Slenderness Limit for Hybrid FRP-Concrete Columns

Due to confinement effects, concrete-filled fiber-reinforced polymer (FRP) tubes have an enhanced performance comparable to conventionally reinforced concrete members. However, the strength and ductility enhancements may result in slender sections, which may be susceptible to instability or geometric and loading imperfections. Because stiffness of FRP is less than that of steel, designers cannot directly use current specifications to size compression members. Uniaxial compression tests on a total of seven hybrid columns, with slenderness ratios up to 36, showed that strength is reduced by as much as 71% of the equivalent short column, and the axial and hoop strains are reduced by as much as 85 and 87%, respectively. These significant reductions result in underutilization of confinement in slender columns. An analytical tool with an incremental approach was developed and compared favorably with test results. A parametric study was carried out, which showed the modulus of elasticity of the tube to have a pronounced effect on the slenderness limit of the column. A new equation was proposed for the slenderness limit of hybrid columns based on a maximum of 5% strength reduction.     

Modeling nano-scale grain growth of intermetallics

The Monte Carlo simulation is utilized to model the nano-scale grain growth of two nano-crystalline materials, Pd₈₁Zr₁₉ and RuAl. In this regard, the relationship between the real time and the time unit of simulation, i.e. Monte Carlo step (MCS), is determined. The results of modeling show that with increasing time of heating, the grain sizes of both nano-crystalline materials increased as in the case of conventional materials. Moreover, it is found that for both nano-crystalline materials the relationship between the real time and MCS is in power law form, which is linear for the conventional materials.     

Environmental sustainability assessment of buildings in hot climates: the case of the UAE

Sustainability has acquired great importance due to the negative impact of various developments on the environment. The rapid growth during the last decade has been accompanied by active construction which, in some instances, neglected the impact on the environment and human activities. The impact of developments on the traditional heritage has not been taken into consideration although the latter represents a rich resource for sustainable building practices. The study aims at examining these developments in the UAE using an assessment tool that measures the performance of buildings in terms of their sustainability. This study attempts to: (a) develop a comprehensive definition of sustainability to suit UAE needs; (b) classify sustainable building practices at international and regional levels; (c) assess building performance in the UAE; and (d) establish guidelines for future sustainable architecture. T-Sol software was used to predict the CO₂ emission level in selected buildings in the UAE. Results illustrate that average energy use/area in domestic buildings is high (213 kWh/m²) and public buildings showed less sustainable measures in terms of energy features, energy performance and environmental features. Issues considered in the assessment of buildings such as energy use per square metre and CO₂ emission are alarming. Traditional buildings in the UAE were more sustainable than contemporary buildings, however.     

Insight into the Impact of Oxidative Stress on the Barrier Properties of Lipid Bilayer Models

As a new field of oxidative stress-based therapy, cold physical plasma is a promising tool for several biomedical applications due to its potential to create a broad diversity of reactive oxygen and nitrogen species (RONS). Although proposed, the impact of plasma-derived RONS on the cell membrane lipids and properties is not fully understood. For this purpose, the changes in the lipid bilayer functionality under oxidative stress generated by an argon plasma jet (kINPen) were investigated by electrochemical techniques. In addition, liquid chromatography-tandem mass spectrometry was employed to analyze the plasma-induced modifications on the model lipids. Various asymmetric bilayers mimicking the structure and properties of the erythrocyte cell membrane were transferred onto a gold electrode surface by Langmuir-Blodgett/Langmuir-Schaefer deposition techniques. A strong impact of cholesterol on membrane permeabilization by plasma-derived species was revealed. Moreover, the maintenance of the barrier properties is influenced by the chemical composition of the head group. Mainly the head group size and its hydrogen bonding capacities are relevant, and phosphatidylcholines are significantly more susceptible than phosphatidylserines and other lipid classes, underlining the high relevance of this lipid class in membrane dynamics and cell physiology.     

