金属卟啉仿生催化剂进展

细胞色素P-450是一种生物体内催化分子氧氧化内源底物的单加氧酶,其活性片段的核心结构是金属卟啉络合物。人工合成的金属卟啉络合物可作为细胞色素P-450的有效模拟物,应用于烯烃、直链烷烃、环烷烃、芳烃、芳烃侧链、及各种杂原子等多种底物的催化氧化。人工合成的金属卟啉络合物可分为：对称型金属卟啉、非对称型金属卟啉、μ-氧代双核金属卟啉、负载型金属卟啉4大类。现以金属卟啉络合物的结构为线索,论述了结构与催化活性及稳定性的内在联系,重点介绍了近几年国内外金属卟啉仿生催化剂的氧化应用研究进展,及仿生催化氧化的工业化发展前景。     

石英晶体最大双折射率色散特性的椭偏测量

为了测量石英晶体最大双折射率的色散特性,在椭偏光谱仪的水平透射测量模式下,通过对确定厚度的石英波片相位延迟量的精确测量,计算出了石英晶体的最大双折射率值,并进行了误差分析。结果表明:这种方法光路简单、操作方便,屏蔽了光源的不稳定性;双折射率测量精度达到了10-6,比连续偏光干涉法的测量精度提高了1个数量级;实现了对石英晶体的最大双折射率色散特性的连续光谱测量;此方法对其它双折射晶体材料的双折射率色散特性的研究也同样适用。     

柞蚕丝织物的柔软整理方法分析

采用蛋白酶和有机硅柔软剂对柞蚕丝织物进行柔软整理,通过正交试验,确定了两种整理的最佳工艺条件,并对比分析了两种整理方法在柔软效果、工艺条件和整理成本上的差异,得出柞蚕丝织物采用有机硅柔软整理优于蛋白酶整理的结论。     

Isolation and identification of a sulfate reducing bacteria and sequence analysis of its dissimilatory sulfite reductase gene

A sulfate reducing bacteria was isolated from mining sewage of Daqing Oilfield by Hungate anaerobic technology. Physiological-biochemical analysis showed that the strain could utilize polyacrylamide as sole carbon and nitrogen source. The sequence analysis of 16S rDNA illustrated that the similarity of F8 and Desulfovibrio desulfuricans (AF192153) was 99%, and the similarity sequence of dissimilatory sulfite reductase gene (DSR) cloned from the strain and Desulfovibrio desulfuricans (AF273034) was 98%. Their phylogenitic analysis was basically anastomosed, and thus temporarily named as Desulfovibrio desulfuricans F8. The DSR cloned from F8 strain was 2740 bp in length consisting of three ORF, DSRA, DSRB and DSRD as a single operon (DSRABD) regulated by the same operator. DSRA contained typical conservative box of sulfate—sulfite reducing enzyme (SiteⅠand SiteⅡ), which could bind siroheme and [Fe4S4]. DSRB retained a [Fe4S4] binding site, with an uncomplimentary structure for siroheme binding. There was no conservative box in DSRD. Sequence analysis of DSR will provide a theoretical basis for quantitative detection, metabolic pathway modification through gene engineering, and sulfate reducing bacteria (SRB) suppression.     

Damage and deterioration mechanism and curing technique of concrete structure in main coal cleaning plants

Concrete structures in main coal cleaning plants have been rebuilt and reinforced in the coal mines of the Shanghai Da-tun Energy Sources Co. Ltd., the first colliery of the Pingdingshan Coal Co. Ltd. and the Sanhejian mine of the Xuzhou Mining Group Co. Ltd. In these projects, the operating environment and reliability of concrete structures in the main plants of the three companies were investigated and the safety of the structures inspected. Qualitative and quantitative analyses were made on the spe-cial natural, technological and mechanical environments around the structures. On the basis of these analyses, we discuss the long-term, combined actions of the harsh natural (corrosive gases, liquids and solids) and mechanical environments on concrete structures and further investigated the damage and deteriorating mechanisms and curing techniques of concrete structures in the main coal cleaning plants. Our study can provide a theoretical basis for ensuring the reliability of concrete structures in main coal cleaning plants.     

剩余电流动作保护装置的设计

针对设备的剩余电流问题,根据剩余电流保护装置的工作原理,基于C8051F410单片机运行速率高、功耗低等优点,设计了一款剩余电流动作保护装置．详细描述了该装置的产品结构和各项功能．经实验证明,该装置体积小,重量轻,便于携带,功耗低,测试准确,精度高．     

压型钢板—混凝土组合楼板瞬态温度场有限元分析

要对压型钢板—混凝土组合楼板进行抗火性能的研究,首先要研究组合楼板在受火情况下板内温度场的分布情况.用大型通用有限元分析软件ANSYS对青岛理工大学韩金生所进行的组合楼板抗火试验进行数值分析,并与试验结果进行对比,验证所建立的模型的正确性,并为以后进一步对组合楼板抗火性能研究提供基础性的研究成果.     

米曲霉在牛乳中最适生长条件的研究

利用米曲霉对牛乳进行发酵,通过单因子及正交试验以菌丝体干重为指标对其在牛乳中的生长进行了研究．结果表明：接种量为4％,装液量为30mL,摇床转速为180r／min时菌丝体干重可达到最大．此外测得最大菌丝体干重时的蛋白质分解率可达35．6％．     

三聚氰胺对酸乳发酵的影响

为了阐明三聚氰胺对酸乳发酵的影响,以含不同浓度三聚氰胺的鲜牛乳为原料进行了酸乳的发酵实验,测定了发酵过程中的pH值、发酵前后的活菌数及凝乳时间.结果表明：添加三聚氰胺会增大凝乳时的pH值,变化的最大值为0.78;也会增加凝乳时间,增加的最大值为1.5 h;凝乳时,乳酸菌的活菌数有所下降,但下降值不超过一个数量级;酸乳中三聚氰胺浓度越高,凝乳时质地越疏松;酸乳中菌体的形态差异并不明显.     

单级倒立摆系统分析与设计

倒立摆系统以其自身的不稳定性为系统的平衡提出了难题,也因此成为自动控制实验中验证控制算法优劣的极好实验装置.作者对倒立摆系统的非线性模型进行了线性化处理,通过利用全状态反馈和线性二次型最优控制两种方法对系统进行控制以满足设计指标,最后设计仿真实验软件平台以方便对比参数设置和系统性能之间的关系.