Coke Formation on Pt?CSn/Al2O3 Catalyst in Propane Dehydrogenation: Coke Characterization and Kinetic Study

The influences of gas compositions on the rates of coke formation over a Pt?CSn/Al₂O₃ catalyst are studied. The coke formed on the catalyst is characterized by thermal gravimetric analysis, IR spectroscopy, Raman spectroscopy and elemental analysis. Two kinds of coke are identified from the TPO profiles and assigned to the coke on the metal and the coke on the support, respectively. The coke formed on the metal is softer (containing more hydrogen) than that formed on the support. The rate of coke formation on the metal is weakly dependent on the propylene and hydrogen pressures but increasing with the propane pressure, while the rate of coke formation on the support is increasing with the propane and propylene pressures and decreasing with the hydrogen pressure. Based on the kinetic analysis, a mechanism for the coke formation on the Pt?CSn/Al₂O₃ catalyst is proposed, and the dimerization of adsorbed C₃H₆ is identified to be the kinetic relevant step for coke formation on the metal.     

多孔阳极氧化铝表面的润湿性能

在10%体积分数的磷酸溶液中进行阳极氧化得到多孔阳极氧化铝(PAA),在PAA表面修饰低表面能物质得到疏水性良好的表面.研究了在不同的阳极氧化及后期工艺条件下,PAA表面润湿性能的变化.结果表明:该方法可以得到接触角为155°的超疏水表面;试样粗糙度对多孔阳极氧化铝的润湿性有影响,粗糙度越小,所得到的试样镀膜后的接触角越大;纳米孔的直径大小是影响多孔氧化铝膜润湿性的重要因素,在一定直径范围内(160～190 nm之间)的氧化膜疏水性最好;大于1.7 μm的膜厚即能调节表面润湿性,恒压或恒流状态对接触角的影响较小.     

利用DS1302实现时间锁定及密码保护功能

引 言 DS1302时钟芯片功能强、功耗低,可以提供年、月、日、时、分、秒及带闰年补偿等信息.它内部有一个31字节RAM的高速数据暂存器,工作电压在2.0～5.5 V范围内选择.它与时钟/RAM间的通信仅需3根线: RST(复位)、I/O(数据线)和SCLK(串行时钟).     

基于非常稀疏随机投影的图像重建方法

将非常稀疏随机投影引入可压缩传感CS（Compressed Sensing）理论,提出一种新的CS测量矩阵：非常稀疏投影矩阵。利用非常稀疏投影分布的渐近正态性,证明了新的矩阵满足CS测量矩阵的必要条件。该矩阵由于其构成的非常稀疏性大大简化了图像重建过程中的投影计算,从而提高重建速度。实验结果表明非常稀疏投影矩阵在满足一定测量数目要求的条件下可以精确重建。最后给出了新的测量矩阵与一般采用的高斯和贝努里测量矩阵的重建结果比较和分析。     

碱／表面活性剂复合驱油体系与胜利孤东原油间协同效应的研究

考察了碱／非离子表面活性剂ＯＰ１０＋石油磺酸盐Ｃｙ体系与胜利孤东原油及萃取其酸性组分后的剩余油间的动态界面张力特性，发现复合驱油体系中的外加表面活性剂、碱与原油原位生成的表面活性物质之间存在明显的协同效应。这种协同效应对低离子强度下短时间内的界面张力影响较大；外加表面活性剂对高离子强度下长时间的界面张力影响较大。动态界面张力的最低值与界面上各表面活性物质的浓度和比值有着十分重要的关系     

基于各向异性Gibbs随机场与高斯混合模型的脑MR图像分割算法

为了克服高斯混合模型(GMM)的局限性,利用 Gibbs 理论和图像结构信息构造各向异性 Gibbs 随机场,并将其引入到 GMM 框架中,完善 GMM 的分类效果,使其在克服噪声影响的同时,还能够保持细长拓扑结构区域信息以及角点区域信息.实验结果证明,文中算法可以得到较好的分类结果.     

综合自适应阈值与多尺度的TV图像修复方法

基于TV模型的图像修复算法具有较好的修复效果,但其对参数的选取较敏感,且运算量较大。该文提出了一种综合自适应阈值与多尺度的TV图像修复算法,该方法不仅可以提高TV图像修复模型的修复稳定性,还可以进一步压缩运算量,提高修复速度。     

DMD全息系统重构灰度级分数傅立叶全息图

论文提出一种基于DMD投影系统的全息重构系统,用VC++实现分数傅立叶变换全息图生成平台并生成灰度全息图,由DMD全息系统实现灰度级分数傅立叶变换全息图重构,验证了DMD全息系统的可行性。此系统可为动态全息显示提供硬件基础。     

射孔防砂技术在桩西馆陶组油藏开发中的应用

桩西馆陶组油藏物性较差,地层胶结疏松,易出砂,开发效率低,部分井因地层能量不足伴随出砂等情况,导致防砂后地层严重供液不足,影响了油井的正常生产。为提高桩西油区馆陶组油藏的开发水平,进行了射孔防砂工艺的优化研究与应用,采取增孔疏通近井地带后再防砂工艺技术,取得了较好的效果。     

Small Molecule Compounds of Natural Origin Target Cellular Receptors to Inhibit Cancer Development and Progression

Receptors are macromolecules that transmit information regulating cell proliferation, differentiation, migration and apoptosis, play key roles in oncogenic processes and correlate with the prognoses of cancer patients. Thus, targeting receptors to constrain cancer development and progression has gained widespread interest. Small molecule compounds of natural origin have been widely used as drugs or adjuvant chemotherapeutic agents in cancer therapies due to their activities of selectively killing cancer cells, alleviating drug resistance and mitigating side effects. Meanwhile, many natural compounds, including those targeting receptors, are still under laboratory investigation for their anti-cancer activities and mechanisms. In this review, we classify the receptors by their structures and functions, illustrate the natural compounds targeting these receptors and discuss the mechanisms of their anti-cancer activities. We aim to provide primary knowledge of mechanistic regulation and clinical applications of cancer therapies through targeting deregulated receptors.