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21.
The results of conversion determinations on the products from Powhatan No.5 coal liquefied in an autoclave and in a high-pressure, high-temperature e.s.r. cavity are reported. Oil, asphaltene and preasphaltene yields, and overall conversion have been determined for Powhatan No.5 coal samples liquefied in tetralin, SRC-11 heavy distillate, and naphthalene at temperatures from 400 to 480 ° C in both reactor systems. The concept of reaction severity is introduced and used to formalize the relation between the effect of temperature and reaction time on oil yield and conversion. Oil is the predominant product in liquefaction in tetralin or naphthalene, asphaltene is the major product of liquefaction in SRC-II heavy distillate. Retrogressive reaction (THF-insoluble product formation) becomes severe when SRC-II heavy distillate is the liquefaction solvent and residence time of >10 min are used at temperatures >450 °C. Preasphaltenes appear to be the only intermediate species in Powhatan No.5 liquefaction. 相似文献
22.
The reactivity of hexamethylphosphorus triamide, (P[N? (CH3)2]3) (HPT), with cotton cellulose was examined under various conditions. HPT was found to react readily with the cellulose to produce a cellulose phosphite and/or phosphate ester having approximately one acidic hydrogen atom per phosphorus atom. The reaction of HPT with cotton cellulose was efficiently catalyzed by dimethylamine hydrochloride (1%). The phosphorus content imparted by the catalyzed reaction on cotton fabrics was approximately twice that imparted by the uncatalyzed reaction. Flame resistance of the treated fabrics ranged from fair to excellent. The treated fabrics also exhibited ion exchange properties and some crosslinking. 相似文献
23.
The reductive alkylation of Illinois No. 6 coal has been carried out using potassium and naphthalene in tetrahydrofuran and methyl-13C and butyl-1 -13C iodides to alkylate the resultant polyanion. The soluble products of the reductive alkylation reaction were isolated by extraction and chromatography. Proton and carbon n.m.r. spectra were recorded. The intense resonance signal at δ3.95 which appears in the proton n.m.r. spectra of Illinois No. 6 coal butylated with unenriched butyl iodide is split into a doublet by the 13C nuclei. Similar results were obtained for the methylation products. The chemical shift and coupling interaction establish that aryl ethers are a very important constituent of the alkylated coal. The carbon n.m.r. spectra of the coal alkylated with 13C-enriched alkyl iodides are intense. The resonances of the C-alkylation products appear in a single broad band with a maximum intensity in spectral regions compatible with the formation of the reductive alkylation products of certain polynuclear aromatic hydrocarbons or the base-catalysed alkylation of certain benzylic carbon atoms. The resonances of the N -alkylation products appear in two distinct bands. These resonances are tentatively assigned to amines produced as a result of reductive alkylation of heterocyclic compounds. The resonances of the 0-alkylation products appear in three distinct bands which can be assigned to alkyl aryl ethers, alkyl aryl ethers with substituents at the adjacent positions, and to alkyl carboxylates. The ratio of ethers to carboxylates in the soluble alkylation products was determined to be 7.8 for butylation and 8.0 for methylation. The Chromatographic fractions contain different amounts of C-, N-, and 0-alkylation products. This finding suggests that the coal structure is not highly uniform. 相似文献
24.
The reductive alkylation of Illinois No. 6 coal was investigated using alkali metals and alkyl halides in liquid ammonia. Potassium is the most effective reducing agent and butyl iodide is the most effective alkylating agent for the preparation of coal alkylate that is soluble in tetrahydrofuran. The overall yield of soluble product is often improved through the reaction of the tetrahydrofuran-insoluble portion of the initial reaction products with an alkylating agent in the presence of tetrabutylammonium hydroxide. The infrared spectra of these materials suggest that the phase transfer agent catalyses the esterification of residual carboxylic acid functions. The intermolecular interactions between such acid groups and acceptor groups markedly restrict the solubility of the coal alkylate. The gel permeation chromatograms of the soluble reaction products are essentially featureless with only modest maxima at short and long elution volumes. The proton and carbon nuclear magnetic resonance spectra of the reductive methylation products, prepared using methyl-13C iodide, suggest that carbon alkylation exceeds oxygen alkylation and that the alkylation of phenolic groups is the dominant O-alkylation reaction. The spectra also suggest that fewer ethers are cleaved in the reaction in liquid ammonia than under the conditions of the Sternberg reaction. 相似文献
25.
