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81.
Lisa J. Lobree In‐Chul Hwang Jeffrey A. Reimer Alexis T. Bell 《Catalysis Letters》1999,63(3-4):233-240
The interactions of NO, O2 and NO2 with Fe‐ZSM‐5, as well as the reduction of NO by C3H8 in the presence of O2, have been investigated using in situ infrared spectroscopy. The sample of Fe‐ZSM‐5 (Fe/Al =0.56) was prepared by solid‐state
ion exchange. NO adsorption in the absence of O2 produces only mono‐ and dinitrosyl species associated with Fe2+ cations. Adsorbed NO2/NO3 species are formed via the reaction of adsorbed O2 with gas‐phase NO or by the adsorption of gas‐phase NO2. The reduction of NO in the presence of O2 begins with the reaction of gas‐phase C3H8 with adsorbed NO2/NO3 species to form a nitrogen‐containing polymeric species. A reaction pathway is proposed for the catalyzed reduction of NO
by C3H8 in the presence of O2.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
82.
Micellar Growth in Cetylpyridinium Chloride/Alcohol System: Role of Long Chain Alcohol,Electrolyte and Surfactant Head Group 下载免费PDF全文
Jasila Karayil Sanjeev Kumar Yeshayahu Talmon P. A. Hassan B. V. R. Tata Lisa Sreejith 《Journal of surfactants and detergents》2016,19(4):849-860
The microstructural transition of aqueous 0.1 M cetylpyridinium chloride (CPC) in the combined presence of salt KBr and long chain alcohol (C9OH-C12OH) has been studied as a function of alcohol concentration, electrolyte concentration and temperature. The viscosity of the CPC/KBr micellar system showed a peaked behavior with alcohol concentration (C 0), due to alcohol induced structural transition, which was confirmed by dynamic light scattering (DLS) and rheological analysis. Besides C 0, the chain length of alcohol (n) was found to show a remarkable effect on the micellization behavior of CPC/KBr system. It was observed that the ability of alcohol to induce micelle growth diminishes with n, which was well supported by viscosity, rheology and DLS measurements. To examine the effect of the electrolyte on the micellar growth, the salt concentration was varied from 0.05 to 0.15 M and it was observed that with increase in [KBr], the peak position shifts towards lower C 0. The effect of temperature on the micellar system showed interesting phase behavior for CPC/KBr/Decanol. The system exhibited a closed solubility loop with an upper critical solution temperature (UCST) > the lower critical solution temperature (LCST), reminiscence of nicotine-water system. The role of surfactant head group on the structural evolution was revealed by comparing the present results with our previous report for similar micellar system, CTAB/KBr/long chain alcohol. 相似文献
83.
Horizontal Dip‐Spin Casting of aqueous alumina‐polyvinylpyrrolidone suspensions with chopped fiber 下载免费PDF全文
Valerie Wiesner Manuel Acosta Lisa Rueschhoff Jeffrey Youngblood Rodney Trice 《International Journal of Applied Ceramic Technology》2017,14(6):1077-1087
A novel ceramic processing method, called Horizontal Dip Spin Casting (HDSC), enabled fabrication of tubular ceramic parts with an aligned chopped fiber phase. HDSC was demonstrated using highly loaded aqueous alumina suspensions with >50 vol.% solids loading and ≤5 vol.% water‐soluble polymer employed as a rheological modifier. Chopped carbon fibers were added to the suspensions to attain maximum loadings of 30 vol.%. During forming, cylindrical foam molds were dipped into the suspension while being rotated radially about the long axis. Simultaneously, a doctor blade was placed at a specified distance from the foam surface to facilitate the flow of the suspension to align the fiber and control the thickness of the material that accrued on the mold. Rheological study of alumina‐PVP suspensions with and without chopped carbon fiber showed that the suspensions exhibited a yield‐pseudoplastic flow behavior. The degree of alignment of the carbon fiber phase in the green bodies was characterized for various suspension formulations, carbon fiber contents and forming speeds. Stereological characterization of green body specimens confirmed the effectiveness of HDSC to attain the desired tubular geometry with considerable fiber alignment for a suspension composition containing ≤20 vol.% chopped fibers. 相似文献
84.
