Analyzing the efficiency of nanostructured Sm3+- and Gd3+-doped TiO2 and constructing DSSCs using efficacious photoanodes

The rare earth elements, gadolinium and samarium, are doped with TiO₂ by hydrothermal synthesis technique to study the photoconversion performance of a photoanode in a dye-sensitized solar cell (DSSC). The obtained materials are subjected to the characterizations XRD, HR-TEM, UV–Vis spectroscopy, and XPS. DSSCs are fabricated using N719 dye, redox electrolyte, and platinum counter electrode. Charge-transfer ability was investigated using electrochemical impedance spectroscopy (EIS) on DSSCs. The efficiencies of DSSCs are influenced by the electron transport within the TiO₂–dye–electrolyte system. After the fabrication and simulation, among the two, Gd³⁺-doped TiO₂ gives the desired outcomes and higher efficiency (5.542%) than the pure and Sm³⁺-doped TiO₂ and thus it proves to be a superior solar cell anode material.

     

Spontaneous programmed cell death in infiltrating duct carcinoma: association with p53, BCL-2, hormone receptors and tumor proliferation

Recent evidence has emphasized the importance of programmed cell death or apoptosis in the maintenance of tissue homeostasis and pathogenesis of tumors. This study, analyzed in breast cancer, investigates the significance of apoptosis in relation to the expression of p53 and bcl-2 proteins, tissue proliferation defined by Ki-67 expression, hormone receptors and tumor grade. The extent of apoptosis was defined by morphological criteria and the TUNEL (Tdt-mediated dUTP biotin nick end labelling) assay. Immunocytochemistry was performed for p53, bcl-2, estrogen receptor, progesterone receptor and Ki-67 expression. Mutant p53 protein was detected using a mutant specific ELISA. Immunoreactivity of p53 significantly correlated with the presence of mutant p53 protein detected by ELISA (r = 0.654, p = 0.00001). An inverse correlation was observed between bcl-2 expression and the extent of apoptosis (r = -0.33369, p = 0.01912). The extent of apoptosis directly correlated with p53 protein accumulation (r = 0.485, p = 0.00041), Ki-67 immunoreactivity (r = 0.435, p = 0.001), histopathological grade (r = 0.492, p = 0.0003), tumor size (r = 0.326, p = 0.023) and lymph node status (r = 0.287, p = 0.047). A direct correlation was also observed between p53 expression and Ki-67 immunoreactivity (r = 0.623, p = 0.0002). There was no statistically significant association between estrogen and progesterone receptor status and apoptosis. In addition, the TNM stage of the disease correlated with immunoreactivity of p53 (r = 0.572, p = 0.00012) and Ki-67 (r = 0.3744, p = 0.00818). Bcl-2, by inhibiting apoptosis, may cause a shift in tissue kinetics towards the preservation of genetically aberrant cells, thereby facilitating tumor progression. These results imply that rapidly proliferating tumors appear to have a high "cell turnover state" in which there may be an increased chance of apoptosis amongst the proliferating cells. The ability of apoptosis to also occur in the presence of mutant p53 protein suggests the existence of at least two p53-dependent apoptotic pathways, one requiring activation of specific target genes and the other independent of it.     

UNDERSTANDING OF FINITE ELEMENT ANALYSIS RESULTS UNDER THE FRAMEWORK OF OXLEY'S MACHINING MODEL

We introduce an accurate coupled thermo-mechanical finite element analysis (FEA) of machining using the Arbitrary Lagrangian Eulerian (ALE) analysis capability of ABAQUS/Explicit. This analysis provides detailed information about the cutting forces, chip thickness, contact length, the extent of the primary and secondary shear zones as well as the distribution of strain, strain rate and temperature in the deformation zones. This information has to be viewed under the framework of an analytical model for it to lead to better understanding of the physics of machining. We use the best available analytical model, namely, Oxley's machining model, for this purpose and the FEA results are compared with the assumptions and predictions of Oxley's analysis. The strain rate in the primary shear zone, the hydrostatic pressure variation along the shear plane, the distribution of normal and shear stresses along the tool-chip interface and the shape of the secondary shear zone are the quantities compared. Due to the key role of temperature in the prediction of tool wear, the fraction of heat conducted away into the workpiece, the maximum temperature along the tool-chip interface and the maximum temperature along the flank face are also compared. The comparison reveals that Oxley's model captures the physics of machining quite well. However, some details such as the heat partition module and the assumptions on stress and temperature distribution at the tool-chip interface need to be revisited.     

