溶液法制备高接枝率HDPE-g-MAH

用溶液法制备了HDPE -g -MAH,并讨论了单体、引发剂用量、反应温度、反应时间、投料方式等因素对产物接枝率的影响。     

氯乙酸生产工艺的改进与探讨

介绍了影响氯乙酸质量、消耗的因素,探讨了对氯乙酸工艺的改进措施。     

Cysteine adds to lipid hydroperoxide

Cysteine reacts with linoleic acid hydroperoxide to yield several products, some of which were identified as fatty acid-cysteine adducts. The addition was catalyzed by ferric chloride (10⁻⁵ M) by initiating free radical reactions. When isomerically pure 13-hydroperoxy-cis-9,trans-11-octadecadienoic acid and cysteine were reacted in 80% ethanol under N₂, the major adducts were 9-S-cysteine-13-hydroxy-10-ethoxy-trans-11-octadecenoic acid (I) and 9-S-cysteine-10,13-dihydroxy-trans-11-octadecenoic acid (II). When the reaction included both isomers of the hydroperoxide (13-and 9-hydroperoxide) and air, an adduct of 9-oxononanoic acid and cysteine also was isolated. Additional experiments gave information about possible mechanisms of I and II formation.     

玻璃钢筋混凝土的有限元计算与试验

钢筋混凝土广泛应用于土木工程领域，但其结构耐久性因钢筋本身的锈蚀成为现今急待解决的问题。人们一直在寻找对钢筋混凝土进行改良的途径，用玻璃钢筋代替普通钢筋是解决这一问题的一个有效的方法，为此进行了试验和ANSYS有限元分析，结果证明此法具有可行性。     

Lactobacillic and methyl-branched olefinic acids inByrsocarpus coccineus seed oil

A detailed investigation of the seed oil ofByrsocarpus coccineus Schum. and Thonn. has disclosedcis-11,12-methyleneoctadecanoic (lactobacillic) (13%) and two branched octadecenoic acids (0.1%). Other fatty acids in the oil are those normally associated with seed lipids except for an unusually high proportion (12%) ofcis-11-octadecenoic acid. Lactobacillic acid has long been known as a constituent of certain bacterial lipids, but this is the first report of its presence in a seed oil. The branched olefinic acids have not heretofore been found to occur in plants. Mention of firm names or trade products does not imply endorsement or recommendation by the Department of Agriculture over other firms or similar products not mentioned.     

用于光纤并带的UV固化胶粘剂性能的研究

研究了用于光纤带的紫外光固化胶粘剂的剥离性、柔韧性、拉伸强度和延伸率的影响因素。     

Palmitoleic acid inRoureopsis obliquifoliata (Connaraceae) Seed oil

Roureopsis obliquifoliata Schellenberg seeds contain an oil (45% by weight) comprised primarily of 16-carbon fatty acids. Palmitic acid constitutes 50% of the fatty acids, palmitoleic acid 32%, and small amounts of the usual C₁₈ acids make up the remainder. Identifications were based on Chromatographic properties of the acids and their ozonolysis products.     

Detection of spermaceti in a hand cream

The presence of spermaceti, an embargoed item, was confirmed in a sample of hand cream detained by federal agents. The identification was based on chromatographic characteristics of the intact wax esters and of their component fatty acids and alcohols. These acids and alcohols were combined in a manner so closely resembling spermaceti that they undoubtedly came from this source.     

Myristicin. The major volatile component in mature seed ofPortenschlagia ramosissima

Portenschlagia ramosissima (Port.) vis. (Umbelliferae) seed contains 15% essential oils, 70% of which is the aromatic ether myristicin. These structural assignments were made from nuclear magnetic resonance, combined gas chromatography-mass spectrometry (GC-MS), and infrared and ultraviolet data. GC-MS data also indicate the presence of pinene, cymene, terpinene, elemicin, methyl eugenol, and a variety of sesquiterpene hydrocarbons.     

氧化铝上吸附平衡与动力学的分形特性

在实验测定氧化铝吸附氮气的平衡和动力学过程的基础上 ,由平衡数据得到分形维数 ,对动力学结果分别用欧氏几何和分形几何的动力学模型进行处理 ,比较两种方法得到的扩散系数之间的差别。结果表明 :粉状氧化铝的分形维数为 2 .12 ;采用分形动力学模型得到的扩散系数同欧氏几何扩散模型的结果不一样 ,扩散系数不随浓度的变化而改变 ;而欧氏几何扩散模型中的扩散系数随浓度变化发生改变 ,且变化符合Darken关系