无锡市硫酸厂废热发电和三废综合治理技术改造情况介绍

介绍了硫酸厂废热发电和三废综合治理技术改造情况。沸腾炉顶改成由异形砖砌筑的球拱结构，废热锅炉采用混合循环方式，净化系统改用文－文－间－电流程，干吸塔式改为高强度塔，转化系统改用ⅤⅣⅠ－Ⅲ－Ⅱ“３＋２”两次转化流程，污水处理改用二级 和沉降，废热发电并网。     

Protein folding transition states: elicitation of Hammond effects by 2,2,2-trifluoroethanol

Adaptation of the techniques of classical physical-organic chemistry to the study of protein folding has led to our current detailed understanding of the transition states. Here, we have applied a series of structure--activity relationships to analyse the effects on protein folding transition states of 2,2,2-trifluoroethanol (TFE), a reagent that is usually assumed to act by stabilising secondary structure. The folding and unfolding of the highly alpha-helical tetramerisation domain of p53 provides a useful paradigm for analysing its effects on kinetics: The first step of its folding consists of an association reaction with little, if any, formation of secondary structure in the transition state; and the final step of the folding reaction involves just the formation of bonds at subunit interfaces, with the alpha-helical structure being completely formed. We have systematically measured the effects of TFE on two sets of structure--activity relationships. The first is for Phi values, which measure the degree of non-covalent bond formation at nearly every position in the transition state. The second is for relative effects of the denaturant, guanidinium chloride, on kinetics and equilibria, which measure the gross position of the transition state on the reaction co-ordinate. We find that TFE modulated the kinetics by a variety of effects other than that on secondary structure. In particular, there were Hammond effects, movement of the position of the transition state along the reaction co-ordinate, which either significantly speeded up or slowed down protein unfolding, depending on the particular mutant examined. The gross effects of TFE on protein folding kinetics are thus not a reliable guide to the structures of transition states.     

赤泥催化剂的制备及其对模拟烟气中微量氨的脱除性能

以赤泥固废为原料，采用酸解-碱沉淀法制备了赤泥粉体催化剂，并提出一种将催化剂直接喷入SNCR尾气中的除氨工艺，考察了催化剂加入点温度、空速、NH₃浓度及水蒸气对氨去除能力的影响。研究发现，该催化过程具有很高的活性和N₂的选择性，450℃以上NH₃的转化率可达100%，同时在400～500℃间，N₂的选择性高于80%，达到了很好的除氨效果；在500℃，空速为3×10⁶~6×10⁶ h^-1之间时，出口NH₃浓度均为0；此工艺对于逃逸NH₃浓度的适用性较强，入口[NH₃] = 50×10^-6~1000×10^-6 mol/L范围内均可完全脱除，且具有一定的抗水能力。通过一系列表征发现，该种方法制备的赤泥催化剂不仅消除了原始固废的强碱性，还提高了其表面酸性，具有较高的比表面积、孔容和丰富的表面微观结构，使NH₃的吸附及活化反应能力大大增加；该催化剂过程遵循iSCR机理，在400～500℃温度区间主要发生NH₃-SCO反应，低于400℃主要发生NH₃-SCR反应，粉体催化剂通过NH₃-SCR和NH₃-SCO协同反应达到了去除尾气中微量氨的目的。     

气液固三相反应装置的应用情况(摘译)

<正> 1979年化学工学协会内成立了“气液固三相反应装置研究会”,对三相反应装置的应用实例进行了调查。本文将其调查情况和作者做的一些文献调查综合起来叙述于后。三相反应器的应用例列于表1—1中。表1—1所列内容以日本国内现已应用的为主,同时也列入一些现在虽未应用,但被认为是重要的三相反应系统。表中所列     

Growth and the microstructural and ferroelectric characterization of oriented BaMgF(4) thin films

The growth of ferroelectric BaMgF(4) thin films on Si(100), sapphire, and other substrates under ultrahigh vacuum (UHV) conditions is reported. Microstructural characterization of the films using transmission electron microscopy (TEM) revealed that they were oriented crystalline films, although not epitaxial. Ferroelectric hysteresis measurements yielded spontaneous polarization and coercivity values of almost 1.0 muC/cm(2) and 160 kV/cm, respectively. The discrepancy with the bulk ferroelectric values were attributed to the electrical contacts, impurities in the film, and lack of polar axis orientation. Preliminary capacitance-voltage (C-V) hysteresis measurements on a 480-nm-thick BaMgF(4) film yielded a 10.8-V threshold shift (memory window) in response to a +/-10-V programming voltage for a MIS gate structure similar to that of the ferroelectric memory field-effect transistor (FEMFET).     

自复位防屈曲支撑钢框架的抗震性能分析

为了消除防屈曲支撑在强震后留有残余变形的弊端,本文针对一种新型支撑构件—自复位防屈曲支撑,通过有限元软件ANSYS对自复位防屈曲支撑钢框架、防屈曲支撑钢框架和钢框架进行罕遇地震作用下的抗震性能对比分析。结果表明,自复位防屈曲支撑钢框架的顶点位移、层间位移角、残余变形等地震响应均明显小于防屈曲支撑钢框架和钢框架,尤其在残余变形方面,自复位防屈曲支撑基本消除了结构的残余变形,具有良好的复位效果。     

铸铁件中缩孔状气孔

本文提出了铸铁件中气孔缺陷的一种表现形式——缩孔状气孔。作者认为:导致缩孔状气孔的形成,有三个充分与必要条件:(1)铸件具有较宽的热节区;(2)在气体侵入铸件热节区的液态合金里形成气泡且无法排出;(3)合金本身的凝固应有体积膨胀。作者在对缩孔状气孔的形成机理进行探讨的同时,还提出了予防及消除缺陷的方法     

热处理对两种铜膜结合强度的影响

采用PVD和CVD技术制备Cu/TiN/PI试样，研究表明，TiN薄膜可以有效地阻挡Cu向PI基板内部扩散，CVD工艺制备的Cu膜内部残余应力很小，Cu膜有相对高的结合强度；而PVD制备的Cu膜，在有TiN阻挡层存在的情况下，Cu膜内存在拉应力，拉应力降低了Cu膜结合强度，300℃退火可以消除膜内残余应力，结合强度提高。     

金、银、铂、钯合金中钯的选择性滴定方法的研究与应用

建立了丁二肟选择性沉淀分离和析出EDTA-Pd络合物中的EDTA,Pb(NO3)2返滴定测定Pd的新方法,系统地研究了在硝酸或盐酸介质中测定Pd的条件,并对比了本法与《国家标准》分析方法的结果.研究表明:2种方法测得Pd的结果吻合,测定5～30mg Pd,相对误差-0.17% ～ 0.20%;但拟定方法的选择性好,适用性强,分析快速,操作简便、易于掌握.方法已应用于Au、Ag、Pt、Pd合金中5%～99%的Pd含量的测定,结果满意.