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Rafael Schmitt Markus Kubicek Eva Sediva Morgan Trassin Mads C. Weber Antonella Rossi Herbert Hutter Jens Kreisel Manfred Fiebig Jennifer L. M. Rupp 《Advanced functional materials》2019,29(5)
Memristive devices based on mixed ionic–electronic resistive switches have an enormous potential to replace today's transistor‐based memories and Von Neumann computing architectures thanks to their ability for nonvolatile information storage and neuromorphic computing. It still remains unclear however how ionic carriers are propagated in amorphous oxide films at high local electric fields. By using memristive model devices based on LaFeO3 with either amorphous or epitaxial nanostructures, we engineer the structural local bonding units and increase the oxygen‐ionic diffusion coefficient by one order of magnitude for the amorphous oxide, affecting the resistive switching operation. We show that only devices based on amorphous LaFeO3 films reveal memristive behavior due to their increased oxygen vacancy concentration. We achieved stable resistive switching with switching times down to microseconds and confirm that it is predominantly the oxygen‐ionic diffusion character and not electronic defect state changes that modulate the resistive switching device response. Ultimately, these results show that the local arrangement of structural bonding units in amorphous perovskite films at room temperature can be used to largely tune the oxygen vacancy (defect) kinetics for resistive switches (memristors) that are both theoretically challenging to predict and promising for future memory and neuromorphic computing applications. 相似文献
23.
Electron cyclotron heating (ECH) is one of the main candidates for heating and current drive on ITER (170 GHz) and W7-X (140 GHz). High unit power (1 MW or greater) and high efficiency single-mode continuous-wave (CW) gyrotrons are under development in order to reduce significantly the systems costs. Face-cooled double-disk sapphire and silicon nitride windows (FC-75 liquid cooling), cryogenically edge-cooled single-disk sapphire (liquid nitrogen, liquid neon or liquid helium cooling) and silicon (230 K refrigerator cooling) windows, water-edge-cooled single-disk CVD-diamond windows and water-cooled distributed windows are being investigated in order to solve the window problem. A water-cooled window has two very important advantages; it employs a cheap and effective coolant and it is compact and probably more reliable than other solutions and thus can also be easily used as a torus window. The present paper summarizes the development status of high-power millimeter-wave windows with emphasis on CVD diamond. 相似文献
24.
Based on different current long-term energy scenarios the paper discusses the future perspectives of hydrogen in the German energy system as a representative example for the development of sustainable energy systems. The scenario analysis offers varying outlines of the future energy system that determine the possible role of hydrogen. The paper discusses the possibilities of expanding the share of renewable energy and the resulting prospects for establishing clean hydrogen production from renewable energy sources. Emphasis is given to the questions of an ecologically efficient allocation of limited renewable energy resources that can only be assessed from a systems analysis perspective. Findings from recent studies for Germany reveal a strong competition between the direct input into the electricity system and an indirect use as fuel in the transport sector. Moreover, the analysis underlines the paramount importance of reducing energy demand as the inevitable prerequisite for any renewable energy system. 相似文献
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Synthetic Crystals of Silver with Carbon: 3D Epitaxy of Carbon Nanostructures in the Silver Lattice 下载免费PDF全文
Lourdes G. Salamanca‐Riba Romaine A. Isaacs Melburne C. LeMieux Jiayu Wan Karen Gaskell Yeping Jiang Manfred Wuttig Azzam N. Mansour Sergey N. Rashkeev Maija M. Kuklja Peter Y. Zavalij Jaime R. Santiago Liangbing Hu 《Advanced functional materials》2015,25(30):4768-4777
Only minimum amounts of carbon can be incorporated into silver, gold, and copper in a thermodynamically stable form. Here, the structure of stable silver carbon alloys is described, which are produced by thermoelectrically charging molten silver with carbon ions. Transmission electron microscopy and Raman scattering are combined to establish that large amount of carbon is accommodated in the form of epitaxial graphene‐like sheets. The carbon bonds covalently to the silver matrix as predicted from density functional theory (DFT) calculations with bond energies in the range 1.1–2.2 eV per atom or vacancy. Graphitic‐like sheets embedded in the crystal lattice of silver form 3D epitaxial structures with the host metal with a strain of ≈13% compared to equilibrium graphene. The carbon nanostructures persist upon remelting and resolidification. A DFT‐based analysis of the phonon density of states confirms the presence of intense vibration modes related to the Ag? C bonds observed in the Raman spectra of the alloy. The solid silver–high carbon alloy, termed “Ag‐covetic,” displays room temperature electrical conductivity of 5.62 × 107 S m?1 even for carbon concentrations of up to ≈6 wt% (36 at%). This process of incorporation of carbon presents a new paradigm for electrocharging assisted bulk processing. 相似文献
27.