Diagnostic value of determining hemoglobin in cerebrospinal fluid in acute cerebral circulatory disorders

The results of hemoglobin determination in the CSF by the method of fluorescence microscopy in 195 patients speaks in favor of relative diagnostical importance of hemoglobin in the supra fall-out CSF for establishing the character of the stroke. The following circumstances testify to this fact: 1) in an artificial admixture of blood in the CSF in some cases there may be hemolysis of "passing" erythrocytes; 2) in a genuine admixture of blood, tests of hemoglobin in the centrifugate of the CSF may be negative since in some cases the transition of hemoglobin into bilirubin in the subarachmoid space occurs more rapidly than the hemolysis of erythrocytes. Thus, the hemoglobin does not accumulate in the liquid in quantities, sufficient enough to be measured by the existing methods; 3) in a large amount of artificial blood admixture, even without a hemolysis of "passing" erythrocytes the hemoglobin tests in the centrifugate of the CSF may be positive at the expense of hemoglobin of the blood plasma.     

The interaction of dietary fibers and cholesterol upon the plasma lipids and lipoproteins, sterol balance, and bowel function in human subjects

To identify any metabolic effects of dietary fiber upon cholesterol metabolism in man, six adult volunteer subjects were fed eucaloric cholesterol-free formula diets, with and without added dietary fiber for two 4-wk periods. A large quantity of dietary fiber was fed, some 60 g of plant cell wall material (or 16 g of crude fiber) derived from corn, beans, bran, pectin, and purified cellulose. This provided about five times the fiber intake of the typical American diet. The addition of fiber to the cholesterol-free diet did not change either the plasma cholesterol level (171+/-21 mg/dl, SEM, to 167+/-18) or the triglyceride (103+/-39 to 93+/-27 mg/dl). The excretion of both endogenous neutral steroids and bile acids were unchanged with fiber (505+/-41 to 636+/-75 mg/day and 194+/-23 to 266+/-47 mg/day, respectively.) However, total fecal steroid excretion was increased 699+/-29 to 902+/-64 mg/day, P < 0.025). With fiber, intestinal transit time was decreased (59+/-9 to 35+/-8 h, P < 0.005), and both the wet and dry stool weights were greatly increased.A second group of six subjects was fed similar diets containing 1,000 mg cholesterol derived from egg yolk. The addition of fiber to the 1,000-mg cholesterol diet did not alter either plasma cholesterol level (233+/-26 to 223+/-36 mg/dl) or triglyceride (102+/-19 to 83+/-11 mg/dl). The excretion of endogenous neutral steroids (618+/-84 to 571+/-59 mg/day), of bile acids (423+/-122 to 401+/-89 mg/day), and of total fecal steroids (1,041+/-175 to 972+/-111 mg/day) were unchanged by fiber. The absorption of dietary cholesterol was not altered when fiber was added to the 1,000-mg cholesterol diet (44.0+/-3.3 to 42.9+/-2.5%). A two-way analysis of variance utilizing both groups of subjects indicated a significant (P < 0.001) effect of dietary cholesterol upon the plasma cholesterol concentration. We concluded that a large quantity of dietary fiber from diverse sources had little or no effect upon the plasma lipids and sterol balance in man in spite of the fact that intestinal transit time and stool bulk changed greatly.     

Application of titanium oxide nanotube films containing gold nanoparticles for the electroanalytical determination of ascorbic acid

Au/TiO₂/Ti electrodes have been prepared by galvanic deposition of gold particles on TiO₂ nanotube substrates. Titanium oxide nanotubes are fabricated by anodizing titanium foil in a Dimethyl Sulfoxide electrolyte containing fluoride. The scanning electron microscopy results indicated that gold particles are homogeneously deposited on the surface of TiO₂ nanotubes. The TiO₂ layers consist of individual tubes of about 40-80 nm diameters. The electro-catalytic behavior of Au/TiO₂/Ti and flat gold electrodes for the ascorbic acid electro-oxidation was studied by cyclic voltammetry. The results showed that the flat gold electrode is not suitable for the oxidation of ascorbic acid. However, the Au/TiO₂/Ti electrodes are shown to possess catalytic activity toward the oxidation reaction. Catalytic oxidation peak current showed a linear dependence on the ascorbic acid concentration and a linear calibration curve is obtained in the concentration range of 1-5 mM of ascorbic acid. Also, determination of ascorbic acid in real samples was evaluated. The obtained results were found to be satisfactory. Finally the effects of interference on the detection of ascorbic acid were investigated.     

