Novel design and simulation of reversible ALU in quantum dot cellular automata

The Journal of Supercomputing - Quantum dot cellular automata (QCA) technology is considered as one of the most suitable replacements to reduce the CMOS-based digital circuit design problems at the...     

Adaptive discrete-time sliding-mode control of nonlinear systems described by Wiener models

In this paper, we propose an adaptive control scheme that can be applied to nonlinear systems with unknown parameters. The considered class of nonlinear systems is described by the block-oriented models, specifically, the Wiener models. These models consist of dynamic linear blocks in series with static nonlinear blocks. The proposed adaptive control method is based on the inverse of the nonlinear function block and on the discrete-time sliding-mode controller. The parameters adaptation are performed using a new recursive parametric estimation algorithm. This algorithm is developed using the adjustable model method and the least squares technique. A recursive least squares (RLS) algorithm is used to estimate the inverse nonlinear function. A time-varying gain is proposed, in the discrete-time sliding mode controller, to reduce the chattering problem. The stability of the closed-loop nonlinear system, with the proposed adaptive control scheme, has been proved. An application to a pH neutralisation process has been carried out and the simulation results clearly show the effectiveness of the proposed adaptive control scheme.     

A recursive hierarchical parametric estimation algorithm for nonlinear systems described by Wiener‐Hammerstein models

In this paper, a recursive hierarchical parametric estimation (RHPE) algorithm is proposed for stochastic nonlinear systems which can be described by Wiener‐Hammerstein (W‐H) mathematical models. The formulation of parameters estimation problem is based on the prediction error approach and the gradient techniques. The convergence analysis of the developed RHPE algorithm is derived using stochastic gradient‐based theory. Wiener‐Hammerstein hydraulic process is treated to prove the efficiency of the proposed approach.     

Robust self-tuning control based on discrete-time sliding mode for auto-regressive mathematical model in the presence of unmodelled dynamics

In this paper, we propose a new robust self-tuning control, called the generalized minimum variance αl-equivalent selftuning control (GMVSTC-αl) for the linear timevarying (LTV) systems, which can be described by the discrete-time auto-regressive exogenous (ARX) mathematical model in the presence of unmodelled dynamics. The estimation of the parameters contained in this mathematical model is made on the basis of the proposed modified recursive least squares (m-RLS) parametric estimation algorithm with dead zone and forgetting factor. The stability analysis of the proposed parametric estimation algorithm m-RLS is treated on the basis of a Lyapunov function. A numerical simulation example is used to prove the performances and the effectiveness of the explicit scheme of the proposed robust self-tuning control GMVSTC-αl.     

Disperse-within-disperse patterning on ternary/binary mixed-brush single crystals using polyaniline,polystyrene and poly(methyl methacrylate) grafts

Novel binary rod-coil and ternary rod-coil-coil mixed-brushes were designed using poly(ethylene glycol) (PEG)-b-poly(styrene) (PS), PEG-b-poly(methyl methacrylate) (PMMA), and PEG-b-polyaniline (PANI) block copolymers. In the current rod-coil mixed-brushes, the brush osmotic pressure did not absolutely affect the surface morphology, instead, the rigidity or flexibility of brushes was a dominant factor. The flexibility of coily PS brushes caused them to be easily entered into the system compared to the rod brushes with higher osmotic pressure, thereby they composed the matrix phase. In a similar growth condition but with packed pancake PMMA brushes, a more faise osmotic pressure was detected for PANI nanorods in the vicinity of PMMA brushes compared to PS ones. A higher faise osmotic pressure for PANI nanorods reflected the lower diameter dispersity and population of PANI nanorods in PEG-b-PMMA/PEG-b-PANI compared to PEG-b-PS/PEG-b-PANI. Via enhancing the amorphous brushes molecular weight, in a constant PANI nanorods molecular weight, the diameter dispersity and population of PANI nanorods increased. The PANI nanorods diameter in binary PS/PANI and PMMA/PANI mixed-brushes ranged in 6–10 nm. With elevating the crystallization temperature, no changes were detected in the morphology of rod-coil mixed-brush single crystals. In the novel ternary mixed-brushes with the amorphous PS and PMMA brushes and the PANI nanorods, the PANI nanorods were dispersed within both matrix (PS) and disperse (PMMA) phases. In these systems, the PANI diameters were 6 and 7 nm in PMMA disperses and 6–9 nm in PS matrix phase. The overall PANI nanorods population was in the range of 594–1392 for binary mixed-brushes. Furthermore, in ternary structures, the PANI overall populations were about 222 and 316 in PMMA and PS phases, respectively. Generally, in all binary and ternary mixed-brush systems, the amorphous brushes (PS and PMMA), due to their flexibility could be arranged in the vicinity of each other in a more facile manner compared to the PANI nanorods, they thus developed matrix phase.

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Graphical abstract The mixed-brush single crystals were carefully patterned with double rod-coil and triple rod-coil-coil grafted polymer chains

     

Assessment of thermal,morphological, and mechanical properties of poly(methyl methacrylate)/glass flake composites

In this work, poly(methyl methacrylate)/(glass flake) (GF) composites were prepared with different compositions via melt mixing. The effect of the filler ingredient on thermal behavior, morphology, and mechanical and optical properties was investigated by using various techniques, namely differential scanning calorimetry, ultraviolet‐visible spectra, mechanical testing, and scanning electron microscopy. For evaluating the level of dispersion of particles, energy dispersive X‐ray analysis was performed. Differential scanning calorimetry analysis showed that the glass transition temperature of the samples slightly increased by increasing GF content. Scanning electron microscopy images showed that sized flakes were uniformly dispersed within poly(methyl methacrylate). Energy dispersive X‐ray analysis images of samples with different inclusions of GFs showed that the appearance of white dense spots represents the GF particles. It was found that the presence of 0.5 wt% of GF in composites gave more transparency than the other compositions. Furthermore, this composition indicated maximum tensile strength and elongation‐at‐break values in comparison with the other compositions. J. VINYL ADDIT. TECHNOL., 23:62–69, 2017. © 2015 Society of Plastics Engineers     

