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101.
Looking to increase the functionality of current wireless platforms and to improve their quality of service, we have explored the merits of using frequency-reconfigurable antennas as an alternative for multiband antennas. Our study included an analysis of various reconfigurable and multiband structures such as patches, wires, and combinations. Switches, such as radio-frequency microelectromechanical systems (RFMEMS) and p-i-n diodes, were also studied and directly incorporated onto antenna structures to successfully form frequency-reconfigurable antennas. 相似文献
102.
Mabel Ebenezer Rajkumar Mattacaud Ramachandralal Chandramohanan Nair Padmanabha Pillai Sarasamma 《电力部件与系统》2015,43(20):2251-2261
Transformers are critical components in power systems and their failure can cause long interruption of power supply. The condition of a transformer can be monitored by performing thermal analysis. The use of non-linear devices, such as rectifiers and converters, draws harmonic currents that increase losses in transformers, thereby increasing their operating temperature. In this article, a new numerical approach is presented for determining the rise in hot spot temperature in a 5-kVA, 400/400-V dry-type three-phase transformer laboratory prototype. The key novelty is that the additional winding eddy current loss due to non-linear loads is considered in the numerical modeling. The winding eddy current loss corresponding to harmonic distortion is estimated by conducting experiments and calculations. Numerical simulations are carried out for a wide range of non-linear loads using a commercial computational fluid dynamics package, FLUENT 6.3. The proposed numerical methodology is validated by performing experiments on the transformer for possible non-linear loads and comparing the measured hot spot temperature with the simulated values. Correlation equations for rise in hot spot temperature as a function of total harmonic distortion are presented, which can be used for estimating the life of transformers when connected to different types of loads. 相似文献
103.
Material properties and operating configurations of membrane reactors for propane dehydrogenation
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Seung‐Won Choi Christopher W. Jones Sankar Nair David S. Sholl Jason S. Moore Yujun Liu Ravindra S. Dixit John G. Pendergast 《American Institute of Chemical Engineers》2015,61(3):922-935
A modeling‐based approach is presented to understand physically realistic and technologically interesting material properties and operating configurations of packed‐bed membrane reactors (PBMRs) for propane dehydrogenation (PDH). PBMRs composed of microporous or mesoporous membranes combined with a PDH catalyst are considered. The influence of reaction and membrane transport parameters, as well as operating parameters such as sweep flow and catalyst placement, are investigated to determine desired “operating windows” for isothermal and nonisothermal operation. Higher Damköhler (Da) and lower Péclet (Pe) numbers are generally helpful, but are much more beneficial with highly H2‐selective membranes rather than higher‐flux, lower‐selectivity membranes. H2‐selective membranes show a plateau region of conversion that can be overcome by a large sweep flow or countercurrent operation. The latter shows a complex trade‐off between kinetics and permeation, and is effective only in a limited window. H2‐selective PBMRs will greatly benefit from the fabrication of thin (~1 µm or less) membranes. © 2014 American Institute of Chemical Engineers AIChE J, 61: 922–935, 2015 相似文献
104.
105.
K. N. Remani E. Nirmala S. R. Nair 《The International journal of environmental studies》2013,70(4):285-295
One of the striking features of Kerala state is the continuous chain of lagoons or backwaters existing along the coastal region. The backwaters support rich and diverse life forms and provide crucial nurseries for shrimps and fishes as well as habitat for oysters, clams and mussels which later enrich the ocean and make Kerala the principal exporter of marine products amongst the states of India. The shallow fringes of the backwaters and the channels drawn from them are used for retting of coconut husk. It adversely affects the productivity of the backwaters and is harmful to marine fisheries. The retting of coconut husks in backwaters is brought about by the pectinolytic activity of micro organisms especially bacteria fungi and yeasts degrading the fibre binding materials of the husk and liberating large quantities of organic matter and chemicals into the environment, including pectin, pentosan, tannins, polyphenols, etc. Consequently hydrogen sulphide, phosphate and nitrate contents increase while dissolved oxygen and community diversity of plankton decrease in the ambient waters during the retting process. The present study is to evaluate pollution due to coir retting activity and its influence on quality of water and estuarine flora and fauna. 相似文献
106.
Sivashankaran Nair Sujatha Lekshmy Vijayam Sukumaran Nair Anitha PuthenKadathil Vargehese Thomas Kunjkunju Joy 《Journal of the American Ceramic Society》2014,97(10):3184-3191
Manganese‐doped tin oxide (SnO2:Mn) thin films were deposited on glass substrates by the sol–gel dip coating technique. The effect on structural, morphological, magnetic, electrical, and optical properties in the films with different Mn concentrations (0–5 mol%) were investigated. X‐ray diffraction patterns (XRD) showed the deterioration of crystallinity with increase in Mn‐doping concentration. Scanning electron microscopy (SEM) studies showed an inhibition of grain growth with an increase in Mn concentration. X ray photoelectron spectroscopy (XPS) revealed the presence of Sn4+ and Mn3+ in SnO2: Mn films. SnO2: Mn films show ferromagnetic and paramagnetic behavior. These SnO2:Mn films acquire n‐type conductivity for 0–3 mol% (SnO2 ‐ Sn0.97Mn0.03O2) ‐doping concentration and p type for 5 mol% Mn‐doping concentration(Sn0.95Mn0.05O2) in SnO2 films. An average transmittance of > 75% (in UV‐Vis region) was observed for all the SnO2:Mn films. Optical band gap energy of SnO2: Mn films were found to vary in the range 3.55 to 3.71 eV with the increase in Mn‐doping concentration. Photoluminescence (PL) spectra of the films exhibited an increase in the emission intensity with increase in Mn‐doping concentration which may be due to structural defects or luminescent centers, such as nanocrystals and defects in the SnO2. Such SnO2:Mn films with structural, magnetic and optical properties can be used as dilute magnetic semiconductors. 相似文献
107.
