A sorption rate hypothesis for the increase in H2 permeability of palladium-silver (Pd-Ag) membranes caused by air oxidation

Hydrogen permeation measurements were performed at 300 °C for 25-μm cold-rolled Pd-Ag 25 wt% membranes before and after air oxidation at the same temperature as permeation. The air oxidation resulted in enhanced H₂ permeation through the membrane, as well as a roughening of the surface with the formation of surface grains and defects. The protruding grains can be leveled off by exposure to H₂ but the surface defects cannot. These microstructure changes are only on the membrane surfaces and do not create transmembrane defects that would allow permeation for gas species other than H₂. The H₂ permeability of the oxidized membrane increased by 25-90% compared to that of the as-received film at the same permeation condition, and the membranes retained perfect H₂ selectivity over N₂. The percent improvement of H₂ permeability decreases with increasing H₂ feed pressure. A new sorption kinetics hypothesis is proposed to elucidate the increase in H₂ permeability of Pd-Ag membranes caused by oxidation. H₂ solubility and sorption rate results were presented to test the new hypothesis. It is found that air oxidation does not change the H₂ solubility in Pd-Ag membranes, but enhances the H₂ sorption kinetics significantly. The extent of kinetics enhancement also decreases with increasing H₂ pressures. The much faster sorption equilibrium implies higher effective H₂ diffusivity at the Pd-Ag membrane surface for the oxidized sample and a higher transfer rate of atomic hydrogen from surface/sub-surface to the membrane bulk that contributes to the increase of H₂ permeability observed in experiments.     

Towards an end-to-end airborne remote-sensing system for post-hazard assessment of damage to hyper-critical infrastructure: research progress and needs

The objective of this article is to synthesize research findings and requirements pertaining to development of time-sensitive remote-sensing systems (TSRSS) that support decision-making pertaining to post-hazard assessment of damage to what we define as hyper-critical infrastructure (HCI), based on an aerial imaging approach known as repeat station imaging (RSI). The following TSRSS components are addressed and related findings are reported: (1) understanding information requirements of emergency managers pertaining to damage of HCI; (2) flight planning and data capture requirements for supporting bi-temporal RSI pairs; (3) automatic image registration and shadow classification and normalization routines applied to RSI pairs; (4) damage detection and delineation approach that exploits simple temporal differences in image brightness to automatically, reliably, and robustly delineates new cracks associated with damage; and (5) rapid data and information transfer to emergency managers. The highest priority follow-on research topics are: (1) integrating small unmanned aerial systems (sUAS) with the RSI approach, while enabling multiple view perspectives other than vertical (i.e. nadir pointing) and (2) developing and testing of machine learning routines for automatic identification of damage features from RSI pairs, particularly those captured from integrated sUAS–RSI.     

Covalently-Bonded “Onion Type” Double Fullerenic Carbon Cages

Abstract

Three “onion type” double carbon cages (consisting of an inner sp³-hybridized C₆₀ buckminsterfullerene skeleton and an outer larger carbon cage with icosahedral symmetry, with covalent bonds between the carbon atoms of the 5-membered rings) are described and their strain energies are discussed: (i) when the outer cage is a C₁₂₀ cage derived from buckminsterfullerene by replacing each bond between two six-membered rings by an acetylenic group, the strain is smallest.; (ii) when the same derivation concerns each bond between 5- and 6-membered rings leading to a C₁₈₀ outer cage, the strain is largest.; (iii) when the outer cage is C₁₈₀ with benzenoid rings, the strain is intermediate.     

Bifunctional Catalyst Control of Alkene Isomerization

The ability to control the formation and chemistry of alkenes is of central importance to organic synthesis in both industry and academia. Progress in using catalysts with bifunctional (heteroaryl)phosphines to control positional and/or geometric selectivity in alkene isomerization and related chemistry is summarized.     

Mapping and mining interictal pathological gamma (30-100 Hz) oscillations with clinical intracranial EEG in patients with epilepsy

Localizing an epileptic network is essential for guiding neurosurgery and antiepileptic medical devices as well as elucidating mechanisms that may explain seizure-generation and epilepsy. There is increasing evidence that pathological oscillations may be specific to diseased networks in patients with epilepsy and that these oscillations may be a key biomarker for generating and indentifying epileptic networks. We present a semi-automated method that detects, maps, and mines pathological gamma (30-100 Hz) oscillations (PGOs) in human epileptic brain to possibly localize epileptic networks. We apply the method to standard clinical iEEG (<100 Hz) with interictal PGOs and seizures from six patients with medically refractory epilepsy. We demonstrate that electrodes with consistent PGO discharges do not always coincide with clinically determined seizure onset zone (SOZ) electrodes but at times PGO-dense electrodes include secondary seizure-areas (SS) or even areas without seizures (NS). In 4/5 patients with epilepsy surgery, we observe poor (Engel Class 4) postsurgical outcomes and identify more PGO-activity in SS or NS than in SOZ. Additional studies are needed to further clarify the role of PGOs in epileptic brain.     

Examining housing discrimination across race,gender and felony history

Those who have been convicted of crimes are subjected to a stigma that affects many aspects of their social lives. The “felon” label brings collateral consequences that make it difficult to obtain basic human needs, including housing. This study uses the audit method to examine the effects of race, gender, and criminal history on housing outcomes. Testers, exhibiting characteristics suggestive of race and gender and disclosing one of three offenses, placed phone calls to rental property owners across the Midwest to inquire about renting a property. We found powerful negative effects for those with a criminal record seeking apartments, regardless of whether the offense was sexual or drug-related. However, we found no differences between minority and non-minority testers. We explain these findings in the context of housing as an essential resource for formerly incarcerated individuals.     

Developing an Efficient Auto-Calibration Algorithm for HEC-HMS Program

Two auto-calibration methods, namely Nelder-Mead (NM) and Univariate-Gradient (UG) and a manual approach are available for calibrating the HEC-HMS program. However, their being either inefficient or time consuming makes it difficult to work with HEC-HMS especially when using a snowmelt module in a continuous mode. The main objective of this paper is to develop an efficient Genetic Algorithm (GA) based auto-calibration method for HEC-HMS model (HMS-GA) for continuous snowmelt simulation. A general novel procedure is presented in the absence of the HMS source code to link a heuristic algorithm with the HEC program through Jython programming language. The models are developed and evaluated using daily data from basins in Ajichai, northwestern Iran. A comparison of results for a verification period indicates a substantial improvement by applying the HMS-GA over the other available methods. Moreover, it is shown that neither NM nor UG is able to improve the results obtained by either the manual or HMS-GA. Furthermore, the proposed method significantly improves the calibrations of the HMS model found by the three other methods.     

Developing electrochemical measurements in order to assess anti-corrosive coatings more effectively

The aim of this project was to check reproducibility of results obtained using NOCS (no connection to the substrate) arrangement of the electrochemical noise method (ENM). NOCS involves taking measurements from three nominally identical areas on the coated surface. Thus, no electrical connection to substrate is required. In practice the areas are not identical and various arrangements for connection of the three cells were tried to see if the individual areas could be separated out and whether the individual resistances could be computed. Also different ways of calculating the R_n (noise resistance) and R_sn (spectral noise resistance) parameters were attempted to see which one gave the best comparison with the more standard EIS measurements. The maximum entropy method was recognized to be the most useful for comparison with EIS, as well as for graphic evaluation of results. Regarding distinguishing three areas using different connection arrangements, it was possible to identify the situation when one of the three values was different to the other two. However further experiments are needed before it will be possible to confidently assign an R_n value to each individual area.