Association between antiinflammatory cytokine,IL‐10, and sleep quality in patients on maintenance hemodialysis

Elevated proinflammatory cytokines have been attributed to poor sleep quality in patients receiving hemodialysis. This is the first investigation about the relationship between sleep quality and circulating levels of antiinflammatory markers in these patients. A total of 72 patients who were receiving maintenance hemodialysis were enrolled in this cross‐sectional study. The Pittsburgh Sleep Quality Index (PSQI) was used to measure sleep quality. Patients were divided into two groups: good sleepers (PSQI score < 5) and poor sleepers (PSQI score ≥ 5). Assessments were made for serum biochemical parameters (albumin, parathyroid hormone), inflammatory (interleukin [IL]‐6, tumor necrosis factor‐alpha [TNF‐α], and high‐sensitivity c‐reactive protein [hs‐CRP] ) and antiinflammatory (IL‐10) markers. Fifty‐four patients (75%) were classified as poor sleepers. Poor sleepers showed significantly lower levels of serum IL‐10 and higher serum triglyceride and parathyroid hormone concentrations. These patients were more likely to have more comorbidities. The global PSQI score was significantly correlated with serum IL‐10 (p = 0.03) and triglyceride levels (p = 0.01). Multivariate logistic regression analysis showed a direct correlation between PSQI and having comorbidities (p = 0.011, odds ratio [OR] = 3.918; confidence interval 95% [CI] = 2.742–19.031), between PSQI and serum triglyceride (p = 0.027, OR = 1.027 [95% CI = 1.007–1.048] ), and an inverse correlation between PSQI and serum IL‐10 level (p = 0.021, OR = 0.424 [95% CI = 0.195–0.922]). Reduced circulating levels of the antiinflammatory cytokine IL‐10 were significantly associated with poor sleep quality in hemodialysis patients. Factors including serum IL‐10 and triglyceride concentrations and having comorbidities may predict patients prone to poor sleep quality.     

A planar micro-concentrator/injector for low power consumption microchromatographic analysis of benzene and 1,3 butadiene

In the present study, we present the first steps of the development of a low power consumption GC microsystem for the analysis of benzene in the presence of butadiene, involved in petrochemical industrial applications. This system is made by coupling a low power consumption planar microhotplate based on a preconcentrator with good preconcentration capability and a spiral microchromatographic column that presents a separation capability of both compounds at room temperature, when tested in front of a gas sensor. The first characterization results of the device showed a successful injection of benzene and butadiene when placed in front of the micro-separation module.     

Application of several non-linear prediction tools for estimating uniaxial compressive strength of granitic rocks and comparison of their performances

Uniaxial compressive strength (UCS) of rock is crucial for any type of projects constructed in/on rock mass. The test that is conducted to measure the UCS of rock is expensive, time consuming and having sample restriction. For this reason, the UCS of rock may be estimated using simple rock tests such as point load index (I _s(50)), Schmidt hammer (R _n) and p-wave velocity (V _p) tests. To estimate the UCS of granitic rock as a function of relevant rock properties like R _n, p-wave and I _s(50), the rock cores were collected from the face of the Pahang–Selangor fresh water tunnel in Malaysia. Afterwards, 124 samples are prepared and tested in accordance with relevant standards and the dataset is obtained. Further an established dataset is used for estimating the UCS of rock via three-nonlinear prediction tools, namely non-linear multiple regression (NLMR), artificial neural network (ANN) and adaptive neuro-fuzzy inference system (ANFIS). After conducting the mentioned models, considering several performance indices including coefficient of determination (R ²), variance account for and root mean squared error and also using simple ranking procedure, the models were examined and the best prediction model was selected. It is concluded that the R ² equal to 0.951 for testing dataset suggests the superiority of the ANFIS model, while these values are 0.651 and 0.886 for NLMR and ANN techniques, respectively. The results pointed out that the ANFIS model can be used for predicting UCS of rocks with higher capacity in comparison with others. However, the developed model may be useful at a preliminary stage of design; it should be used with caution and only for the specified rock types.