真空辅助成型工艺(VARI)研究

VARI在低成本成型工艺中起着很重要的作用，本文将介绍它的特点、制造、性能以及在国内外的应用。     

[Cu_2(Gly—GlyO)_2(OH)_2(4,4—bpy)]·9H_2O配合物合成、晶体结构研究

采用Gly—GlyOH,4,4＇—联吡啶与Cu(NO_3)_2·H_2O在二次水溶液中反应,合成出以4,4＇—bpy为中继基,Gly—Glyo为螯环新型双核铜配合物。经X射线单晶结构分析确定该配合物品体的化学结构式:[(H_2NCH_2CONHCH_2COO) Cu(OH) (C_(10)H_8N_2)Cu(OH) (H_2NCH_2CONHCH_2COO)]·9H_2O.晶体属于三斜晶系,P_空间群,晶胞参数a=1.1412nm,b=1.2298nm,C=1.4269nm,α=113.82°,β=101.91°,y=103.64°,V=1.6747nm~3,Z=2。衍射数据是在Nicolet XRD R3型四圆衍射仪上收集,结构参数经块矩阵最小二乘法精修后,最终一致性因子R值为0.068,RW值为0.057。     

Vinyl‐containing silicone resin as the crosslinking agent of heat‐curable silicone rubber

Heat‐curable silicone rubber (HCSR) was prepared by using vinyl‐containing silicone resin (VSR) as the crosslinking agent instead of polyvinylsilicone oil (C gum). Mechanical properties and crosslink density of the vulcanizates were measured. The results indicate that VSR is a good crosslinking agent for HCSR. The tensile strength, tearing strength, elongation at break, and hardness of the vulcanizate can reach 10.2 MPa, 29.1 kN/m, 720%, and 58 SHA, respectively. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 3123–3127, 2002; DOI 10.1002/app.10054     

以显微荧光检验法检测常用盖印材料

显微荧光检验法是显微检验的一个重要角度,由于缺少基础性研究,这一方法在文件检验中的运用并不广泛.着重考虑曝光时间这一因素,以盖印材料的荧光特性为观察角度,运用显微荧光检验法对大量常用盖印材料进行系统、全面的观察和研究.研究表明,绝大部分盖印材料可被激发出荧光,每种盖印材料的荧光特性都有各自的规律性特点.     

Morphologies-Controlled Synthesis and Optical Properties of Bismuth Tungstate Nanocrystals by a Low-Temperature Molten Salt Method

Well-crystallized bismuth tungstate (Bi₂WO₆) powders with different morphologies were successfully synthesized via a low-temperature molten salt method. The powders were characterized by X-ray diffraction, transmission electron microscopy, and UV-Vis, respectively. It was found that the variation of morphology of the obtained Bi₂WO₆ powder mainly depends on the different reaction temperatures and the weight ratio of LiNO₃–NaNO₃ salt to precursor. In addition, the UV-Visible absorption spectra showed that the synthesized powders had strong light absorption properties not only in the ultraviolet light but also in the visible light region.     

The extrusion of polymers below their melting temperatures by the application of high pressures

A number of polymers have been “cold” extruded (i.e. at temperatures well below their normal melting temperatures) by the application of relatively high pressures. In all cases extrudates of relatively large cross-sectional area have been produced, and non-circular cross-sections have also been extruded. The extruded products has been evaluated and the results discussed. In general it has been found that whilst extrusion gives an oriented product, the increase in tensile modulus is much less than for a comparably drawn fibre. This phenomenon has been discussed in terms of the changes in crystalline structure produced by extrusion.     

Nanocrystalline CeO2 in SBA-15: Performance of Pt/CeO2/SBA-15 Catalyst for Water-gas-shift Reaction

CeO₂ particles confined within the pores of an SBA-15 mesoporous silica host were prepared by incipient wetness impregnation (IMP) and deposition precipitation (DP) methods. The materials were characterized by XRD, N₂-adsorption and temperature programmed reduction (TPR) to evaluate the structure, texture, and redox properties. The preparation procedure had significant impact on the assembling mode of CeO₂ inside the SBA-15 mesopores. A high dispersion of CeO₂ particles was achieved via DP, whereas the dispersion of CeO₂ prepared by IMP was found to be inhomogeneous and CeO₂ partially blocked the pores. The CO conversion in the water-gas-shift reaction was enhanced over 1 wt% Pt supported on CeO₂-modified SBA-15 obtained by DP.     

Study of different effect on foaming process of biodegradable bionolle in supercritical carbon dioxide

Microcellular foaming of biodegradable Bionolle in supercritical CO₂ has been produced. The effects of a series of variable factors, such as saturation temperature, saturation pressure, and depressurization time and step on the foam structures and density, were studied through measurement of density and SEM observation. The experimental results show that higher saturation temperatures lead to an increase in bulk densities; and different depressurization time and step result in different product cell morphology. In addition, at some saturation temperature, the orientation of the cells can be found in the product morphology. XRD experimental results show that the foaming treatment with SC CO₂ increased the crystallinity of Bionolle. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2901–2906, 2006     

英汉情感隐喻的共性与差异

为进一步了解情感隐喻的实质,以人类基本情感的隐喻表达作讨论对象,对英汉语言中的基本情感隐喻进行共性与差异分析。     

VR技术对地下步行商业街心理环境辅助设计初探

文章力图以VR（虚拟现实）技术手段应用于城市地下步行商业街规划设计,来解决当前传统规划手段地下步行商业街规划中普遍存在的对其心理环境构筑的忽视和考虑不完善的诟病,以期最大限度消除规划设计中消极空间的产生,并对其关键技术进行了研究和探讨