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排序方式: 共有237条查询结果,搜索用时 15 毫秒
81.
82.
H. Rached D. Rached S. Benalia A.H. Reshak M. Rabah R. Khenata S. Bin Omran 《Materials Chemistry and Physics》2013
The structural stabilities, elastic and electronic properties of 5d transition metal mononitrides (TMNs) XN with (X = Ir, Os, Re, W and Ta) and 5d transition metal monocarbides (TMCs) XC with (X = Ir, Os, Re and Ta) were investigated using the full-potential linear muffin-tin orbital (FP-LMTO) method, in the framework of the density functional theory (DFT) within the local density approximation (LDA) for the exchange correlation functional. The ground state quantities such as the lattice parameter, bulks modulus and its pressure derivatives for the six considered crystal structures, Rock-salt (B1), CsCl (B2), zinc-blend (B3), Wurtzite (B4), NiAs (B81) and the tungsten carbides (Bh) are calculated. The elastic constants of TMNs and TMCs compounds in its different stable phases are determined by using the total energy variation with strain technique. The elastic modulus for polycrystalline materials, shear modulus (G), Young's modulus (E), and Poisson's ratio (ν) are calculated. The Debye temperature (θD) and sound velocities (vm) were also derived from the obtained elastic modulus. The analysis of the hardness of the herein studied compounds classifies OsN – (B4 et B81), ReN – (B81), WN – (B81) and OsC – (B81) as superhard materials. Our results for the band structure and densities of states (DOS), show that TMNs and TMCs compounds in theirs energetically and mechanically stable phase has metallic characteristic with strong covalent nature Metal–Nonmetal elements. 相似文献
83.
84.
Bijal Kottukkal Bahuleyan Muataz Ali Atieh Sadhan Kumar De Masihullah Jabarulla Khan Mamdouh A. Al-Harthi 《Journal of Polymer Research》2012,19(2):9744
An easy one pot method is demonstrated for the controlled periodical surface coating of polyethylene over multiwalled carbon
nanotubes (MWCNT) by insitu polymerization of ethylene using highly active metallocene catalysts (Cp2ZrCl2 and Cp2TiCl2) in combination with methylalumoxane. The crystallinity of the nanocomposite was increased and its morphology could be tuned
from “sausage” like to “shish-kebab” in the presence of CNT depending on the experimental condition and choice of metal atom. 相似文献
85.
Muhammad Shahzad Kamal Bijal Kottukkal Bahuleyan Omer Bin Sohail Abdul-Hamid M. Emwas John E. Bercaw Mamdouh A. Al-Harthi 《Polymer Bulletin》2013,70(9):2645-2656
Ethylene homo polymer and ethylene–styrene copolymers were synthesized using Cp2ZrCl2 (1)/methyl aluminoxane (MAO) and rac-silylene-bis (indenyl) zirconium dichloride (2)/MAO catalyst systems by varying styrene concentration and reaction conditions. Crystallization analysis fractionation (CRYSTAF), DSC, FTIR and 1H NMR spectroscopy were used for characterizing the synthesized polymers. Interestingly, styrene was able to increase the activity of 1/MAO and 2/MAO catalyst systems at low concentrations, but at higher concentrations the activity decreases. The 1/MAO system at low and high pressure was unable to incorporate styrene, and the final product was pure polyethylene. On the other hand, with 2/MAO polymerization of ethylene and styrene yielded copolymer containing both styrene and ethylene. Results obtained from CRYSTAF and DSC reveal that on using 1/MAO system at high pressure, the resulting polymer in the presence of styrene has similar crystallinity as the polymer produced without styrene. Using both 1/MAO at low pressure and 2/MAO leads to decrease in crystallinity with increase in styrene concentration, even though the former does not incorporate styrene. 相似文献
86.
