Correlation of polymerization conditions with drag reduction efficiency of poly(1-hexene) in oil pipelines

High molecular weight with long linear side branches are frequently used in oil pipelines as one of the main classes of drag reducer agents (DRAs). We studied the effects of polymerization conditions, including reaction temperature, monomer concentration and cocatalyst concentration ratio (Al/Ti), on the polymerization yield and molecular weight of the resultant poly(1-hexene) made by Ziegler–Natta catalyst and their consequent effects on the drag reduction efficiency in a loop test. The experimental results verified that the catalyst activity increased from 115 to 220 kgPH/molTi.atm, while the molecular weight of poly(1-hexene) dropped from 2100 to 1030 kDa, as the reaction temperature was increased from 0 to 50 °C. The loop test results also revealed that the highest pressure drop was achieved using the polymer synthesized at 0 °C and by subsequent increase in reaction temperature the pressure drop decreased. Furthermore, the catalyst activity increased from 143 to 262 kgPH/molTi.atm by increasing Al/Ti ratio, while the molecular weight increased up to a maximum level of 1500 kDa at Al/Ti = 143 and decreased at higher cocatalyst contents. Similarly, the results showed the maximum pressure drop of 20 % at Al/Ti = 143. Finally, by increasing monomer concentration, the catalyst activity and polymer molecular weight increased from 75 to 262 kgPH/molTi.atm for the former, and from 700 to 1800 kDa for the latter which resulted in maximum pressure drop by 25 %. Moreover, the pressure drop for each utilized poly(1-hexene) was increased proportionately with DRA’s concentration, and interestingly enough, DRAs were further effective at more turbulent flows with higher Reynolds numbers.     

真空感应熔炼炉真空度对Ni-Fe-Cr基合金力学性能的影响(英文)

为研究真空感应熔炼炉的真空度对Ni-Fe-Cr基合金力学性能的影响,在不同真空度条件下制备 4 个样品。化学分析结果表明:在氩气保护气氛下,Al和Ti的损耗较多,而在真空条件下其损耗较少。气体分析结果表明:样品中氧和氮的含量随真空度的增加而降低。而在更高的真空度下,样品中的氧和氮则没有损耗。热力学计算表明:由于平衡的氧含量值较低,TiO2和Al2O3生成的可能性高。高真空度使合金的拉伸强度和屈服强度降低,但是由于少量的杂质以及Al和Ti的损耗,合金的伸长率和断面收缩率增加。此外,提高真空度使合金由脆性断裂转变为韧性断裂。     

中间层成分对GTD-111/IN-718高温合金在瞬时液相连接过程中显微组织和力学性能的影响

研究使用不同的中间层瞬时液相连接两种异种高温合金的适用性.在1100℃、不同时间下瞬时液相连接GTD-111/IN-718体系,研究BNi-2、BNi-3和BNi-9三种类型的中间层对该体系显微组织和力学性能的影响.采用场发射扫描电子显微镜和能量色散光谱技术,研究接头区域的成分变化和显微组织.结果表明,非热凝固区Ni3...     

The effect of ethane on the performance of commercial polyphenylene oxide and Cardo-type polyimide hollow fiber membranes in CO<Subscript>2</Subscript>/CH<Subscript>4</Subscript> separation applications

Impurities such as hydrogen sulfide, water vapor and heavy hydrocarbons in natural gas have considerable effects on the membrane performance. Small amounts of condensable and polymer soluble components in the feed gas cause swelling or plasticization of glassy membranes, leading to a reduction in membrane selectivity. In the present research the influence of ethane was investigated on the permeance and selectivity of two commercially available hollow fiber membranes, namely Cardo-type polyimide and PPO hollow fibers for CO₂/CH₄ separations. It was concluded that the gas mixture permeation rate was increased in the presence of C₂H₆. However, the CO₂/CH₄ separation factors remained almost the same in the presence and absence of the C₂H₆.     

Age-induced multi-stage transformation in a Ni-rich NiTiHf alloy

Abnormal multi-stage transformations have already been studied in binary Ni-rich NiTi alloys. In this research, this kind of transformation was investigated in a low supersaturated Ni-rich ternary NiTiHf high-temperature shape memory alloy by aging at intermediate temperatures for various durations. Meticulous examinations of the results of differential scanning calorimetry tests demonstrated the heterogeneous precipitation of (Ti,Hf)₃Ni₄ particles and the three-stage transformation (one-stage R and two-stage B19′) in the aged alloy. Aging provided a significant rise in transformation temperatures (TTs) until they reached their equilibrium states, corresponding to the equilibrium Ni content at each aging temperature. Equilibrium TTs were higher when aging was performed at a lower temperature. The remarkable increase in TTs was compared with those in aged Ni-rich NiTi alloys, and discussed based on the variation in valence electron concentration. A model was also proposed for the microstructural evolution during aging. Furthermore, aging provided enhanced hardness and strain recovery for the alloy. In particular, aging at a lower temperature resulted in a considerable improvement in hardness and shape recovery, which was discussed based on the microstructural changes in the aged alloy. Equilibrium Ni content at each aging temperature proved to be a crucial parameter in controlling the alloy properties, even in heterogeneous precipitations.     

Nonlinear Interval Parameter Programming Combined with Cooperative Games: a Tool for Addressing Uncertainty in Water Allocation Using Water Diplomacy Framework

Water Resources Management - This paper shows the utility of a new interval cooperative game theory as an effective water diplomacy tool to resolve competing and conflicting needs of water users...     

Optimizing environmental flow regime by integrating river and reservoir ecosystems

Water Resources Management - The present study develops a novel form of optimization framework to assess environmental flow in the reservoirs in which upstream and downstream river ecosystems and...     

Determining the Main Factors in Declining the Urmia Lake Level by Using System Dynamics Modeling

Urmia Lake in Iran is the second largest saline lake in the world. This ecosystem is the home for different species. Due to various socio-economical and ecological criteria, Urmia Lake has important role in the Northwestern part of the country but it has faced many problems in recent years. Because of droughts, overuse of surface water resources and dam constructions, water level has decreased in such a way that one quarter of the lake has changed to saline area in the last 10 years. The purpose of this research is to determine the main factors which reduce the lake’s water level. To this end, a simulation model, based on system dynamics method, is developed for the Urmia Lake basin to estimate the lake’s level. After successful verification of the model, results show that (among the proposed factors) changes in inflows due to the climate change and overuse of surface water resources is the main factor for 65% of the effect, constructing four dams is responsible for 25% of the problem, and less precipitation on lake has 10% effect on decreasing the lake’s level in the recent years. In the future, the model also can be used by managers as a decision support system to find the effects of building new dams or other infrastructures.     

Monitoring the aging of beers using a bioelectronic tongue

This paper deals with the implementation and the application of a bioelectronic tongue including three enzymatic biosensors based on tyrosinase and phthalocyanines as electron mediators, to evaluate the changes that occur during the aging of beers. For this purpose, alcoholic and non alcoholic beers, packaged in can and bottle, have been analyzed using cyclic voltammetry. The electrochemical signals showed significant changes during the aging process. The features extracted from the cyclic voltammograms have been used to perform Principal Component Analysis (PCA) and Linear Discriminant Analysis (LDA). Data have revealed a clear discrimination among the beer classes in the aging process and the results were confirmed by Probabilistic Neural Networks (PNN) with Radial Basis Functions (RBF) and FeedForward Networks with Backpropagation (BP) learning method. The bioelectronic tongue has demonstrated a good capability to discriminate and classify the beer types satisfactorily in such a way, for all beer treatments, full classification accuracy was found.