A developed single-phase cascaded multilevel inverter with reduced number of circuit devices

In this paper, an advanced configuration for multilevel voltage source inverters is proposed. The proposed topology can be used as symmetric and asymmetric inverter. In asymmetric mode, DC sources’ magnitudes are defined in a way that the number of output voltage levels gets more than the case when the symmetrical DC sources are applied. In this regard, to calculate the magnitudes of required DC voltage sources, several different solutions are proposed. In multilevel inverters, the overall cost, circuit size and so installation area, complexity of control scheme and reliability are directly dependent on the number of circuit devices needed. The provided comparison study among suggested inverter in all defined solutions, CHB and recently proposed converters validates that the proposed modular inverter uses reduced number of circuit devices. The provided simulation and experimental results confirm the feasibility of the proposed structure and show that the obtained results are in good agreements.     

One-pot three-component synthesis of some novel ethyl 3-alkyl-2-thioxo-2,3-dihydrothiazole-4-carboxylates under solvent- and catalyst-free conditions at room temperature

A green and efficient one-pot three-component synthesis of some novel ethyl 3-alkyl-2-thioxo-2,3-dihydrothiazole-4-carboxylates from the reaction of primary alkyl or benzyl amines, carbon disulfide and ethyl bromopyruvate is introduced. This straightforward technique gave the looked-for products in high yields during 1.5–3?h without need for catalyst or solvent assistance.     

Ethanol and chitosan production from wheat hydrolysate by Mucor hiemalis

BACKGROUND: High glucose and ethanol tolerance is among the most important requirements of ethanol‐producing microorganisms. The purpose of this study was evaluation of filamentous fungus Mucor hiemalis for ethanol production from wheat and starch hydrolysates with high glucose concentration. RESULTS: The results showed high tolerance of the fungus in fermentation of the hydrolyzates with high glucose concentrations (as high as 190 g L^?1). Interestingly, increasing the glucose concentration from 15 to 190 g L^?1 was accompanied by enhancement of initial sugar uptake rate. Ethanol was the most important metabolite obtained during all fermentations and its concentration reached over 50 g L^?1. Beside ethanol, chitosan was another valuable product of the process. Glucosamine, a precursor of chitosan, made up 37.3–46.7% of the cell wall of this fungus. CONCLUSIONS: M. hiemalis is a promising microorganism for simultaneous production of ethanol and chitosan from substrates with high sugar concentrations. © 2012 Society of Chemical Industry     

Numerical and Experimental Biomass Separation from Fermentation Process by Minihydrocyclones

Biomass particle separation is challenging in the pharmaceutical industry because of the smallness and lightness of such particles. Centrifugation is applied conventionally for batch separation. However, imposing multiple wash steps in order to eliminate culture residues and the high risk of extrinsic contamination hamper batch techniques. In this research, minihydrocyclones were introduced to provide a better solution for the mentioned limitations in continuous processes. Numerical separation of methylotrophic yeast from fermentation broth was carried out in three hydrocyclones with different lengths, and the most efficient one was examined experimentally. Three various feed flow rates and seven feed concentrations were evaluated. The concentration of biomass suspension in the product was raised to 20 %.     

The meshless approach for solving 2D variable-order time-fractional advection–diffusion equation arising in anomalous transport

In this paper, with the aim of extending an elegant and straightforward numerical approximation to describe one of the most common physical phenomena has been undertaken. In this regard, the generalization of advection–diffusion equation, namely, the time-fractional advection–diffusion equation with understanding sense variable-order fractional derivative, is taken into consideration. An efficient and accurate approach is relying on the Kansa scheme and finite difference method to provide a mathematical framework to treat the spatial discretization and temporal term, respectively. The meshless collocation approach is utilized for interior scattered points and those on the boundary. Thus, the problem under consideration is reduced to a system of linear algebraic equations. The use of the radial basis function as shape function brings many advantages for proposal numerical method in terms of improved accuracy by setting an appropriate shape parameter and applied for solving high-dimensional models without extra cost. The validity and accuracy of the proposed approach is investigated by four various examples involving three benchmark examples and a practical application of pollution transfer phenomena.

     

Kinetic modeling of mass transfer during deep fat frying of shrimp nugget prepared without a pre-frying step

The objective of this study was to evaluate the effect of different batter formulation on mass transfer during deep fat frying of shrimp nuggets prepared without a pre-frying step. The effects of soy and corn flour (5, 10%) addition to the batter formulation, frying temperature and time on mass transfer were determined. The results showed an interaction effect of these processing conditions on mass transfer. The most reduction in fat absorption was observed when samples were coated with batter contained 10% soy flour and fried at 190 °C. The first order kinetic based on the Fick's law were used to describe moisture transfer data. The effective moisture diffusivity ranged between 2.05 × 10⁻⁸ and 5.71 × 10⁻⁸ m²/s with R² between 0.91 and 0.98, and fat transfer rate constant was between 3.5 × 10⁻³ and 7.8 × 10⁻³ s⁻¹ with R² from 0.82 to 0.99. Activation energy obtained from the Arrhenius plot for the effective moisture diffusivity ranged between 18.42 and 23.84 kJ/mol.     

