Nucleation with Simultaneous Chemical Reaction in the Vapor-Phase Synthesis of AlN Ultrafine Powders

Using the classical (one-component) homogeneous nucleation theory approach of a constrained equilibrium distribution of sub- critical particles, a nucleation equation that considers the effect of heterogeneous reaction is derived for the AlN system. In the absence of more detailed information about the aluminum nitride (AlN) reaction kinetics, a simplified surface reaction model is formulated. Clusters, which can be formed by AlN and pure Al, are assumed to grow from the condensation of Al vapor followed by surface reaction between condensed Al and absorbed NH₃. The composition of any subcritical particle is assumed to be determined by the rates at which Al and AlN species are added to their surface and thus made entirely dependent upon local gas concentrations. This assumption resulted in important simplifications that allowed this development to be cast in a form resembling the one used by the classical theory for one-species nucleation. An analysis intended to evaluate the dependence of this nucleation equation on temperature, concentration of reacting species, and degree of aluminum supersaturation is presented. Considerable changes of the nucleation rate were observed between low and high concentration ratio of reacting species. These changes are directly related to the changes of the surface energy and bulk free energy terms determined as a function of the free-Al content in a nucleus.     

Modeling hourly electricity dynamics for policy making in long-term scenarios

Energy policies are often related to the global effort in reducing greenhouse gas emissions through increased use of renewable energies in electricity production. The impact of these policies is usually calculated by energy planning tools. However, the modeling methodologies most currently used are not adequate to simulate long-term scenarios while considering the hourly dynamics of supply and demand.     

Behavior of square and circular columns strengthened with aramidic or carbon fibers

The confinement of reinforced concrete (RC) columns with transverse reinforcement has been extensively studied and it is known that the response of concrete cylinders subjected to equivalent levels of pressure depends on how that lateral pressure is transmitted, and not on its magnitude alone. When confinement is, additionally to that given by steel stirrups, provided by external jackets of fiber reinforced polymers (FRP) the complexity and the scarcity of experimental data increase and tests to gain insight into the structural behavior and consequent design procedures are still required. The present study reports tests performed on axially loaded RC columns, with and without jackets. The FRP tested were made either of carbon fibers reinforced polymers (CFRP) or aramidic (AFRP) wraps and the geometry of the specimens included square and circular cross-sections. Comparison of gains of axial strength and ductility are presented and aspects of the variation of the lateral pressure and rupture of FRP jackets are examined.     

The comparison of the corrosion resistance of advanced ferromagnetic stainless steels by Mott–Schottky approach

Ferromagnetic stainless steels (SSs) have been investigated as potential candidates for dental prosthesis applications in replacement of magnetic attachments made of noble and expensive alloys. In order to be used as biomaterials, their corrosion resistance has to be appropriate. The corrosion resistance of passive materials is related to the characteristics of the passive film formed and their properties might be investigated by electrochemical impedance spectroscopy (EIS), potentiodynamic polarization curves, and Mott–Schottky approach. The corrosion resistance and the capacitance of the passive films formed on PM2000, DIN 1.4575, and 17‐4 PH advanced SSs during 2 days of immersion in a phosphate buffered saline solution (PBS), at 25 °C and pH 7.0 were studied by electrochemical techniques. A commercial alloy Dyna EFM was also analyzed for comparison reasons. The results showed that films on tested materials behave as both n‐type and p‐type semiconductors and the PM2000 presented the highest corrosion resistance among all of them.     

A conserved LIM protein that affects muscular adherens junction integrity and mechanosensory function in Caenorhabditis elegans

The glycosylation of the equine interhaemal barrier and areola was studied throughout the period of gestation. Placentae of 35, 37, 50, 119, 152, 200, 280 and 300 days gestation were investigated, using semithin plastic embedded sections and a panel of 15 biotinylated lectins with an avidin-peroxidase revealing system. Glycosylation of the trophoblast and maternal epithelium showed the most change during the first 50 days of gestation, being associated with the initial stages of adhesion and attachment. In the trophoblast, non-bisected tri/tetraantennary complex N-glycan was only evident after day 37 and terminal N-acetyl galactosamine, alpha2,3- and alpha2,6-linked sialic acids disappeared at the same time. The areolar trophoblast exhibited some differences from microcotyledonary areas, especially with respect to 2-deoxy, 2-acetamido alpha-galactose and tri/tetraantennary, non-bisected complex N-glycan, suggesting that the differences in function between microcotyledonary and areolar trophoblast are reflected at both the morphological and the biochemical level. Granules of the maternal uterine epithelium bound many lectins, particularly those with specificity for bisected and non-bisected bi/triantennary N-linked glycan, 2-deoxy, 2-acetamido alpha-galactosyl, beta-galactosyl and some fucosylated termini. Binding to sialic acids in alpha2,3- and alpha2,6-linkage was sparse. Maternal and fetal capillaries showed little change in glycan expression over the period studied, being rich in bisected and non-bisected bi/triantennary N-linked glycan and sialic acids, with some terminal N-acetyl galactosamine and no detectable terminal fucosyl residues.     

Biohydrometallurgical/UV production of ferrous sulphate heptahydrate crystals from pyrite present in coal tailings

The objective of this work was to develop a biohydrometallurgical/UV radiation route to produce ferrous sulphate heptahydrate (melanterite) from the pyrite present in coal tailings. The experimental work was carried out with a pyrite concentrate obtained from gravimetric processing of coal tailing. At laboratory scale it was performed the oxidation of pyrite in an aqueous medium in packed bed leaching columns in an oxidising environment with the presence of acidophilic bacteria (Acidithiobacillus ferrooxidans). The recirculation of the liquor allowed obtaining an iron-rich extract. The conversion of Fe³⁺ to Fe²⁺ was performed using ultraviolet irradiation (UV). Finally, the solution was evaporated allowing the formation of iron sulphate crystals. The results demonstrated that it is possible to produce high purity ferrous sulphate heptahydrate crystals using coal tailings as raw material.     

Variable-order fractional derivatives and their numerical approximations

This paper addresses the different possible definitions of variable-order derivatives and their numerical approximations; both approximations based upon the definitions and approximations consisting of non-linear transfer functions (in particular combining existing approximations of constant-order fractional derivatives, such as the Crone approximation, with fuzzy logic) are considered. There are different possible configurations, implementing variable-order fractional derivatives both with and without memory of past values of the time-dependent differentiation order.     

The influence of impurities on the acid-catalyzed reaction of glycerol with acetone

The acid-catalyzed reaction of glycerol with acetone was studied in the presence of impurities that might be present in the crude glycerin of biodiesel production. These are mainly methanol, water and sodium chloride, in different amounts. The results indicated that methanol has minor effect on the glycerol conversion, whereas the concomitant addition of water and sodium chloride produces a drastic decrease of the conversion. The nature of the acid catalyst also affects the conversion in the presence of impurities. Amberlyst-15™ acid resin is more sensible to the water content than zeolite Beta. The results of the glycerol adulteration with different contaminants were compared with the reaction using a crude glycerin from a Brazilian biodiesel industrial plant.