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961.
Various properties of submicronic silver-palladium powders (70/30 and 75/25 Ag/Pd % wt/wt), recently obtained by a new process of precipitation in aqueous solution, are described. These powders are intended to be used in the multilayer ceramic capacitor industry. The morphology of the particles has been analysed through various measurements, such as SEM images, tap density, BET surface area, and the size distribution by a sedimentation technique. The powders were found to be made of spherical shaped particles of mean diameter close to 0.3 m with a narrow size distribution. The individual grains were agglomerated only to a small extent. After being conditioned as a paste by blending with an organic binder, screen-printed and fired, the particles sintered into a conductive layer of low resistivity (15–30 Wcm for 2 m thickness) with only a few remaining voids, as observed by SEM. Thermal measurements indicated no melting of a pure silver phase at 960 °C, thus indicating that alloying was achieved before this temperature. 相似文献
962.
R. A. Olson B. J. Christensen R. T. Coverdale S. J. Ford G. M. Moss H. M. Jennings T. O. Mason E. J. Garboczi 《Journal of Materials Science》1995,30(20):5078-5086
The d.c. conductivity, , and low-frequency relative dielectric constant, k, of Portland cement paste were monitored, using impedance spectroscopy, during cooling from room temperature down to -50 °C. Dramatic decreases in the values of and k, as great as two orders of magnitude, occurred at the initial freezing point of the aqueous phase in the macropores and larger capillary pores. This result provides strong experimental support for the dielectric amplification mechanism, proposed in Part II of this series, to explain the high measured low-frequency relative dielectric constant of hydrating Portland cement paste. Only gradual changes in the electrical properties were observed below this sudden drop, as the temperature continued to decrease. The values of and k of frozen cement paste, at a constant temperature of -40 °C, were dominated by properties of calcium-silicate-hydrate (C-S-H) and so increased with the degree of hydration of the paste, indicating a C-S-H gel percolation threshold at a volume fraction of approximately 15%–20%, in good agreement with previous predictions. Good agreement was found between experimental results and digital-image-based model computations of at -40 °C. Freeze-thaw cycling caused a drop in the dielectric constant of paste in the unfrozen state, indicating that measurements of k could be useful for monitoring microstructural changes during freeze-thaw cycling and other processes that gradually damage parts of the cement paste microstructure. 相似文献
963.
Characterization of shock-hardened Al-8090 alloy 总被引:1,自引:0,他引:1
The structure and mechanical properties of Al-Li8090 alloy, that was dynamically deformed and then age hardened, were studied as a function of the changes in the nature and amount of precipitates produced. A comparison was made between two groups of samples, one group that was solution heat treated (SHT) and quenched from 530°C before the dynamic deformation and the other group that was dynamically deformed in the as-received (AR) condition. The higher values for microhardness and ultimate tensile strength observed (138 and 140 VHN, and 405 and 458 MPa, respectively), subsequent to shock treatment (ST), have been attributed to the increase in dislocation density and grain-boundary precipitation produced due to shock deformation. Dislocations and grain boundaries were assumed to act as precipitation sites and an increase in dislocation density, due to ST, was expected to increase precipitation density of (Al3Li), S(Al2CuMg), and T1(Al2CuLi) phases which, in turn, are expected to increase strength properties of the alloy. Differential scanning calorimetry showed that, for the species that precipitate below 180°C, (Al3Li) and GP zones, an increase in the amount of deformation increased the precipitation temperatures. However, for the species that precipitate at 197°C, S(Al2CuMg), an increase in the amount of deformation produced a decrease in its precipitation temperature. These results have been partially confirmed by the activation energy calculations for temperatures below 197 °C, which show a decrease of precipitation energies with an increase in the amount of deformation. Activation energies calculated from ageing curves showed that when ageing at low temperature (165–180 °C range), activation energies for the precipitation process are decreased upon increase in cold work. Shock treatment of SHT samples exhibited decreased activation energy values of precipitation, from 36.14 kcal mol–1 for the SHT sample to 24.18, 24.08, and 21.00 kcal mol–1 for SHT + ST samples 1, 2, and 3, respectively (corresponding to 1, 2, and 3 sheets of explosive). Activation energies of precipitation for AR + ST samples showed even lower values; 9.45, 9.95, and 8.21 kcal mol–1 for samples 4, 5, and 6, respectively. These activation energies strongly corroborate the role of defect substructure on the age-hardening kinetics of this alloy. 相似文献
964.
Four cases of citation histories of highly cited related papers from the field of chemical correlation analysis indicate that authors have been citing preferably fashionable, but less relevant references. 相似文献
965.