Abdel-Nasser Omran Kee-Do Woo Hyun Bom Lee 《Metallurgical and Materials Transactions A》2012,43(12):4866-4874
A developed Ti-35?pct Nb-2.5?pct Sn (wt pct) alloy was synthesized by mechanical alloying using high-energy ball-milled powders, and the powder consolidation was done by pulsed current activated sintering (PCAS). The starting powder materials were mixed for 24 hours and then milled by high-energy ball milling (HEBM) for 1, 4, and 12 hours. The bulk solid samples were fabricated by PCAS at 1073?K to 1373?K (800 °C to 1100 °C) for a short time, followed by rapid cooling to 773?K (500 °C). The relative density of the sintered samples was about 93?pct. The Ti was completely transformed from ?? to ??-Ti phase after milling for 12 hours in powder state, and the specimen sintered at 1546?K (1273 °C) was almost transformed to ??-Ti phase. The homogeneity of the sintered specimen increased with increasing milling time and sintering temperature, as did its hardness, reaching 400?HV after 12 hours of milling. The Young??s modulus was almost constant for all sintered Ti-35?pct Nb-2.5?pct Sn specimens at different milling times. The Young??s modulus was low (63.55 to 65.3 GPa) compared to that of the standard alloy of Ti-6Al-4V (100 GPa). The wear resistance of the sintered specimen increased with increasing milling time. The 12-hour milled powder exhibited the best wear resistance. 相似文献
87.
88.
Nasser H. Shalaby Samia A. Hanafi Salah A. Hassan Mamdouh S. Elmelawy 《Petroleum Chemistry》2018,58(5):387-394
Waste aluminum foil was used for preparation of mesoporous TiO2-Al2O3 using starch as a textural modifier. The catalytic species, Mo and Ni or Co were loaded onto the mesoporous support, following incipient wetness sequential impregnation. To gain an insight into the pore dimensions effect, Ni and Mo species with the same mass ratio were loaded onto the TiO2-Al2O3, prepared from analytical grade chemicals without templating. TPR spectra, TEM images and BET analysis showed how the promoter (Ni or Co), TiO2 and the template (starch) affect the ease of reduction of Mo species, the morphology of the active MoS2 phase and the pore dimensions of the catalysts. The catalysts were employed in hydro-desulfurization process of gas oil using a fixed bed down flow microreactor at varying operating conditions, viz., temperature (320–400°C), Liquid hourly space velocity (0.5–4 h–1), H2/oil ratio of 450 v/v, and 6 MPa operating pressure. The results showed that the promotion effect prevails over the textural effect, where Ni promoted catalyst (with lower surface parameters) exhibits higher activity than Co promoted one. The dual layer catalytic bed system achieved the sulfur level less than 10 ppm. 相似文献
89.
Integration of geophysical and geochemical approaches is used for qualitative and quantitative evaluation of source rocks. The Upper Jurassic rocks in the Sayun-Masila basin are used as a case study due to its high hydrocarbon potentiality. Stratigraphically, these rocks could be differentiated from base to top into: Shuqra, Madbi and Nayfa formations. The total organic carbon (TOC) values were determined in the shale and/or carbonate intervals of these formations from four studied wells by the ΔlogR method using sonic, resistivity and gamma-ray log data. Then the discriminant analysis was applied in differentiating source from non-source rocks. Also, the effect of the burial and thermal histories on the organic material maturation and the oil and/or gas generation was studied through the application of two analytical methods, namely, the level of organic metamorphism (LOM) and the time-temperature index (TTI), depending on the corrected temperature logs integrated with the time and depth data. The reliability of the obtained results has been confirmed and combined with the results supplied from geochemical analyses. The Upper Jurassic sediments are found to be oil–prone source rock in a mature stage. The Madbi Formation is considered as the most effective source rock. The burial and thermal histories of the basin in four modeled wells showed that mature oil generation window and hydrocarbon expulsion would have been initiated in the depocenters from Upper Jurassic Madbi Formation source rock during Late Cretaceous to Middle Miocene time. 相似文献
90.