Ruthenium tetroxide selectively oxidizes activated aromatic compounds under mild conditions and has been used for the catalytic oxidation of several different coals. The quantities of the volatile monocarboxylic acids with 2–6 carbon atoms have been determined by an isotope dilution technique. The amount of ethanoic acid ranges from 1 to 3mol/100C and the quantities of propanoic acid, and butanoic acid exceed 0.1 mol/100C. Methylpropanoic, pentanoic, 2-methylbutanoic, 3-methylbutanoicand hexanoic acid are formed in lesser amounts. The outcome of the experiment depends upon whether or not the coal has been extracted prior to oxidation. The results for Illinois No. 6 coal expressed in moles of ethanoic acid produced/l00C illustrate this feature: raw whole coal, 1.9; coal extracted by the method of Hayatsu and co-workers, 1.0. Dehydrogenation with benzoquinone prior to oxidation increases the yield of ethanoic acid to The amounts of ethanoic acid obtained from the other extracted coals are 1.0 for Texas lignite, 1.2 for Rawhide subbituminous, 3.4 for Pittsburgh No. 8, 3.3 for a higher ranking bituminous coal (PSOC 726) and 0.7 for an anthracite (PSOC872). The results obtained in this study are compared with related information concerning the distribution of alkyl groups within coal by other methods. 相似文献
26.
Renata FurtunaSilvia Curteanu Florin Leon 《Engineering Applications of Artificial Intelligence》2011,24(5):772-785
This paper presents an original software implementation of the elitist non-dominated sorting genetic algorithm (NSGA-II) applied and adapted to the multi-objective optimization of a polysiloxane synthesis process. An optimized feed-forward neural network, modeling the variation in time of the main parameters of the process, was used to calculate the vectorial objective function of NSGA-II, as an enhancement to the multi-objective optimization procedure. An original technique was utilized in order to find the most appropriate parameters for maximizing the performance of NSGA-II. The algorithm provided the optimum reaction conditions (reaction temperature, reaction time, amount of catalyst, and amount of co-catalyst), which maximize the reaction conversion and minimize the difference between the obtained viscometric molecular weight and the desired molecular weight. The algorithm has proven to be able to find the entire non-dominated Pareto front and to quickly evolve optimal solutions as an acceptable compromise between objectives competing with each other. The use of the neural network makes it also suitable to the multi-objective optimization of processes for which the amount of knowledge is limited. 相似文献
27.
J. Ponce de Leon 《Gravitation and Cosmology》2009,15(4):345-352
We study the effective spacetimes in lower dimensions that can be extracted from a multidimensional generalization of the
Schwarzschild-Tangherlini spacetimes derived by Fadeev, Ivashchuk, and Melnikov (Phys. Lett. A 161, 98 (1991)). The higher-dimensional spacetime has D = (4 + n + m) dimensions, where n and m are the number of “internal” and “external” extra dimensions, respectively. We analyze the effective (4 + n) spacetime obtained after dimensional reduction of the m external dimensions. We find that when the m extra dimensions are compact (i) the physics in lower dimensions is independent of m and the character of singularities in higher dimensions, and (ii) the total gravitational mass M of the effective matter distribution is less than the Schwarzschild mass. In contrast, when the m extra dimensions are large, this is not so; the physics in (4 + n) does explicitly depend on m as well as on the nature of singularities in high dimensions, and the mass of the effective matter distribution (with the
exception of wormhole-like distributions) is larger than the Schwarzschild mass. These results may be relevant to observations
for an experimental/observational test of the theory. 相似文献
28.
Stephen J.H. Yang Jia Zhang Leon Lin Jeffrey J.P. Tsai 《Expert systems with applications》2009,36(7):10312-10324
As a large amount of information is added onto the Internet on a daily basis, the efficiency of peer-to-peer (P2P) search has become increasingly important. However, how to quickly discover the right resource in a large-scale P2P network without generating too much network traffic remains highly challenging. In this paper, we propose a novel P2P search method, by applying the concept of social grouping and intelligent social search; we derive peers into social groups in a P2P network to improve search performance. Through a super-peer-based architecture, we establish and maintain virtual social groups on top of a P2P network. The interactions between the peers in the P2P network are used to incrementally build the social relationships between the peers in the associated social groups. In such a P2P network, a search query is propagated along the social groups in the overlay social network. Our preliminary experiments have demonstrated that our method can significantly shorten search routes and result in a higher peer search performance. In addition, our method also enhances the trustworthiness of search results because searches go through trusted peers. 相似文献
29.
30.
This study employs expectancy theory to evaluate some key factors that motivate students to participate in the teaching evaluation process. The results show that engineering students generally consider the improvement of teaching to be the most important outcome of teaching evaluations, followed by the improvement of course content and format. Making the results of evaluations available for students' decisions on course and instructor selection ranked third, while the least important use was influencing a professor's tenure, promotion, and salary raise. Students' motivation to participate in teaching evaluations is also impacted significantly by their expectation that they will be able to provide meaningful feedback. 相似文献