Sugar fatty acid ester surfactants: Base-catalyzed hydrolysis

Rate constants for the base-catalyzed hydrolysis of sucrose laurate, sucrose α-sulfonyl laurate, and sucrose α-ethyl laurate were measured at several temperatures in pH 11 buffer. Activation energies and Arrhenius factors for the hydrolysis reactions were determined. At 27°C, sucrose laurate hydrolyzed fastest and sucrose α-ethyl laurate slowest. Activation energies and Arrhenius factors showed that both steric and electronic factors affect the rates of ester hydrolysis. Other work has shown that bacterial hydrolysis of sugar fatty acid esters is inhibited in the presence of either α-sulfonyl or α-alkyl groups. A kinetic study of base-catalyzed ester hydrolysis has revealed reasons for the inhibition of bacterial hydrolysis and provided information regarding ester stability at elevated pH.     

Sugar fatty acid ester surfactants: Structure and ultimate aerobic biodegradability

Ultimate aerobic biodegradabilities of an array of sugar ester surfactants were determined by International Standards Organisation method 7827, “Water Quality—Evaluation in an Aqueous Medium of the Aerobic Biodegradability of Organic Compounds, Method by Dissolved Organic Carbon” (1984). The surfactants were nonionic sugar esters with different-sized sugar head groups (formed from glucose, sucrose, or raffinose) and different lengths and numbers of alkyl chains [formed from lauric (C₁₂) or palmitic (C₁₆) acid]. Analogous anionic sugar ester surfactants, formed by attaching an α-sulfonyl group adjacent to the ester bond, and sugar esters with α-alkyl substituents were also studied. It was found that variations in sugar head group size or in alkyl chain length and number do not significantly affect biodegradability. In contrast, the biodegradation rate of sugar esters with α-sulfonyl or α-alkyl groups, although sufficient for them to be classified as readily biodegradable, was dramatically reduced compared to that of the unsubstituted sugar esters. An understanding of the relationship between structure and biodegradability provided by the results of this study will aid the targeted design of readily biodegradable sugar ester surfactants for use in consumer products.     

Odor Detection in Insects: Volatile Codes

Insect olfactory systems present models to study interactions between animal genomes and the environment. They have evolved for fast processing of specific odorant blends and for general chemical monitoring. Here, we review molecular and physiological mechanisms in the context of the ecology of chemical signals. Different classes of olfactory receptor neurons (ORNs) detect volatile chemicals with various degrees of specialization. Their sensitivities are determined by an insect-specific family of receptor genes along with other accessory proteins. Whereas moth pheromones are detected by highly specialized neurons, many insects share sensitivities to chemical signals from microbial processes and plant secondary metabolism. We promote a more integrated research approach that links molecular physiology of receptor neurons to the ecology of odorants.     

Changes in the quality parameters of seedling tea due to height and frequency of mechanical harvesting

Quality parameters of black tea change due to the use of a mechanical harvester, varying plucking round lengths and plucking heights. Compared with hand plucking, mechanically harvested teas have inferior quality as measured by volatile flavour compounds, theaflavins and caffeine. Similarly, longer plucking rounds produced inferior teas compared with shorter rounds. Raising mechanical plucking height by 2 cm from the previous plucking height caused less quality deterioration than increasing the height by 1 cm irrespective of plucking rounds.     

Noise-shaping sense amplifier for MRAM cross-point arrays

A sensing technique using a voltage-mode architecture, noise-shaping modulator, and digital filter (a counter) is presented for use with cross-point MRAM arrays and magnetic tunnel junction memory cells. The presented technique eliminates the need for precision components, the use of calibrations, and reduces the effects of power supply noise. To obviate the effects of cell-to-cell variations in the array, a digital self-referencing scheme using the counter is presented. Measured experimental results in a 180-nm CMOS process indicate an RMS sensing noise of 20 /spl mu/V for a 5-/spl mu/s sense time. Further increases in sense time are shown to increase the signal-to-noise ratio. The current used by the sense amplifier and counter was measured as 10 /spl mu/A when running at 100 MHz or 10 mA when 1000 sense amplifiers are used with a memory subarray having 1000 bitlines.     

