Controlled undercooling of liquid iron in contact with ZrO2 and MgO substrates under varying oxygen partial pressures

The objective of this study is to determine the conditions under which the inclusions present in liquid steel can act as heterogeneous nucleants for solidification. In order to study the factors that define the undercooling of a given metal/oxide couple, the undercooling of a pure iron sessile droplet in contact with Al₂O₃, ZrO₂, and MgO substrates was measured under controlled oxygen partial pressures by observing droplet recalescence. The results showed that the undercooling of iron, in contact with a particular substrate, did not have a unique value, but was significantly affected by the oxygen content on the gas phase. For oxygen partial pressures between 10⁻²¹ and 10⁻¹⁹, the undercooling of iron on ZrO₂ substrates was stable and around 290 °C. In the same range of oxygen partial pressure, the undercooling of iron on MgO substrates remained below 100 °C due to the low stability of this oxide. At lower oxygen contents, substrate decomposition might be the cause for the observed drop in the undercooling of iron on ZrO₂ substrates to below 100 °C. The undercooling also decreased for increasing oxygen content as verified when the gas was changed from gettered Ar/Ar-H₂ to CO/CO₂ mixtures. The variation in undercooling was related to the wetting of the substrate by the liquid metal, where the deep undercooling observed in the ZrO₂ experiments occurred when the highest contact angle between the liquid metal and the substrate was achieved.     

IPv6 delay and loss performance evolution

Although packet delay and loss are two important parameters of the Internet performance, to the best of our knowledge, the evolution of large‐scale IPv6 delay and loss performance has previously not been studied. In this paper, we analyze more than 600 end‐to‐end IPv6 paths between about 26 testboxes of RIPE Network Coordination Centre over two years, and compare the delay and loss performance over time with their IPv4 counterparts. We present and discuss the measurement methodologies and show that IPv6 paths have a higher delay and loss than their IPv4 counterparts. The main reason for the worse performance stems from IPv6‐in‐IPv4 tunnels rather than from native IPv6 paths and such tunnels are still widely used today. Copyright © 2007 John Wiley & Sons, Ltd.     

What do we know about innovation in nanotechnology? Some propositions about an emerging field between hype and path-dependency

This contribution formulates a number of propositions about the emergence of novel nanoscience and nanotechnology (N&N). Seeking to complement recent work that aims to define a research agenda and draws on general insights from the innovation literature, this paper aims to synthesize knowledge from innovation-related studies of the N&N field. More specifically, it is suggested that N&N is often misconstrued as either a field of technology or an area of (broadly) converging technologies while evidence to date suggests rather that N&N be considered a set of inter-related and overlapping about not necessarily merging technologies. The role of instrumentation in connecting the various N&N fields is underlined. Finally, the question is raised whether change in N&N tends to be incremental rather than discontinuous, being the result of technological path-dependencies and lock-ins in industry-typical search regimes that are only slowly giving way to more boundary-crossing activities.     

Congenic rats reveal three independent Copenhagen alleles within the Mcs1 quantitative trait locus that confer resistance to mammary cancer