Buckling of centerline-stiffened plates subjected to uniaxial eccentric compression

A solution for the elastic buckling of flat rectangular plates with centerline boundary conditions subjected to non-uniform in-plane axial compression is presented. The loaded edges are simply supported, the non-loaded edges are free, and the centerline is simply supported with a variable rotational stiffness. The Galerkin method is used to establish an eigenvalue problem and a series solution for plate buckling coefficients is obtained by using combined trigonometric and polynomial functions that satisfy the boundary conditions. It is demonstrated that the formulation approaches the classical solution of a plate with a clamped edge as the variable rotational stiffness is increased. The variation of buckling coefficient with aspect ratio is presented for various stress gradient ratios. The coupling between plate aspect ratio, centerline rotational stiffness, and gradient of applied compressive stress is illustrated and discussed. The solution is applicable to stiffened plates and I-shaped beams that are subjected to biaxial bending or combined flexure and torsion, and is important to estimate the reduction in elastic buckling capacity due to stress gradient.     

Growth of iron diselenide nanorods on graphene oxide nanosheets as advanced electrocatalyst for hydrogen evolution reaction

Advanced electrocatalysts for the fabrication of sustainable hydrogen from water splitting are innermost to energy research. Herein, we report the growth of iron diselenide (FeSe₂) nanorods on graphene oxide (GO) sheets using two-step process viz., simple hydrothermal reduction and followed by wet chemical process. The orthorhombic phase of FeSe₂ incorporated GO nanosheet was developed as a low-cost and efficient electrocatalyst for hydrogen evolution reaction (HER) by water splitting. The phase purity, crystalline structure, surface morphology and elemental composition of the synthesized samples have been investigated by UV–visible absorption spectroscopy (UV–vis), fourier transform-infrared spectroscopy (FT-IR), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and energy dispersive X-ray analysis (EDS). Voltammetry and Tafel polarization methods have been utilized to assess the performance of various weight ratio of GO nanosheet in FeSe₂ nanorods towards H₂ evolution. Detailed electrochemical investigations revealed that the 30% FeSe₂/GO composite showed a tremendous electrocatalytic HER activity in acidic medium with high cathodic current density of 9.68 mA/cm² at η = 250 mV overpotential and with a Tafel slope of 64 mV/dec. The 30% FeSe₂/GO composite offers a high synergistic effect towards HER activity, which is mainly due to high electrochemical active catalytic sites, low charge-transfer resistance and enhanced electrocatalytic performances of H₂ production. The present analysis revealed the possible application of FeSe₂/GO composite as a promising low-cost alternative to platinum based electrocatalysts for H₂ production.     

Effect of nano additives (titanium and zirconium oxides) and diethyl ether on biodiesel-ethanol fuelled CI engine

