Liquid limit of low- to medium-plasticity soils: comparison between Casagrande cup and cone penetrometer test

For liquid limit determination, the European Standards require the cone penetrometer technique or, alternatively, the Casagrande cup method; but the latter is widely used in practice. As most European soil classification systems are not adapted to the new European Standards, a systematic study was carried out to verify the differences between the two techniques for liquid limit determination, examining clayey soils from various geologic units. Comparison of 100 liquid limit values ranging between 20 and 50% indicates that the liquid limit obtained by the fall cone method is generally 2.2% points higher than that obtained by the hard base Casagrande apparatus. Comparison of data from different sources consistently indicates that the equation proposed in this study may be useful in revising existing soil classification systems, avoiding problems of soil classification due to the technique used for liquid limit determination.     

A theoretical model of the relationship between the <Emphasis Type=Italic>h</Emphasis>-index and other simple citation indicators

In this study, we quantitatively compared the impact of mission-oriented research grants and curiosity-driven grants on the diversity of research subjects in Japan. First, we examined data for Japanese principal investigators receiving research funding between 2000 and 2010 in the field of nanotechnology and materials science, and identified groups of researchers whose publication performance was positively affected by the mission-oriented grant, CREST. We then compared the effect of CREST with that of the curiosity-driven grant, KAKENHI. The analysis uses both propensity score matching and difference in differences (PSM-DID) methodologies. Our results show that for participants in the CREST program there was an increase in number of publications of more than 10% per year, for periods of both 5 and 3 years after the funding ended, even though the observed average effect on citation was not statistically significant. Second, we evaluated the diversity of research subjects through analysis of the distribution of the classification codes applied to articles published between 1996 and 2013, utilizing the J-Global database, which has the finest granularity of category among existing bibliographic scientific publication databases. Research subjects were better conserved under the mission-oriented program than the curiosity-driven one, a finding contrary to predictions of conventional theory. We also found that under mission-oriented funding, there was an increase in diversity in the sense of marginal utility. These findings should be of use in the “diversity-aware” design of programs for the funding of fundamental research.     

Ion beam analysis of partial lithium extraction of LiMn2O4 by chemical delithiation

Lithium manganese oxide, LiMn₂O₄, has been studied by many research groups. This material is a great candidate to be used as positive electrode in rechargeable lithium-ion batteries because of its low cost, abundant precursors and non-toxicity. LiMn₂O₄ has a spinel Fd-3m structure and shows a reversible extraction and insertion of lithium ions that is one of the most important characteristic of positive electrodes in rechargeable batteries.In this work, LiMn₂O₄ samples were synthesized by solid state reaction. A partial lithium removal was performed on this system by chemical delithiation using HCl aqueous solutions at different concentrations. Six partial-extracted compounds were obtained and characterized by Ion beam analysis (IBA) in order to obtain the Li concentrations. X-ray diffraction (XRD) and Rietveld analyses were also performed. A rigorous study of lithium contents is critical to analyze the structure properties of these compounds and samples production parameters. The IBA method used in this work was the analysis of energy spectra of elastic backscattered (EBS) proton from Mn, O and Li nuclei and the α-particles energy from the ⁷Li(p,α)⁴He nuclear reaction (NR).     

Differential ionisation measurements for positron impact

An overview of methods being used at the University of Missouri-Rolla to measure differential ionisation for positron impact is presented. Examples of triply differential electron emission and doubly differential positron scattering and energy loss data are given and contributions to each due to binary and recoil events are discussed. In addition, angular distribution data for electron emission due to double and triple ionisation are presented.     

Truncated Analogues of a G-Quadruplex-Forming Aptamer Targeting Mutant Huntingtin: Shorter Is Better!

Two analogues of the MS3 aptamer, which was previously shown to have an exquisite capability to selectively bind and modulate the activity of mutant huntingtin (mHTT), have been here designed and evaluated in their physicochemical and biological properties. Featured by a distinctive propensity to form complex G-quadruplex structures, including large multimeric aggregates, the original 36-mer MS3 has been truncated to give a 33-mer (here named MS3-33) and a 17-mer (here named MS3-17). A combined use of different techniques (UV, CD, DSC, gel electrophoresis) allowed a detailed physicochemical characterization of these novel G-quadruplex-forming aptamers, tested in vitro on SH-SY5Y cells and in vivo on a Drosophila Huntington’s disease model, in which these shorter MS3-derived oligonucleotides proved to have improved bioactivity in comparison with the parent aptamer.     

