Synthesis and characterization of poly(N-(2-(thiophen-3-yl)methylcarbonyloxyethyl)maleimide) and its spectroelectrochemical properties

A new monomer; N-(2-(thiophen-3-yl)methylcarbonyloxyethyl) maleimide (NMT) was synthesized. The chemical structure of the monomer was characterized by Nuclear Magnetic Resonance (¹H-NMR) and Fourier Transform Infrared (FTIR) Spectroscopy. Electrochemical polymerization of NMT was performed in acetonitrile (AN)/borontrifloride ethylether (BFEE) solvent mixture (1:1, v/v) where tetrabutylammonium tetrafluoroborate (TBAFB) was utilized as the supporting electrolyte. The resulting conducting polymer was characterized by Fourier Transform Infrared (FTIR) Spectroscopy, thermal analyses and Scanning Electron Microscopy (SEM). Electrical conductivity was measured by the four-probe technique. The spectroelectrochemical behavior and switching ability of P(NMT) film were investigated by UV–Vis spectrophotometry. P(NMT) revealed color changes between yellow and blue in the reduced and oxidized states respectively.     

Optimization of Multireservoir Systems by Genetic Algorithm

Application of optimization techniques for determining the optimal operating policy of reservoirs is a major issue in water resources planning and management. As an optimization Genetic Algorithm, ruled by evolution techniques, have become popular in diversified fields of science. The main aim of this study is to explore the efficiency and effectiveness of genetic algorithm in optimization of multi-reservoirs. A computer code has been constructed for this purpose and verified by means of a reference problem with a known global optimum. Three reservoirs in the Colorado River Storage Project were optimized for maximization of energy production. Besides, a real-time approach utilizing a blend of online and a posteriori data was proposed. The results obtained were compared to the real operational data and genetic algorithm was found to be effective and can be utilized as an alternative technique to other traditional optimization techniques.     

Effect of injection timing on the exhaust emissions of a diesel engine using diesel–methanol blends

Environmental concerns and limited resource of petroleum fuels have caused interests in the development of alternative fuels for internal combustion (IC) engines. For diesel engines, alcohols are receiving increasing attention because they are oxygenated and renewable fuels. Therefore, in this study, the effect of injection timing on the exhaust emissions of a single cylinder, naturally aspirated, four-stroke, direct injection diesel engine has been experimentally investigated by using methanol-blended diesel fuel from 0% to 15% with an increment of 5%. The tests were conducted for three different injection timings (15°, 20° and 25 °CA BTDC) at four different engine loads (5 Nm, 10 Nm, 15 Nm, 20 Nm) at 2200 rpm. The experimental test results showed that Bsfc, NO_x and CO₂ emissions increased as BTE, smoke opacity, CO and UHC emissions decreased with increasing amount of methanol in the fuel mixture. When compared the results to those of original injection timing, NO_x and CO₂ emissions decreased, smoke opacity, UHC and CO emissions increased for the retarded injection timing (15 °CA BTDC). On the other hand, with the advanced injection timing (25 °CA BTDC), decreasing smoke opacity, UHC and CO emissions diminished, and NO_x and CO₂ emissions boosted at all test conditions. In terms of Bsfc and BTE, retarded and advanced injection timings gave negative results for all fuel blends in all engine loads.     

Process control at the sealing line during sheet metal hydroforming

Sheet metal hydroforming is a deep drawing process that uses a pressure medium for load transmission. The process is mainly influenced by the control of the blank holder force and the fluid pressure. This report describes investigations of a newly developed process-control system. Process variables can be controlled by the sealing state of the tool. The detection is performed by a CCD-camera system that allows the continuous recording of occurring leakages. Different control strategies can be used to control the multiple process parameters. This paper describes the performance and the limits of the aforementioned technology.     

Parasitic compensation in CCI-based circuits for reduced power consumption

In this paper, the compensation advantage of the first-generation current conveyor (CCI) over the second-generation current conveyor (CCII) in tunable circuits is shown. For this purpose, a new floating frequency dependent negative resistor (FDNR) simulator using three CCIs is presented and employed in a third-order high-pass filter. The compensation feature of the CCI is shown for the proposed high-pass filter. As a second example, the presented compensation method is tested in a second-order band-pass filter constructed with two CCIs. Applying the proposed compensation technique, the CCI-based circuits can operate in lower biasing currents, which result in lower power consumption.     

Ge-Si-O phase separation and Ge nanocrystal growth in Ge:SiO(x)/SiO(2) multilayers--a new dc magnetron approach

Ge:SiO(x)/SiO(2) multilayers are fabricated using a new reactive dc magnetron sputtering approach. The influence of the multilayer stoichiometry on the ternary Ge-Si-O phase separation and the subsequent size-controlled Ge nanocrystal formation is explored by means of x-ray absorption spectroscopy, x-ray diffraction, electron microscopy and Raman spectroscopy. The ternary system Ge-Si-O reveals complete Ge-O phase separation at 400?°C which does not differ significantly to the binary Ge-O system. Ge nanocrystals of < 5?nm size are generated after subsequent annealing below 700?°C. It is shown that Ge oxides contained in the as-deposited multilayers are reduced by a surrounding unsaturated silica matrix. A stoichiometric regime was found where almost no GeO(2) is present after annealing. Thus, the Ge nanocrystals become completely embedded in a stoichiometric silica matrix favouring the use for photovoltaic applications.     

Wavelet decomposition of cardiovascular signals for baroreceptor function tests in pigs

In this paper, the discrete wavelet transform (DWT) was applied to analyze the fluctuations in RR interval and systolic arterial pressure (SAP) recorded from eight alpha-chloralose anesthetized pigs. Our aim was to characterize the autonomic modulation before and after cardiac autonomic blockade and during baroreflex function tests. The instantaneous power of decomposed low-frequency (LF) and high-frequency (HF) components was used for a time-variant spectral analysis. Our results suggested that transient events and changes in autonomic modulation were detected with high temporal resolution. A nonlinear relationship between RR interval and SAP during pharmacologically induced changes in blood pressure was found, when the superimposed effect of respiratory sinus arrhythmia was removed. In addition, the baroslopes were nearly linear when both the LF and HF components were removed using DWT decomposition.     

A comparative study on structural,morphological and photocatalytic properties of anodically grown ZnO nanowires under varying parameters

Journal of Materials Science: Materials in Electronics - In this study, zinc oxide (ZnO) nanowires (NWs) were successfully produced on Zn plates through electrochemical anodization in potassium...