GENOTOXICITY IN CHIRONOMUS KIIENSIS (CHIRONOMIDAE: DIPTERA) AFTER EXPOSURE TO POLLUTED SEDIMENTS FROM RIVERS OF NORTH PENINSULAR MALAYSIA: IMPLICATION FOR ECOTOXICOLOGICAL MONITORING

Rapid industrialization and urbanization has led to increasing input of chemical contaminants into the aquatic environment of Malaysia. Despite the threat civilization poses to the biota, there are still very few relevant studies on ecotoxicological testing of river ecosystems. To overcome this knowledge gap, we examined lethal and genotoxic effects of sediments from different rivers of the northern Malaysia against Chironomus kiiensis, a group well represented in the aquatic fauna of this region. We exposed the larvae to sediments from Selama River (SR), Permatang Rawa River (PRR) and Kilang Ubi River (KUR) at various durations (0, 6, 12, 24 and 48 h). The larval mortality was monitored, whereas DNA damage in survivors' cells was determined using the comet assay. Pollution level indexed by the amounts of heavy metals and other organic contaminants in the sediment showed progressive increases from SR to PRR to KUR. Highly polluted sediments (PRR to KUR) were detrimental to C. kiiensis larvae, most of which did not survive following exposure for long periods. DNA analyses revealed greater damages in nuclei derived from larvae maintained on polluted sediments, in particular, those from KUR. The effects on the genomic material of C. kiiensis larvae occurred in a time‐dependent manner, with damage level increasing as exposure time progressed. Our results highlight the genotoxic properties of polluted sediments. More importantly, this study showed that C. kiiensis larvae could respond to different levels of pollution with respect to exposure time. It is concluded that C. kiiensis larvae is a potential candidate for river ecotoxicological monitoring. Copyright © 2012 John Wiley & Sons, Ltd.     

Flexible and Autonomous Integrated System for Characterizing Metal Oxide Gas Sensor Response in Dynamic Environment

Characterization and calibration of gas sensor is a complex problem due to the dynamic behavior of gases and the limitations of current technology. This article reports a flexible, robust, and autonomous integrated system that is able to perform characterization on metal oxide-based gas sensors in dynamic environments. The system controls the concentration and flow of the relevant gases into the gas chamber and simultaneously measuring the sensor response. This feature allows the characterization of the sensor under continuous dynamic flow of gases similar to conditions on a robot or flow pipes. Several experiments have been performed on the system using hydrogen sulfide. The results provide information on the general characteristics of the sensor as well as its sensitivity. The noise levels were studied with different reference voltages. Overall, the results verify that the system is reliable and able to produce repeatable measurements.     

Simplified Monthly Hydrology and Irrigation Water Use Model to Explore Sustainable Water Management Options in the Murray-Darling Basin

We aimed to provide whole-of-basin simulations of flows and diversions in the Murray-Darling Basin for economic and policy analysis. We describe a model based on a subdivision of the basin into 58 catchments. In each catchment, the monthly runoff, river flow and irrigation demand are modelled as lumped processes. This is the first single model of the whole of the Murray-Darling Basin. The model was calibrated using monthly flow and annual diversion records, both by trial and error and using an automated method. We use the model to examine the impact on the flow and diversions in the Murray-Darling Basin of proposed diversion reductions and climate change. The diversion reductions return water to the environment, increasing river flows below the main irrigation areas. However, a middle-of-the-range climate change projection may result in a 13 % decrease in total flows in 2030, which offsets the enhancement to flows gained by diversion reductions.     

A new external sorting algorithm with no additional disk space

This paper is concerned with an external sorting algorithm with no additional disk space. The proposed algorithm is a hybrid one that uses Quicksort and special merging process in two distinct phases. The algorithm excels in sorting a huge file, which is many times larger than the available memory of the computer. This algorithm creates no extra backup file for manipulating huge records. For this, the algorithm saves huge disk space, which is needed to hold the large file. Also our algorithm switches to special merging process after the first phase that uses Quicksort. This reduces the time complexity and makes the algorithm faster.     