A scalable method for run-time loop parallelization

Current parallelizing compilers do a reasonable job of extracting parallelism from programs with regular, well behaved, statically analyzable access patterns. However, they cannot extract a significant fraction of the avaialable, parallelism if the program has a complex and/or statically insufficiently defined access pattern, e.g., simulation programs with irregular domains and/or dynamically changing interactions. Since such programs represent a large fraction of all applications, techniques are needed for extracting their inherent parallelism at run-time. In this paper we give a new run-time technique for finding an optimal parallel execution schedule for a partially parallel loop, i.e., a loop whose parallelization requires synchronization to ensure that the iterations are executed in the correct order. Given the original loop, the compiler generatesinspector code that performas run-time preprocessing of the loop's access pattern, andscheduler code that schedules (and executes) the loop interations. The inspector is fully parallel, uses no sychronization, and can be applied to any loop (from which an inspector can be extracted). In addition, it can implement at run-time the two most effective transformations for increasing the amount of parallelism in a loop:array privatization andreduction parallelization (elementwise). The ability to identify privatizable and reduction variables is very powerful since it eliminates the data dependences involving these variables and An abstract of this paper has been publsihed in Ref. 1. Research supported in part by Army contract #DABT63-92-C-0033. This work is not necessarily representative of the positions or policies of the Army of the Government. Research supported in part by Intel and NASA Graduate Fellowships. Research supported in part by an AT&T Bell Laboratoroies Graduate Fellowship and by the International Computer Science Institute, Berkeley, California.     

Preparation by flame spray pyrolysis of ABO3±δ catalysts for the flameless combustion of methane

Perovskitic mixed oxides prepared through flame-spray pyrolysis possess a good stability in high-temperature application, viz. the catalytic flameless combustion of methane. Some preparation operating parameters are here analysed, such as O₂ pressure drop along the spraying nozzle, O₂ discharge velocity and flow rate. These parameters have been correlated with specific surface area, activity and durability of the prepared samples, as well as with flame temperature, varied by using different fuel mixtures. It was found that specific surface area increases with increasing O₂ velocity and flow rate and with decreasing the combustion enthalpy of the solvent mixture. This reflects on both activity and durability of the catalyst.     

Robust and quadratic stability via polytopic set covering

In this paper we consider the problem of covering the image of a given function by a polytope. This problem arises in both the robust and quadratic stability context. We present two main algorithms: the first one performs such a covering and works under quite general assumptions on the nature of the function; the second one is iterative and allows us to improve at will the goodness of the covering. The convergence properties of this algorithm are also discussed. Finally two examples of application of our techniques are presented.     

Comparison of nine common coffee extraction methods: instrumental and sensory analysis

The preparation of a cup of coffee may vary between countries, cultures and individuals. Here, an analysis of nine different extraction methods is presented regarding analytical and sensory aspects for four espressi and five lunghi. This comprised espresso and lungo from a semi-automatic coffee machine, espresso and lungo from a fully automatic coffee machine, espresso from a single-serve capsule system, mocha made with a percolator, lungo prepared with French Press extraction, filter coffee and lungo extracted with a Bayreuth coffee machine. Analytical measurements included headspace analysis with HS SPME GC/MS, acidity (pH), titratable acidity, content of fatty acids, total solids, refractive indices (expressed in °Brix), caffeine and chlorogenic acids content with HPLC. Sensory analysis included visual, aroma, flavor and textural attributes as well as aftersensation. The technical differences in the extraction methods led to a higher concentration of the respective quantities in the espressi than in the lunghi. Regarding the contents per cup of coffee, the lunghi generally had a higher content than the espressi. The extraction efficiency of the respective compounds was mainly driven by their solubility in water. A higher amount of water, as in the extraction of a lungo, generally led to higher extraction efficiency. Comparing analytical data with sensory profiles, the following positive correlations were found total solids ? texture/body, headspace intensity ? aroma intensity, concentrations of caffeine/chlorogenic acids ? bitterness and astringency.