The present work is dedicated to the comparative experimental study of biodiesel-ethanol blends in a compression ignition engine using TiO₂ (Titanium oxide) nanoparticle, ZrO₂ (Zirconium oxide) nanoparticle and DEE (Diethyl ether) additives. The test fuels used are a blend of biodiesel (80%) -ethanol (20%) (denoted as BE), a blend of BE with 25 ppm Titanium oxide nanoparticle (denoted as BE-Ti), a blend of BE with 25 ppm Zirconium oxide nanoparticle (denoted as BE-Zr) and a blend of BE with 50 ml Diethyl ether (denoted as BE-DEE). Addition of nanoparticles increases the oxidation rate, reduces the light-off temperature and creates large contact surface area with the base fuel thereby enhancing the combustion with minimal emissions. Experimental results shown that addition of Titanium nanoparticles increased NOx, HC and smoke with lowered BSFC and CO. Whereas addition of Zirconium nanoparticles increases BSFC and HC emissions with lowered CO, CO₂ and smoke emissions in comparison with BE blends. DEE addition to BE blends improved the heat release rate and increased HC, CO emissions were observed with lowered BSFC, NOx and smoke. Simultaneous reduction of NOx and smoke indicates the effect of DEE on Low temperature combustion (LTC).

     

An algorithm for recognizing palm polygons

A polygonP is said to be apalm polygon if there exists a pointxP such that the Euclidean shortest path fromx to any pointyP makes only left turns or only right turns. The set of all such pointsx is called thepalm kernel. In this paper we propose an O(E) time algorithm for recognizing a palm polygonP, whereE is the size of the visibility graph ofP. The algorithm recognizes the given polygonP as a palm polygon by computing the palm kernel ofP. If the palm kernel is not empty,P is a palm polygon.The extended abstract of this paper was reported at the Second Canadian Conference in Computational Geometry, pp. 246–251, 1990     

Similarities and differences between human–human and human–automation trust: an integrative review

The trust placed in diagnostic aids by the human operator is a critical psychological factor that influences operator reliance on automation. Studies examining the nature of human interaction with automation have revealed that users have a propensity to apply norms of human–human inter-personal interaction to their interaction with ‘intelligent machines’. Nevertheless, there exist subtle differences in the manner in which humans perceive and react to automated aids compared to human team-mates. In the present paper, the concept of trust in human–automation dyads is compared and contrasted with that of human–human dyads. A theoretical framework that synthesizes and describes the process of trust development in humans vs automated aids is proposed and implications for the design of decision aids are provided. Potential implications of this research include the improved design of decision support systems by incorporating features into automated aids that elicit operator responses mirroring responses in human–human inter-personal interaction. Such interventions will likely facilitate better quantification and prediction of human responses to automation, while improving the quality of human interaction with non-human team-mates.     

Effect of Annealing Temperature in Al 1145 Alloy Sheets on Formability, Void Coalescence, and Texture Analysis

This paper deals with a combined forming and fracture limit diagram and void coalescence analysis for the aluminum alloy Al 1145 alloy sheets of 1.8 mm thickness, annealed at four different temperatures, namely 200, 250, 300, and 350 °C. At different annealing temperatures these sheets were examined for their effects on microstructure, tensile properties, formability, void coalescence, and texture. Scanning electron microscope (SEM) images taken from the fractured surfaces were examined. The tensile properties and formability of sheet metals were correlated with fractography features and void analysis. The variation of formability parameters, normal anisotropy of sheet metals, and void coalescence parameters were compared with texture analysis.     

Modified medial displacement and valgus osteotomy for unstable intertrochanteric fractures

We have described previously a modification of the medial displacement and valgus osteotomy of Dimon and Hughston to manage non-unions of intertrochanteric fractures. In this study, we have used the same modification to manage fresh, unstable intertrochanteric fractures. Eighty-seven patients underwent this procedure. Four died within 4 months. The remaining 83 patients were evaluated over a period ranging from 4 to 49 months. There was a low complication rate with this method. They included one perforation of the femoral head, one post operative infection that recurred as a deep infection, one partial superior migration of the implant, one varus fixation with noticeable shortening and two cases where the trochanteric wire had snapped. In the others, the hip movement, abductor function, functional recovery and rate of union (8-12 weeks) were good. The method permits early weight-bearing and avoids some of the problems seen with anatomical fixation of unstable fractures using the sliding screw plate. We feel that medial displacement and valgus osteotomy with an angled blade plate has a definite role in the treatment of unstable intertrochanteric fractures in some situations.