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1.
The oxidation of Fe(II) with dissolved molecular oxygen was studied in sulfuric acid solutions containing 0.2 mol . dm-3 FeSO4 at temperatures ranging from 343 to 363 K. In solutions of sulfuric acid above 0.4 mol . dm-3, the oxidation of Fe (II) was found to proceed through two parallel paths. In one path the reaction rate was proportional
to both [Fe2+]2 and po2, exhibiting an activation energy of 51.6 . kJ mol-1. In another path the reaction rate was proportional to [Fe2+]2, [SO4-], and po2 with an activation energy of 144.6 kJ . mol-1. A reaction mechanism in which the SO4- ions play an important role was proposed for the oxidation of Fe(II). In dilute solutions of sulfuric acid below 0.4 mol
. dm-3, the rate of the oxidation reaction was found to be proportional to both [Fe(II)]2 and Po2, and was also affected by [H+] and [SO2-
4]. The decrease in [H+] resulted in the increase of reaction rate. The discussion was further extended to the effect of Fe (III) on the oxidation
reaction of Fe (II). 相似文献
2.
A Study of Shadowing on Indoor Visible-Light Wireless Communication Utilizing Plural White LED Lightings 总被引:3,自引:1,他引:2
Toshihiko Komine Shinichiro Haruyama Masao Nakagawa 《Wireless Personal Communications》2005,34(1-2):211-225
White LED is considered as a strong candidate for the future lighting technology. We have proposed an optical wireless communication
system that employs white LEDs for indoor wireless networks. In this system, LED is used not only as a lighting device, but
also as a communication device. The transmitter has large optical power and large emission characteristics to function as
lighting device. And the system has specific wireless channel impulse response differing from infrared wireless communication.
In this paper, we discuss about shadowing effect on the system utilizing plural LED lightings including the performance of
ISI based on the impulse response. We consider the downlink transmission based on TDMA and evaluate the shadowing effect caused
by pedestrians with computer simulation. When the shadowing often occurs at 800 Mb/s, the performance of outage call duration
rate and blocking rate are improved by using 3 LED lightings compared with 1 or 2 LED lightings. And, we show that the system
with the optimal number of the LED lighting is robust against shadowing and can accommodate more calls.
Toshihiko Komine was born in Shizuoka, Japan, on November 17, 1978. He received the B.E. and M.E. degrees in Information and Computer Science
from Keio University, Yokohama, Japan, in 2001 and 2003 respectively. He is currently studying for the Ph.D. degree at Department
of Information and Computer Science, Keio University. His current research interests are optical wireless communications and
LED communications.
Shinichiro Haruyama is a professor at Department of Information and Computer Science, Faculty of Science and Technology, Keio University, Yokohama,
Japan. He received an M.S. in engineering science from University of California at Berkeley in 1983 and a Ph.D. in computer
science from the University of Texas at Austin in 1990. He worked for Bell Laboratories of AT{&}T and Lucent Technologies,
U.S.A from 1991 to 1996, and for Sony Computer Science Laboratories, Inc. from 1998 to 2002. His research interests include
reconfigurable system, system design automation, wireless communication, and visible light communication.
Masao Nakagawa was born in Tokyo, Japan in 1946. He received the B.E., M.E. and Ph.D. degrees in electrical engineering from Keio University,
Yokohama, Japan, in 1969, 1971 and 1974 respectively. Since 1973, he has been with the Department of Electrical Engineering,
Keio University, where he is now a Professor. His research interests are in CDMA, consumer Communications, Mobile communications,
ITS (Intelligent Transport Systems), Wireless Home Networks, and Visible light Communication. He received 1989 IEEE Consumer
Electronics Society Paper Award, 1999-Fall Best Paper Award in IEEE VTC, IEICE Achievement Award in 2000, IEICE Fellow Award
in 2001. He was the executive committee chairman on International Symposium on Spread Spectrum Techniques and Applications
in 1992 and the technical program committee chairman of ISITA (International Symposium on Spread Spectrum Techniques and Applications)
in 1994. He is an editor of Wireless Personal Communications and was a guest editor of the special issues on “CDMA Networks
I, II, III and IV” published in IEEE JSAC in 1994 (I and II) and 1996 (III and IV). He chairs the Wireless Home Link sub-committee
in MMAC (Multimedia Mobile Access Communication Promotion Committee). 相似文献
3.