Robert G. Jensen F. A. Dejong R. M. Clark Lisa G. Palmgren Teresa H. Liao Margit Hamosh 《Lipids》1982,17(8):570-572
The lingual lipase in gastric aspirates from premature infants was found to be partially stereospecific forsn-3 esters of synthetic enantiometric triacylglycerols containing 18∶1 and 16∶0. Thesn-3 ester was hydrolyzed about 4 times faster than the acid at thesn-1 position with no difference in rates between 18∶1 and 16∶0. Thesn-2 was also hydrolyzed to some extent.
Scientific contribution no. 949, Storrs Agricultural Experiment Station, University of Connecticut, Storrs, Ct 06268. 相似文献
85.
Continuous α-Fe2 O3 films grown on bulk (0001)Al2 O2 substrates by low-pressure chemical vapor deposition have been studied by transmission electron microscopy and the observations compared to those obtained from discontinuous films at an earlier stage of the growth process. Plan-view specimens revealed significant thermal stress in the continuous films, while cross-sectional specimens showed that cracking occurs in thicker films. The free surface of the film and the film/substrate interface appeared sharp and flat, apart from growth ledges and steps. Weak-beam imaging revealed a hexagonal misfit dislocation network consisting of perfect edge dislocations. Fine structure in the selected-area diffraction patterns which corroborates these observations is also discussed. The misfit network of partial dislocations previously observed in the discontinuous films was not observed for the continuous films, indicating an effect of film thickness, growth rate, or surface preparation on the Fe2 O3 /(0001)Al2 O3 interface structure. 相似文献
86.
Non‐aqueous extraction of bitumen from oil sands has the potential to reduce fresh water demand of the extraction process and eliminate tailings ponds. In this study, different light hydrocarbon solvents, including aromatics, cycloalkanes, biologically derived solvents and mixtures of solvents were compared for extraction of bitumen from Alberta oil sands at room temperature and ambient pressure. The solvents are compared based on bitumen recovery, the amount of residual solvent in the extracted oil sands tailings and the content of fine solids in the extracted bitumen. The extraction experiments were carried out in a multistage process with agitation in rotary mixers and vibration sieving. The oil sands tailings were dried under ambient conditions, and their residual solvent contents were measured by a purge and trap system followed by gas chromatography. The elemental compositions of the extraction tailings were measured to calculate bitumen recovery. Supernatants from the extraction tests were centrifuged to separate and measure the contents of fine solid particles. Except for limonene and isoprene, the tested solvents showed good bitumen recoveries of around 95%. The solvent drying rates and residual solvent contents in the extracted oil sands tailings correlated to solvent vapour pressure. The contents of fine solids in the extracted bitumen (supernatant) were below 2.9% for all solvents except n‐heptane‐rich ones. Based on these findings, cyclohexane is the best candidate solvent for bitumen extraction, with 94.4% bitumen recovery, 5 mg of residual solvent per kilogram of extraction tailings and 1.4 wt% fine solids in the recovered bitumen. © 2012 Canadian Society for Chemical Engineering 相似文献
87.
Thines NJ Shipley LA Bassman JH Fellman JK Mattison DS Slusser JR Gao W 《Journal of chemical ecology》2007,33(5):1025-1039
Ultraviolet-B (UV-B) radiation has been increasing in temperate latitudes in recent decades and is expected to continue rising
for some time. Enhanced UV-B radiation can change plant chemistry, yet the effects of these changes on mammalian herbivores
are unknown. To examine the influence of enhanced UV-B radiation on nutrition of a specialist and generalist hindgut fermenter,
we measured nutritional and chemical constituents of three common North American range plants, big sagebrush (Artemisia tridentata), yarrow (Achillea millefolium), and bluebunch wheatgrass (Pseudoregneria spicata), and how these changes influenced in vitro dry matter digestibility and in vivo digestibility by pygmy rabbits (Brachylagus idahoensis) and eastern cottontails (Sylvilagus floridanus). Forages were irradiated for 3 mo with ambient (1×) or supplemental (1.6×) UV-B radiation representing a 15% ozone depletion
for Pullman, WA, USA. Enhanced UV-B radiation had minimal effects on the nutritional content and the tannin-binding capacity
of forages. Similarly, the terpene concentration in sagebrush and yarrow was not affected by higher UV-B irradiances. Flavonoid
compounds increased in sagebrush but decreased in yarrow. Rabbit preference and intake was not affected by treatment levels
for any forage species and no differences were found between treatments for dry matter, fiber, protein digestibility, and
apparent digestible energy. 相似文献
88.