M. J. Hoffman Yiu-Wing Mai R. H. Dauskardt J. Ager R. O. Ritchie 《Journal of Materials Science》1995,30(13):3291-3299
Cyclic fatigue crack growth and crack-resistance behaviour was studied in partially stabilized zirconia (PSZ) with three different cubic-phase grain sizes following sub-eutectoid heat treatments. Raman spectroscopy was used to determine the extent of phase transformation around the cracks for both cyclic and monotonic loading conditions. All tests were on long, through thickness cracks using compact-tension specimens. Predictions of crack-tip shielding were made following determination of toughening parameters using crackresistance data. It was found that the dominant factors affecting cyclic fatigue-crack growth were the level of crack-tip shielding, as a result of phase transformation, and the intrinsic toughness of the material. Grain size did not appear to significantly affect fatigue crack-growth behaviour. 相似文献
966.
M. V. Tsodikov O. V. Bukhtenko O. G. Ellert V. M. Shcherbakov D. I. Kochubey 《Journal of Materials Science》1995,30(4):1087-1094
As a result of titanium and zirconium alcoholates hydrolysis in the presence of dissolved Fe(acac)3, amorphous iron-containing gels have been synthesized. Their heat treatment has led to polycrystalline double oxides Fe
x
Zr1–0.75x
O2– (C) and Fe
x
Ti1–0.75x
O2– (T) formation. It has been shown that oxides (C) and (T) are likely to be solid solutions with 0.01<x<0.17 and 0.01<x<0.14, respectively. On the basis of X-ray diffraction and extended X-ray absorption fine structure data, iron-zirconium and iron-titanium crystallite models for gels and oxides have been proposed. It has been found that the crystallization process does not lead to a significant change in interatomic distances typical for local structures detected in gels. 相似文献
967.
V. C. S. Reynoso L. C. Barbosa Yudong Liu O. L. Alves N. Aranha C. L. Cesar 《Journal of Materials Science》1995,30(24):6299-6302
We study the TiO2-BaO-ZnO-B2O3 glass system, where the ZnO and B2O3 compositions were constant and the ratio TiO2/BaO was varied from 0.87 to 1.76. A super kanthal resistance furnace was used to melt the compounds inside an alumina crucible, at 1200 °C, for 10 min. After melting, the glasses were poured out into steel moulds and rapidly cooled by quenching. The glasses obtained were homogeneous, bubble free and transparent. They were characterized by X-ray diffractometry, Fourier transform infrared spectroscopy (FTIR), UV-VIS spectroscopy, dilatometry, density and linear refractive index. An infrared cut off caused by the composition influence was found in both IR and UV-vis spectra. From dilatometry T
d and T
g were verified as being anomalous. The linear thermal expansion coefficient presented an anomalous behaviour in relation to TiO2 concentrations. The density and linear refractive index increased with increasing TiO2/BaO ratio arriving at their peak value of TiO2/BaO=1.5 and then decreasing. The dependence of softening point T
d on the ratio TiO2/BaO exhibited the same behaviour. It is suggested that Ti4+ plays a dual part in the glass system, assuming a predominantly tetrahedral coordination in the low titania region and a predominantly octahedral coordination in the high titania region. With a heat treatment of the glass around 600 °C, we observed a rapid change of refractive index with increasing temperature. 相似文献
968.
Calculations of the effect of intermediate bosons on the optical properties of the normal state are used to analyze the spectra of these bosons. For high temperature superconductors these spectra are in agreement with the standard electron-phonon model (the end of the spectrum is near 800 cm–1) with a moderate coupling constant =1–1.5. For the heavy fermion compound UPt3 the spectrum of intermediate bosons is consistent with neutron data for spin fluctuations.This work was partially supported by ISF and RFFI (No 94-02-04186a) grants. 相似文献
969.
S Kawai F Imazeki O Yokosuka M Ohto S Shiina N Kato M Omata 《Canadian Metallurgical Quarterly》1995,22(1):112-117
Analysis of X-chromosome inactivation patterns in women has been used to assess the clonality of various tumors. In this report, we analyzed 27 liver tumors in women, including 18 samples obtained by the performance of ultrasonically guided thin-needle biopsies. By analysis of the heterogeneity of phosphoglycerate kinase gene, 11 of 27 (41%) cases were found to be heterozygous at the gene. Of these informative 11 cases with liver tumors, 7 cases were "large" tumors (> 25 mm in diameter) and 4 cases were "small" tumors (< 25 mm in diameter). All 7 large tumors showed monoclonal patterns by the phosphoglycerate kinase gene analysis. Of the 4 small tumors, 2 showed monoclonal, and 2 showed polyclonal patterns. The 2 with monoclonal patterns were pathologically diagnosed as hepatocellular carcinoma despite their small sizes (20 mm and 23 mm). Of the two with polyclonal patterns, the smallest one (15 mm) was diagnosed as benign adenomatous hyperplasia, and the other as hepatocellular carcinoma heavily infiltrated by lymphocytes. These data suggest that analysis of the methylation pattern of the phosphoglycerate kinase gene may be helpful on rare occasions in elucidating the nature of liver tumors but must in fact be used in conjunction with histological appearances to avoid errors secondary to inflammatory infiltrates. 相似文献
970.