Transmission electron microscopy study of Ni–Si nanocomposite films

Nickel induced crystallization of amorphous Si (a-Si) films is investigated using transmission electron microscopy. Metal-induced crystallization was achieved on layered films deposited onto thermally oxidized Si(3 1 1) substrates by electron beam evaporation of a-Si (400 nm) over Ni (50 nm). The multi-layer stack was subjected to post-deposition annealing at 200 and 600 °C for 1 h after the deposition. Microstructural studies reveal the formation of nanosized grains separated by dendritic channels of 5 nm width and 400 nm length. Electron diffraction on selected points within these nanostructured regions shows the presence of face centered cubic NiSi₂ and diamond cubic structured Si. Z-contrast scanning transmission electron microscopy images reveal that the crystallization of Si occurs at the interface between the grains of NiSi₂ and a-Si. X-ray absorption fine structure spectroscopy analysis has been carried out to understand the nature of Ni in the Ni–Si nanocomposite film. The results of the present study indicate that the metal induced crystallization is due to the diffusion of Ni into the a-Si matrix, which then reacts to form nickel silicide at temperatures of the order of 600 °C leading to crystallization of a-Si at the silicide–silicon interface.     

Manufacture of Syntactic Foams: Pre-Mold Processing

Manufacturing processes for syntactic foams made of hollow microspheres and starch were studied. Various manufacturing parameters in relation to the “buoyancy method” were identified and inter-related. An equation based on unit-cell models with the minimum inter-microsphere distance concept for a relation between volume expansion rate of bulk microspheres in aqueous starch and microsphere size was derived and successfully used to predict experimental data. It was demonstrated that the inter-microsphere distance can be calculated numerically for microspheres with known statistical data. The equation relating between volume expansion rate and microsphere size was further extended to accommodate a relation between inter-microsphere distance and microsphere size but with limited accuracy for binders of low starch content. An alternative empirical linear equation for the relation between inter-microsphere distance and microsphere size is proposed for wider applications. A simple method for estimation of syntactic foam density prior to completion of manufacture is suggested. Shrinkage after molding of syntactic foam is discussed in relation with different stages such as slurry, dough and solid. A two-step manufacturing process involving molding and then forming is suggested for syntactic foam dimensional control.     

Enhanced Solar‐to‐Hydrogen Generation with Broadband Epsilon‐Near‐Zero Nanostructured Photocatalysts

The direct conversion of solar energy into fuels or feedstock is an attractive approach to address increasing demand of renewable energy sources. Photocatalytic systems relying on the direct photoexcitation of metals have been explored to this end, a strategy that exploits the decay of plasmonic resonances into hot carriers. An efficient hot carrier generation and collection requires, ideally, their generation to be enclosed within few tens of nanometers at the metal interface, but it is challenging to achieve this across the broadband solar spectrum. Here the authors demonstrate a new photocatalyst for hydrogen evolution based on metal epsilon‐near‐zero metamaterials. The authors have designed these to achieve broadband strong light confinement at the metal interface across the entire solar spectrum. Using electron energy loss spectroscopy, the authors prove that hot carriers are generated in a broadband fashion within 10 nm in this system. The resulting photocatalyst achieves a hydrogen production rate of 9.5 µmol h^?1 cm^?2 that exceeds, by a factor of 3.2, that of the best previously reported plasmonic‐based photocatalysts for the dissociation of H₂ with 50 h stable operation.     

中孟在校青年男子体型对比分析

为分析中孟在校青年男子体型区别,对孟加拉和中国在校青年男子的整体和局部体型进行对比和分类分析。运用手工测量及三维测量法获取中国与孟加拉各200名在校青年男子的相关体型参数,对比分析孟加拉与中国在校青年男子的整体和局部体型。在整体体型方面,分析了两国在校青年男子于国家标准及形态整体特征上的异同点;在局部体型方面,针对肩部、胸部和腰臀部3个人体主要特征部位进行分类,分别将各个部位的体型聚类成3类进行对比分析。研究表明:中孟在校青年男子体型差异较大,中国在校青年男子整体瘦长、整体曲线明显、肩部较宽、胸部线条弧度较大、臀部挺翘;孟加拉在校青年男子大部分属于均匀凸腹体型,整体轮廓线条平缓、肩部较窄、胸围较大且平坦、腰臀围较大、臀部较扁平且腹部凸出。该研究结果可为中孟在校青年男子版型制作提供体型依据。