Benign route for the modification and characterization of poly(lactic acid) (PLA) scaffolds for medicinal application 下载免费PDF全文
Scaffolds fabricated from polymers have imprinted its wide applicability in the field of tissue engineering. The surface of electrospun poly(lactic acid) (PLA) nanofibers was modified to improve their compatibility with living medium. PLA film were treated with alkali solution to introduce carboxyl groups on the surface followed by covalent grafting of gelatin using Xtal Fluoro‐E as coupling agent. The gelatin g‐PLA polymer synthesized via ‘graft‐onto’ method exhibit fascinating properties as studied by contact angle measurement, fourier transformed infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy, water vapor transmission rate(WVTR), swelling studies and differential scanning calorimetry. The fabricated gelatin g‐PLA scaffolds were further characterized to conduct the study on hydrolytic degradation, and extent of biodegradation at ambient temperature. It was observed from the in‐vitro analysis that the gelatin g‐PLA nanofiber (with hemolytic percentage, 0.56 ± 0.13%) was cytocompatible with fibroblast cell and does not impair cell growth. The WVTR obtained for the electrospun mat around 2900 ± 100 g/m2. 24 h signifies the optimal moist environment required for tissue engineering especially wound healing. Notably, many of these strategies resulted in porous hydrophilic scaffolds with human cell growth and proliferation for medical applications of various types. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46056. 相似文献
89.
Erica Costantini Lisa Aielli Federica Serra Lorenzo De Dominicis Katia Falasca Pamela Di Giovanni Marcella Reale 《International journal of molecular sciences》2022,23(4)
Wound healing (WH) proceeds through four distinct phases: hemostasis, inflammation, proliferation, and remodeling. Impaired WH may be the consequence of the alteration of one of these phases and represents a significant health and economic burden to millions of individuals. Thus, new therapeutic strategies are the topics of intense research worldwide. Although radiofrequency electromagnetic field (RF-EMF) has many medical applications in rehabilitation, pain associated with musculoskeletal disorders, and degenerative joint disorders, its impact on WH is not fully understood. The process of WH begins just after injury and continues during the inflammatory and proliferative phases. A thorough understanding of the mechanisms by which RF-EMF can improve WH is required before it can be used as a non-invasive, inexpensive, and easily self-applicable therapeutic strategy. Thus, the aim of this study is to explore the therapeutic potential of different exposure setups of RF-EMF to drive faster healing, evaluating the keratinocytes migration, cytokines, and matrix metalloproteinases (MMPs) expression. The results showed that RF-EMF treatment promotes keratinocytes’ migration and regulates the expression of genes involved in healing, such as MMPs, tissue inhibitors of metalloproteinases, and pro/anti-inflammatory cytokines, to improve WH. 相似文献
90.
Maria Lisa Garavaglia Daniela Giustarini Graziano Colombo Francesco Reggiani Silvia Finazzi Marta Calatroni Lucia Landoni Nicola Marcello Portinaro Aldo Milzani Salvatore Badalamenti Ranieri Rossi Isabella Dalle-Donne 《International journal of molecular sciences》2022,23(5)
Thiols (sulfhydryl groups) are effective antioxidants that can preserve the correct structure of proteins, and can protect cells and tissues from damage induced by oxidative stress. Abnormal levels of thiols have been measured in the blood of patients with moderate-to-severe chronic kidney disease (CKD) compared to healthy subjects, as well as in end-stage renal disease (ESRD) patients on haemodialysis or peritoneal dialysis. The levels of protein thiols (a measure of the endogenous antioxidant capacity inversely related to protein oxidation) and S-thiolated proteins (mixed disulphides of protein thiols and low molecular mass thiols), and the protein thiolation index (the molar ratio of the S-thiolated proteins to free protein thiols in plasma) have been investigated in the plasma or red blood cells of CKD and ESRD patients as possible biomarkers of oxidative stress. This type of minimally invasive analysis provides valuable information on the redox status of the less-easily accessible tissues and organs, and of the whole organism. This review provides an overview of reversible modifications in protein thiols in the setting of CKD and renal replacement therapy. The evidence suggests that protein thiols, S-thiolated proteins, and the protein thiolation index are promising biomarkers of reversible oxidative stress that could be included in the routine monitoring of CKD and ESRD patients. 相似文献