A probe into the status quo of interfacial adhesion in the compatibilized ternary blends with core/shell droplets: Selective versus dictated compatibilization

A simple approach was applied to probe into the situation of interfacial adhesion in the compatibilized ternary polymer blends with core/shell morphology. The performance of compatibilization was discussed in terms of thermal, rheological, and mechanical properties analyses for blends prepared through different mixing strategies for which maleic anhydride‐grafted high‐density polyethylene (HDPE‐g‐MAH) could be localized at the interface of HDPE/poly(ethylene‐co‐vinyl alcohol) copolymer (EVOH) or HDPE/polyamide 6 (PA‐6) in their ternary blends. Two mixing strategies, one simultaneously (one‐step or selective) and two sequentially (two‐step or dictated), were performed, compared, and discussed. It was found that mixing policy (dictated or selective) significantly changes the interfacial adhesion, as signaled by variations in rheological and thermal properties. In the case of mechanical properties, facilitation of stress transfer across the matrix/shell/core interfaces was detected by calculation of semi‐experimental models' coefficients. It was found that one‐step mixing or selective localization of HDPE‐g‐MAH helps in accumulation of more compatibilizer molecules at the interface HDPE/EVOH or EVOH/PA‐6. By contrast, addition of compatibilizer to minor phase (masterbatch of EVOH and PA‐6) or to HDPE matrix alone in case of two‐step blending causes imperfect stress transfer. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 45503.     

Pervaporation properties of polypyrrolidinone‐based membranes for EtOH/ETBE mixtures separation

The separation of ethanol/ethyl‐tertiobutylether mixtures by pervaporation was studied with new membranes prepared from N‐vinyl‐pyrrolidinone (NVP) and N‐[3‐(trimethylamoniopropyl)]methacrylamidemethylsulfate) (TMA). The pervaporation results showed that highly EtOH selective membranes could be obtained from PVP blends and from pyrrolidinone‐based crosslinked copolymers. The influences of the polymer blend composition and the role of the polymer microstructures on the membrane properties were investigated. Whatever the exact NVP/TMA composition used, the membranes strongly favored the pervaporation of ethanol. The ethanol selectivity was higher for the lower PVP/TMA ratio. On the one hand, these results were ascribed to the high pyrrolidinone residues content, which is responsible of the enhanced EtOH sorption affinity. The observed permeation selectivity was in agreement with the swelling data also recorded with the different polymers, showing higher affinity for ethanol with PVP‐enriched materials compared with TMA ones. This is a direct consequence of the Lewis base feature of pyrrolidinone sites towards EtOH molecules. On the other hand, the TMA residues improved the overall stability and selectivity of the membranes thanks to crosslinking reactions, which were induced by thermal treatment. A close comparison made between polymer blend and copolymer pervaporation results helped to clarify the TMA role of the membrane transport properties. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99:3622–3630, 2006     

Towards an immortal operating system in virtual environments

Many OS crashes are caused by bugs in kernel extensions or device drivers while the OS itself may have been tested rigorously. To make an OS immortal we must resurrect the OS from these crashes. We present a novel OS-hypervisor infrastructure that allows automated and transparent OS crash diagnosis and recovery in a virtual environment. This infrastructure eliminates the need for reboots or checkpoint-restart mechanisms, which require preserving the states of critical applications before the crash happens and also require extensive modifications to those applications. At the core of our approach is a small hidden OS-repair-image that is dynamically created from the healthy running OS instance. When an OS crashes, the hypervisor dynamically loads this repair-image to perform diagnosis and repair. One way of repair we have experimented with, is to quarantine the offending process and resume the running of the fixed OS automatically without a reboot. Experimental evaluations demonstrated that it takes less than 3 s to recover from an OS crash. This approach can significantly reduce the downtime and maintenance costs in data centers, and is the first design and implementation of an OS-hypervisor combo capable of automatically resurrecting a crashed commercial server-OS. In addition to online diagnosis and recovery, this infrastructure can also be used for offline diagnosis and can be incorporated into the technical support tools of the OS vendor. Additionally, we have used parts of this infrastructure to speed-up the diagnosis of AIX OS-crashes for the IBM technical support teams.     

Anchoring of Copper(II) Schiff Base Complex into Aminopropyl-Functionalised MCM-41: A Novel,Efficient and Reusable Catalyst for Selective Oxidation of Alcohols

A copper(II) complex containing tetradentate N₂O₂ Schiff base ligand immobilized into aminopropyl-functionalised MCM-41 (mobile crystalline material number 41), was prepared and characterized by Fourier-transform infrared, X-ray diffraction, scanning electron microscopy, thermogravimetric analysis, N₂ adsorption–desorption and inductively coupled plasma analysis techniques. The novel heterogeneous catalyst, MCM-41-pr-NH₂-CuL, can be successfully applied for efficient and selective oxidation of different primary and secondary alcohols to the corresponding carbonyl compounds using hydrogen peroxide as an oxidant in acetonitrile at 60 °C. The effect of reaction parameters such as solvent, amount of catalyst, temperature and kind of oxidant on the oxidation of benzyl alcohol was also studied. The prepared catalyst could be recovered and reused four times without important loss of its catalytic performance. The heterogeneous MCM-41-pr-NH₂-CuL catalyst was found to be catalytically more active in the oxidation of alcohols compared to the similar type of copper(II) Schiff base complex in homogeneous media under the same reaction conditions.