Prospective Reconciliation of Transmission Loss Cost in Alberta

One of the challenges in Alberta's deregulated electricity market is to recover transmission loss costs in a fair and equitable manner. The independent system operator (ISO), the Alberta Electric System Operator or AESO in Alberta, Canada, has introduced a new prospective methodology to reconcile the transmission loss revenue to loss cost on an annual basis since January 1, 2006. In the reconciliation process, a quarterly calibration factor (CF) is calculated to true up the difference between loss revenue and loss cost. The CF is defined as the percentage of the combined actual and forecasted difference in loss revenue and loss cost divided by the loss factor customer volumes and pool price. The focus behind this chosen methodology is to have a small CF in each quarter, a stable reconciliation pattern, and a small year-end difference. The new methodology has met these three goals in Alberta's deregulated electricity market.     

Influence of morphology on the behaviour of electrodes in a proton-conducting Solid Oxide Fuel Cell

SrCe_0.95Yb_0.05O₃ (SCY) and related materials are under consideration as a proton conductors for Solid Oxide Fuel Cell (SOFC) electrolytes. Sintered pellets of SCY are used to perform impedance spectroscopy (IS) studies and fuel cell tests on cells with Pt electrodes of two different morphologies. Electrodes are applied to the SCY pellets by two routes: either by firing on a layer of Pt paint (denoted electrode P) or by magnetron sputtering (electrode S). In impedance spectra recorded over a wide temperature range under humidified hydrogen, in symmetrical cell conditions, cells with S electrodes give rise to a much smaller low frequency impedance feature than the cells with P electrodes. This is tentatively attributed to faster diffusion-related processes taking place at the S electrodes. The behaviour of working fuel cells with S and P electrode morphologies is evaluated in terms of maximum power output and Area Specific Resistance in two-atmosphere tests. The fuel cell anode with the S morphology results in superior fuel cell performance, in agreement with the impedance study. The influence of the two different electrode morphologies on the behaviour of the cells is discussed with reference to their morphology, as determined by SEM and AFM.     

Lack of biological effects of water accommodated fractions of chemically- and physically-dispersed oil on molecular, physiological, and behavioral traits of juvenile snapping turtles following embryonic exposure

Snapping turtle (Chelydra serpentina) eggs were exposed to two concentrations of chemically- or physically-dispersed water accommodated fractions of weathered Arabian light crude oil (Low = 0.5 and High = 10 g oil/L water). Solutions were passed through nest substrate to simulate alterations in composition during percolation to egg depth. Hatchlings were raised for 13 months during which numerous endpoints were measured. Prior to percolation, total PAH (“tPAH”; the sum of 52 PAHs measured) in physically-dispersed oil fractions were similar (High, 43; Low 67 mg/L). Following percolation, tPAH was also similar in physically-dispersed fractions (High, 14; Low 24 mg/L). Addition of dispersant increased tPAH prior to percolation in the High treatment (302 mg/L) relative to Low (13 mg/L), but percolation resulted in nearly equal concentrations in both treatments (High, 30; Low, 22 mg/L) due to physical trapping of dispersed oil by the nest substrate. In both chemically- and physically-dispersed fractions, percolation reduced low molecular weight (MW) compounds such that embryos were exposed to primarily mid- to high MW compounds. Total PAH in eggs differed 15-fold between the chemically-dispersed High and physically-dispersed High treatments (560 and 36 µg/kg respectively), the former characterized by higher MW compounds than the latter. While eggs accumulated up to 560 µg/kg tPAH, we observed no effects on hatching success or hatchling/juvenile traits (DNA integrity, survival, growth, metabolism, energy storage, or behavior), our results demonstrate that PAH profiles are altered during percolation, suggesting that experiments with subsurface organisms should be designed to account for compositional changes that occur as the solutions percolate through the substrate.