Yasushi Sobajima Kunihiro Mori Masahiro Tsukamoto Norimitsu Yoshida Masao Takahashi Hikaru Kobayashi Shuichi Nonomura 《Solar Energy Materials & Solar Cells》2005,85(2):240-187
Effects of cyanide (CN) treatment with hydrogenated amorphous silicon (a-Si:H) films have been investigated. The decrease of ΔV/V was observed in cyanide treated a-Si:H films and the successive thermal annealing at 200°C after CN treatment induced the further reduction of the ΔV/V. XPS spectra show the indirect evidence that the cyanide species is present within 10 nm from the hydrogenated amorphous silicon surface. The results of CN treatment with a-Si:H solar cells are demonstrated. 相似文献
4.
5.
Makoto Iida Masao Gotoh Hitoshi Yokono Yasushi Miyano 《Polymer Engineering and Science》1986,26(10):701-707
Flexural properties of moldings made by Reaction Injection Molding (RIM), which are structural foams consisting of high density skin and low density core, were investigated by three-point bending tests. Two failure modes were observed in bending tests of the moldings made by RIM, and they are classified as follows according to the density ratio of skin layer to core layer: the opposite side of the skin layer to which load was subjected failed by tensile stress: and the same side of the skin layer to which load was subjected failed by compressive stress, causing wrinkling or buckling. Then the conventional composite beam theory was applied to the former failure mode and Hoff s buckling theory to the latter, and equations were derived to predict the flexural properties of the structural foams, which involved buckling from the flexural properties of solid construction. In addition, it has been shown that there exists a density distribution that maximizes the flexural strength of the moldings made by RIM with a given overall density. The results obtained here should be useful to the optimum structural design of moldings made by RIM. 相似文献
6.
Masayuki Asada Yoshinari Miura Akiyoshi Osaka Katsutoshi Oukami Seishiro Nakamura 《Journal of Materials Science》1988,23(9):3202-3205
Calcium hydroxyapatite (Ca-HAP) ceramics containing tricalcium phosphate (TCP) were soaked in three solutions: phosphate buffer, tris buffer, and simulated body fluid (SBF). Petal-like crystals of Ca-HAP were deposited on the Ca-HAP ceramics when (i) Ca-HAP ceramics contained -TCP, (ii) the soaking solution contained phosphate ion and (iii) the pH of soaking solution was higher than 7.3. These conditions facilitate the presence of HPO
4
2–
and Ca2+ ions, the latter from dissolution of -TCP. A well-defined X-ray diffraction pattern for the deposited Ca-HAP crystals indicates preferred growth of {002} planes. Slower crystal growth of Ca-HAP was found for SBF (pH=7.5) than in the phosphate buffer, due possibly to the lower phosphate ion content in SBF. 相似文献
7.
Tensile tests of a 17Cr-7Ni-1Al steel were carried out at 0.1, 300 and 600 MPa hydrostatic pressure, and the mechanical properties of the material were found to be considerably changed by the pressure. The martensitic transition temperatureM
s
decreased under pressure. The volume fraction of-martensite induced by tensile deformation increased with strain, but was suppressed by hydrostatic pressure. The yield stress increased with pressure. The yield surface became a nonlinear cone with a pointed apex. The stress-strain curve was considerably changed by pressure, and was expressed by a modified identical-strain model (law of mixture) as a quantitative function. Uniform-strain limit increased with pressure. It was found that these changes were not caused by the mechanical effect of hydrostatic pressure, but by its thermodynamic effects. 相似文献
8.
9.
Ultrafiltration membrane was prepared from poly(vinyl butyral). The effects of membrane thickness, polymer concentration, evaporation time, and evaporation temperature, etc., on the performance of the resulting membranes have been studied. Dimethylacetamide was used as a casting solvent. The membrane formed by casting the polymer from a 15 wt % solution and evaporation at 25°C for 30 s had a flux value of 250 cm3 / cm2 h (4.8 kg/cm2, 26°C) at 92.9% rejection level for dextran sodium sulfate (average mol. wt. 550,000) separation. © 1993 John Wiley & Sons, Inc. 相似文献
10.
Shingo Kanehira Soshu Kirihara Yoshinari Miyamoto Kazuaki Sakoda Mitsuo Wada Takeda 《Journal of the American Ceramic Society》2003,86(10):1691-1694
Photonic crystals with a diamond structure of epoxy lattices in which TiO2 -based ceramic particles are dispersed were fabricated by stereolithography. The periodicity of the lattice was designed to reflect electromagnetic waves in the gigahertz range. The volume fraction (β) of the dielectric lattice medium was modified from 14% to 33% by changing the rod diameter of the lattice. The photonic band gap was observed along Γ-L 〈111〉, Γ-X 〈100〉, and Γ-K 〈110〉 directions and the complete photonic band gap was formed at over β= 20%. The width of the forbidden gap increased gradually when the β increased over 14%, and reached 2.4 GHz at β= 33%. These results agreed with the band calculation using the plane wave expansion method. 相似文献