It has previously been shown that the Copenhagen (COP) rat contains several genetic loci that contribute to its mammary tumor-resistant phenotype after 7,12-dimethylbenz(a)anthracene (DMBA) administration. One of these loci, mammary carcinoma susceptibility 1 (Mcs1), is located on the centromeric end of chromosome 2 and appears to act in a semidominant fashion. To confirm the existence and independent action of this locus and also aid in the identification of the physical location of the Mcs1 gene, congenic lines were generated by transferring the Mcs1 COP allele onto a Wistar Furth (WF) genetic background. Male carriers were genotyped using microsatellite markers spanning 20-30 cM of the Mcs1 locus. One of the congenic lines minimally retained the COP allele at D2Mit29 on the centromeric end of chromosome 2 and extended distally to D2Rat201. Heterozygous Mcs1 carrier rats were interbred, and the female offspring were treated with DMBA. The female rats from the Mcs1 congenic line that carried one or two COP alleles of the Mcs1 region had a significantly reduced (65 and 85%, respectively) tumor development (P < 0.001) compared with rats carrying zero COP alleles at this locus. A WF.COP-D2Mit29/D2Rat201 homozygous congenic strain derived at the N10 generation was treated with DMBA, and the COP homozygous rats developed 1.5 +/- 0.3 carcinomas/rat versus 6.3 +/- 0.5 in WF control rats (P < 0.0001). Fine mapping of this congenic interval using several recombinant lines identified three genetic loci within the Mcs1 congenic region that independently supported a tumor resistance phenotype. These genetic loci have been termed Mcs1a, Mcs1b, and Mcs1c. In rats for which each locus was homozygous for the COP allele, tumor development was reduced by approximately 60% compared with littermate controls. The identification of these independent loci within the Mcs1 COP allele provide a model of the genetic complexity of cancer.     

Degradation of Stiffness of Cemented Calcareous Soil in Cyclic Triaxial Tests

The deformation characteristics of artificially cemented calcareous soil subjected to undrained cyclic triaxial loading are investigated at different confining pressure and cyclic stress levels. The influence of cementation on the shear stiffness is investigated by comparing the behavior of cemented and uncemented soils with similar initial conditions. It is observed that the deviator stress and the deviatoric strain at yield reduced with increasing number of cycles for cemented sand due to progressive degradation of bond, which results in significant decrease in stiffness. On the other hand, a strain-hardening effect is observed in uncemented sand and this results in increasing yield stress and strain with progressive number of cycles. A linear relationship between degradation index and number of cycles is observed for cemented sand. This relationship has been synthesized in the form of an empirical equation by modifying a previously proposed equation for cohesive soils. This empirical equation was further used to evaluate the fatigue life of soils by adopting a failure criterion.     

Failure of a stationary pump engine piston

Piston failures are not a common occurrence, but they do occur, and failure is usually associated with fatigue crack growth. Most failures initiate at the gudgeon pin hole or in the skirt of the piston. Occasionally they fail elsewhere. In the example covered in this paper, failure initiated in the crown and progressed down to the gudgeon pin before final failure occurred. This paper outlines the cause and mode of failure and shows that small metallurgical discontinuities can contribute to these failures under the right circumstances.     

Delamination Resistant Zinc Alloys: Simple Concept and Results on the System Zinc‐Magnesium

Alloying zinc coatings with elements such as magnesium and titanium increases the corrosion resistance in industrial tests. Based on the fundamental mechanism of cathodic delamination, a simple concept how alloying zinc with specific elements might improve its resistance to cathodic delamination is presented in this paper. As an example, results concerning the delamination of a simple polymer from the zinc‐magnesium intermetallic MgZn₂ are presented. From electrode potential measurements obtained with the Scanning Kelvin Probe it can be concluded that cathodic delamination from this alloy is completely inhibited. This behaviour is attributed to the electronic properties of the magnesium‐rich oxidic passive layer, that inhibits the oxygen reduction reaction at the metal oxide/polymer interface.     

Radiale Wärmeleitung in durchströmten Schüttungsrohren

Heat Transport to the Wall of Packed Tubes. Radial conduction of heat in packed tubes has a crucial influence on yield and selectivity of many heterogeneously catalyzed reactions. In spite of many years of intensive research in the field, there are still tremendous discrepancies between correlations of different origin. Even the standard model using two constant heat transport parameters, which was introduced in the fifties and has since become most widely accepted, has been controversially discussed and called into question. The unsatisfactory state of the art has been an incentive for several groups of researchers to take up this old topic once again. Three parallel experimental investigations on heat transport with air flowing in packed tubes of similar dimensions, electrically heated, steam-heated, or water-cooled, were completed in 1991. Comparative evaluation of the results of these three investigations, together with other data from the relevant literature, now provides the first clear answers to some of the questions so controversially discussed in the past.