Cassava starch‐graft‐polymethacrylamide copolymers as flocculants and textile sizing agents
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Cassava starch‐graft‐polymethacrylamide (PMAM) copolymers were synthesized by a free‐radical‐initiated polymerization reaction, and the products were tested for their efficiency as flocculants and textile sizing agents. The highest percentages of grafting and monomer conversion were 79.9 and 78.0%, respectively. The grafted starches were characterized by Fourier transform infrared spectroscopy, X‐ray diffraction analysis, scanning electron microscopy, differential scanning calorimetry, and thermogravimetric analysis. The average molecular weight of PMAM chains in the grafted starches ranged from 15.9 to 30.8 × 105 g/mol. The grafted starches exhibited a higher peak viscosity and paste stability in comparison to the native starch (NS). Dynamic mechanical analysis showed that grafting provided fairly shear‐stable hydrogels, and the highest storage modulus obtained was 17,900 Pa compared to 1879 Pa for NS. The flocculation studies demonstrated the superiority of starch‐g‐PMAM over cassava starch and PMAM as an efficient flocculant. The tensile strength of cotton yarns sized with the starch‐grafted copolymer was significantly higher (104 MPa) compared to that sized with NS (34 MPa). © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 39810. 相似文献
108.
The effect of phenol end functional shape memory oligomers on the shape memory properties of an epoxy‐cyanate ester resin system was examined. The basic resin system consisted of diglycidyl ether of bisphenol A (DGEBA) cured with bisphenol A dicyanate (BADC). For conferring the shape memory properties, the switching segment (SS) components selected are α, ω‐phenol‐terminated poly(tetramethyleneoxide) (PPTMO), poly(ε‐caprolactone) (PPCL), and poly(propylene glycol) (PPPG). Epoxy‐cyanate ester blend of defined composition was analyzed for thermal, mechanical, thermo‐mechanical, and shape memory properties at two concentrations of the three SSs. The transition temperature of heavily SS loaded matrix increased in the order: PPTMO < PPCL < PPPG commensurate with crystallizability of SS segments at ambient. For same reason flexural property showed an increasing trend. This is in league with the increased crystallizability of the shape memory polymer components. The shape fixity, recovery extent, and recovery time followed a reverse order: PPPG < PPCL < PPTMO. In contrast to the alcohol terminated shape memory components, phenol terminal groups were helpful in integrating the shape memory segments into the matrix by way of reaction with both epoxy and cyanate groups. The coreaction was conducive for achieving better shape memory properties and decreasing the transition temperature. A direct relation existed between the modulus ratio and the shape recovery property. Higher concentration of the SSs caused a diminution in transition temperature but enhanced the shape memory properties, though the mechanical properties were adversely affected. The shape recovery increased with increase in temperature. All polymers possessed good mechanical properties and thermal stability. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 41196. 相似文献
109.
Pranab Dey Kinsuk Naskar Golok B. Nando Biswaranjan Dash Sujith Nair G. Unnikrishnan 《应用聚合物科学杂志》2014,131(23)
Thermoplastic vulcanizates (TPVs), which are a special class of elastomer alloy, prepared by dynamic vulcanization possess unique morphology of finely dispersed micron‐size cross‐linked elastomeric particles in a continuous thermoplastic matrix. The present study investigates the microstructure formation of elastomeric phase and its associated morphological changes during reprocessing of TPVs based on poly[styrene‐b‐(ethylene‐co‐butylene)‐b‐styrene] triblock co‐polymer (S‐EB‐S) and solution polymerized styrene butadiene elastomer (S‐SBR) by scanning electron microscopy and atomic force microscopy. Semi‐efficient and efficient sulfur‐based curing systems have been adopted to cure the elastomeric phase and a comparative study has been made to demonstrate and explain the effect of reprocessing on the melt rheology and dynamic viscoelasticity of the TPVs. The present work also provides a better insight and guidance to control the microstructure of the cross‐linked elastomeric phase to prepare selectively co‐continuous or dispersed phase morphology. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 41182. 相似文献
110.
The formation of polymer networks polymerized with the Copper (I) – catalyzed azide – alkyne cycloaddition (CuAAC) click reaction is described along with their accompanying utilization as shape memory polymers. Due to the click nature of the reaction and the synthetic accessibility of azide and alkyne functional-monomers, the polymer architecture was readily controlled through monomer design to manipulate crosslink density, ability for further functionalization, and the glass transition temperature (55–114 °C). Free strain recovery is used to quantify the shape memory properties of a model CuAAC network resulting in excellent shape fixity and recovery of 99%. The step growth nature of this polymerization results in homogenous network formation with narrow glass transitions ranges having half widths of the transition close to 15 °C for these materials resulting in shape recovery sharpness of 3.9%/°C in a model system comparable to similarly crosslinked chain growth polymers. Utilization of the CuAAC reaction to form shape memory materials opens a range of possibilities and behaviors that are not readily achieved in other shape memory materials such as (meth) acrylates, thiol-ene, thiol-Michael, and poly(caprolactone) based shape memory materials. 相似文献