Arthur H. Heuer Manfred Ruhle David B. Marshall 《Journal of the American Ceramic Society》1990,73(4):1084-1093
Recent evidence is summarized showing that the tetragonal ( t ) → monoclinic ( m ) martensitic transformation in ZrO2 can occur thermoelastically in certain ZrO2 -containing ceramics, and that microcracking accompanying the transformation is more common than had previously been recognized. The implications of these new data for the conditions under which the stress-induced transformation is irreversible, and for the particle size dependence of the transformation start ( M s ), temperature, are discussed. 相似文献
28.
Manfred Wurm 《e & i Elektrotechnik und Informationstechnik》2010,127(6):195-196
Am 9. und 10. Juni 2010 fand in Ulm das "Tutorial Schutz- und Leittechnik 2010" statt, welches vom Forum Netztechnik/Netzbetrieb
im VDE (FNN) und der Energietechnischen Gesellschaft im VDE (ETG) in Zusammenarbeit mit der OGE (?sterreichische Gesellschaft
für Energietechnik im OVE), der ETG von Electrosuisse und Oesterreichs Energie (vormals VE?) veranstaltet wurde. Das Tutorial
war mit rund 300 Teilnehmern sehr gut besucht, was die Aktualit?t der gew?hlten Themen unterstreicht. Die Veranstaltung bestand
aus Plenum-Vortr?gen und -Diskussionen, Workshops sowie einer Fachausstellung und bot dem Fachpublikum auf Hersteller- und
Anwenderseite die Gelegenheit, die aktuellen Entwicklungen auf dem Gebiet der Schutz- und Leittechnik kennen zu lernen, sich
zu informieren und auszutauschen. Zudem war auch eine Postersession in das Programm integriert. 相似文献
29.
ManfredHeld 《兵工学报(英文版)》2005,1(1):1-9
The fundamental protection principles of the new armours for main battle tanks against kinetic energy projectiles(KE) and chemical energy weapons (CE)——shaped charges are shortly described and their efficiency against both threats discussed. The armour topics can be split into: “perpendicular or zero-degree armours”, such as rolled homogeneous armour (RHA), also with extremely high strength, ceramics, glass, liquid filled columns and explosive filled cells,“inclined armours”, as spaced RHA plates with their corner effects, bulging armour, additive and integrated explosive reactive armours (ERA) and “hard kill active defence possibilities” in different defeating distances. 相似文献
30.
Manfred Thumm 《Journal of Infrared, Millimeter and Terahertz Waves》2014,35(12):1011-1017
Megawatt-class gyrotron oscillators for electron cyclotron heating and non-inductive current drive (ECH&CD) in magnetically confined thermonuclear fusion plasmas have relatively low cavity quality factors in the range of 1000 to 2000. The effective length of their cavities cannot be simply deduced from the cavity electric field profile, since this has by far not a Gaussian shape. The present paper presents a novel method to estimate the effective length of a gyrotron cavity just from the eigenvalue of the operating TEm,n mode, the cavity radius and the exact oscillation frequency which may be numerically computed or precisely measured. This effective cavity length then can be taken to calculate the Fresnel parameter in order to confirm that the cavity is not too short so that the transverse structure of any mode in the cavity is the same as that of the corresponding mode in a long circular waveguide with the same diameter. 相似文献