parasyuk L. V. Piskach A. O. Fedorchuk N. S. AlZayed A. M. El-Naggar J. Ebothe M. Lis I. V. Kityk 《Journal of Materials Science: Materials in Electronics》2014,25(7):3226-3232
Principal optical properties of Tl1?xIn1?xSixSe2 solid state crystalline alloys were studied. The influence of the x on the principal optical and structural features was explored. Temperature features of the band energy gap are studied. The possible explanation of the observed behavior is given within a framework of the Urbach rule approach. The role of intrinsic defective sub-system and anharmonic electron–phonon interaction is discussed. A possible application of the titled materials for the infrared optoelectronic is discussed. The replacement of In atoms by Sn is evaluated. Additionally studies of influence of x on the optoelectronic features is done. The formation of the positive charged ions (donors) and negatively charged ions is explored within the introduced intrinsic defect models. 相似文献
86.
K. Stallinski M. Kaczmarek S. Lis D. Komar A. Szyczewski 《中国稀土学报(英文版)》2009,27(4):593-597
Investigation of ultraweak emissions in the processes of chemiluminescence, CL, and electrochemiluminesce, ECL, requires special techniques of their recording and spectral analysis. From among the hitherto proposed methods of detection of the emission spectra of these processes, that of the cut-off filter was most sensitive. The usefulness of this method in interpretation of the CL and ECL systems of the quantum yields in the range 1×10−9−1×10−11 containing ions and complexes of Eu(III), Tb(III) and Dy(III) was shown. Exceptional character of the emission bands of lanthanide ions, being a result of the f-f electron transitions and in particular their low FWHM, permitted the application of the cut-off filter method to their analysis. The results obtained for CL and ECL on the basis of analysis of ultraweak emission proved to be successful in analytical applications. The systems containing Eu(III) ions hydrated or complexed with organic ligands enabled inferring changes in the coordination sphere of the ions. 相似文献
87.
Chamindu Deepagoda T.K.K Ken Kawamoto Hirotaka Saito Lis Wollesen de Jonge Per Moldrup Toshiko Komatsu 《Soils and Foundations》2011,51(1):123-132
Colloid-facilitated transport enhances migration of strongly sorbing compounds (e.g., radionuclides, phosphorus, heavy metals) in soil and groundwater. Mobilization, transport and deposition of soil colloids are the underlying processes governing colloid-facilitated contaminant transport. Although significant progress has been made in simulating mobilization and transport/deposition of model colloids in different collector systems, it may be inadequate for the prediction of natural colloidal behavior in the subsurface. This study quantifies the leaching of natural volcanic ash soil colloids (NC) as well as the simultaneous transport of applied water dispersible soil colloids (WDC) in aggregated volcanic ash soil columns. Two water-saturated soil columns were irrigated with artificial irrigation water (AIW) at an intensity of 80 mm/hr for 60 hours. Two additional columns were irrigated at the same intensity, but a colloidal suspension of 5 mg/L was applied after 20 hours for a period of 20 hours. Effluent colloid concentrations were measured in each experiment. HYDRUS-1D was used for the simulation and estimation of colloid transport parameters. The results clearly showed different kinetics for applied colloid transport and natural colloid leaching. Transport of applied WDC followed first-order attachment kinetics, while the two-site equilibrium/kinetic model with equal fractions of equilibrium and kinetic sites best described the leaching of NC. Coupling these best model approaches well predicted the simultaneous leaching of natural and applied colloids, hereby providing a useful tool for the design of colloid-based in-situ soil remediation systems. 相似文献
88.
Synthesis of Ternary Titanium Aluminum Carbides Using Self-Propagating High-Temperature Synthesis Technique 总被引:6,自引:0,他引:6
Micha opaciski Jan Puszynski Jerzy Lis 《Journal of the American Ceramic Society》2001,84(12):3051-3053
Different ternary carbide phases, namely Ti3 AlC2 , Ti3 AlC, and Ti2 AlC, were successfully synthesized in a self-sustaining regime. Direct reactions among elemental powders of titanium, aluminum, and carbon are strongly exothermic, and the resulting reaction products consist of binary carbides and they are partially molten. The use of TiAl, instead of elemental titanium and aluminum, significantly reduces the combustion temperature. As a result, ternary titanium aluminum carbide phases are formed. In addition, the combustion-synthesized products are not sintered and easy to deagglomerate. Reaction conditions and X-ray diffraction patterns of different ternary phases formed in a self-sustaining regime are presented. 相似文献
89.
Electric arc furnace dusts are among the most environment polluting wastes. Numerous utilization technologies have been developed for dusts containing up to 4% of Zn and more than 20% of Zn. However, the remaining part of steelmaking dusts are the most problematic ones, as they are mostly dumped generating costs and posing serious environmental threats. This paper provides an analysis of the potential utilization options for dusts containing ca. 10% of zinc generated in a single electric steelmaking shop. Physical and chemical properties of dusts have been determined and examined, and furthermore, results of the studies on the EAFD utilization in production of cement clinker and industrial glass have been discussed. It has been found that a particularly beneficial feature of the production technology proposed is that the iron content exceeds 30%. The influence of the dusts used on the functional properties of the products obtained has been established as well as the environmental impact of the processes and products in question and the dust mass possible to be utilized in the production technology proposed have been determined. 相似文献
90.
M Dong XQ Ding DI Pinon EM Hadac RP Oda JP Landers LJ Miller 《Canadian Metallurgical Quarterly》1999,274(8):4778-4785
The molecular basis of ligand binding to receptors provides important insights for drug development. Here, we explore domains of the cholecystokinin (CCK) receptor that are critical for ligand binding, using a novel series of fluorescent photolabile probes, receptor proteolysis, and rapid high resolution separation of peptide fragments by capillary electrophoresis. Each probe incorporated the same fluorophore and a photolabile p-benzoylphenylalanine at the amino terminus of the pharmacophoric domain (residue 24 of CCK-33) of CCK analogues representing full agonist, partial agonist, and antagonist of this receptor. Each was used to label the CCK receptor expressed on Chinese hamster ovary-CCKR cells, with the labeled domain then released by cyanogen bromide cleavage. Capillary electrophoresis with laser-induced fluorescence detection achieved an on-capillary mass sensitivity of 1.6 attomoles (10(-18) mol), with an excellent signal-to-noise ratio. Each of the biologically divergent, but structurally similar probes saturably and specifically labeled the same receptor domain, consistent with conservation of "docking" determinants. This had an apparent mass of 2.9 kDa, most consistent with the first extracellular loop domain. An additional probe having its site of covalent attachment in a different region of the probe (residue 29 of CCK-33) labeled a distinct receptor fragment with differential migration on capillary electrophoresis (third extracellular loop). Identification of the specific receptor residue(s) covalently linked to the amino-terminal probes must await further fragmentation and sequence analysis. 相似文献