Identification of Bioactive Candidate Compounds Responsible for Oxidative Challenge from Hydro‐Ethanolic Extract of Moringa oleifera Leaves

Free radicals trigger chain reaction and inflict damage to the cells and its components, which in turn ultimately interrupts their biological activities. To prevent free radical damage, together with an endogenous antioxidant system, an exogenous supply of antioxidant components to the body in the form of functional food or nutritional diet helps undeniably. Research conducted by the Natl. Inst. of Health claimed that Moringa oleifera Lam possess the highest antioxidant content among various natural food sources based on an oxygen radical absorbent capacity assay. In this study, a 90% (ethanol:distilled water—90:10) gradient solvent was identified as one of the best gradient solvents for the effectual extraction of bioactive components from M. oleifera leaves. This finding was confirmed by various antioxidant assays, including radical scavenging activity (that is, 1, 1‐diphenyl‐2‐picrylhydrazyl, H₂O₂, and NO radical scavenging assay) and total antioxidant capacity (that is, ferric reducing antioxidant power and molybdenum assay). High‐performance liquid chromatography (HPLC) fingerprints of the 90% gradient extract visually showed few specific peaks, which on further analysis, using HPLC–DAD–ESI–MS, were identified as flavonoids and their derivatives. Despite commonly reported flavonoids, that is, kaempferol and quercetin, we report here for the 1st time the presence of multiflorin‐B and apigenin in M. oleifera leaves. These findings might help researchers to further scrutinize this high activity exhibiting gradient extract and its bio‐active candidates for fruitful clinical/translational investigations.     

Highly sensitive amperometric sensor for micromolar detection of trichloroacetic acid based on multiwalled carbon nanotubes and Fe(II)–phtalocyanine modified glassy carbon electrode

A highly sensitive electrochemical sensor for the detection of trichloroacetic acid (TCA) is developed by subsequent immobilization of phthalocyanine (Pc) and Fe(II) onto multiwalled carbon nanotubes (MWCNTs) modified glassy carbon (GC) electrode. The GC/MWCNTs/Pc/Fe(II) electrode showed a pair of well-defined and nearly reversible redox couple correspondent to (Fe(III)Pc/Fe(II)Pc) with surface-confined characteristics. The surface coverage (Γ) and heterogeneous electron transfer rate constant (k_s) of immobilized Fe(II)–Pc were calculated as 1.26 × 10^? 10 mol cm^? 2 and 28.13 s^? 1, respectively. Excellent electrocatalytic activity of the proposed GC/MWCNTs/Pc/Fe(II) system toward TCA reduction has been indicated and the three consequent irreversible peaks for electroreduction of CCl₃COOH to CH₃COOH have been clearly seen. The observed chronoamperometric currents are linearly increased with the concentration of TCA at concentration range up to 20 mM. Detection limit and sensitivity of the modified electrode were 2.0 μM and 0.10 μA μM^? 1 cm^? 2, respectively. The applicability of the sensor for TCA detection in real samples was tested. The obtained results suggest that the proposed system can serve as a promising electrochemical platform for TCA detection.     

An empirical model for modified bituminous binder master curves

Modeling the mechanical behavior of asphalt binders and mixtures has been the subject of intensified research in recent decades. Master curves of the norm of the complex modulus |G*| in the linear viscoelastic domain are frequently used for modeling, while phase angle master curves are less frequently considered for this purpose. Therefore in this research, an empirical model is introduced for phase angle master curves of modified and neat bituminous binders. The model is based on a general form of a double-logistic (DL) mathematical function. The |G*| master curve was then modeled using a mutual relationship between the phase angle and |G*|. Master curves of three neat and seven modified binders were generated and used to validate the DL model. The results showed that the model is capable of properly predicting the plateau region of phase angle master curves. In particular, the asymptotic behavior of the master curves at high frequencies can be modeled correctly. The model also describes irregularities in the high temperature range of the phase angle master curve. In general, model outputs such as the phase angle value at the plateau, glassy modulus, rheological index and crossover frequency correctly predict the behavior of the neat and modified binders.     

Novel extracellular hyper acidophil and thermostable α‐amylase from Micrococcus sp.NS 211

Among several bacteria examined in this study, a hyper acidophil and thermostable Micrococcus sp.NS 211 designated as M.Amy NS 211 was selected for production of amylase using starch agar plates with following incubation at 85°C. Identification by 16SrRNA on selected bacterium disclosed the highest similarity for protean regions of this gene, 27 F and 1492R as Micrococcus sp.NS 211. Although activity of M.Amy NS 211 was established at temperatures between 70 and 110°C and pH ranges 1.2–8.0, the optimum temperature and pH was achieved at 85°C and 3.5 in sodium citrate buffer system respectively. Two‐step chromatography was performed using (CM Bio‐Gel A) and (Bio‐Gel A‐150) columns to purify 84 kDa hyper acidophil and thermostable α‐amylase. SDS‐PAGE analysis showed molecular mass and amylolytic activity as single band. Enhancement of enzyme activity was obtained in presence of 5 mM MnCl₂ (298%), CaCl₂ (347%), FeCl₂ (211%), MgCl₂ (253%), ZnCl₂ (146%), NiCl (142%), NaCl (141%), Na‐sulfate (153%) while inhibition was observed with (5 mM) EDTA, PMSF (3 mM), urea (8 M), and SDS (1%) at 143, 134, 43, and 119%, respectively. M.Amy NS 211 can be applied in laundry detergents, textile, and modern relevant industrial processes at extreme temperatures and under acidic conditions.