The relation of acid rain to energy policy

Current energy policies have severely eroded the earth's natural atmospheric waste-receptor capacity. Present acid rain concentrations may require a switch to an alternative energy-resource emphasis. This policy recommendation follows directly from a deductive control theory demonstration which shows that, if fossil-fuel use is continued at present rates, then there is an ever-increasing risk of a man-made environmental crisis of uncertain nature and scope.     

On-line H NMR spectroscopic investigation of hydrogen bonding in supercritical and near critical CO2–methanol up to 35 MPa and 403 K

On-line NMR spectroscopy can beneficially be applied to studies of supercritical and near-critical fluids as an alternative to optical spectroscopy. Up to now high pressure NMR experiments are predominantly accomplished using custom made NMR batch reactors. The authors present a novel high pressure cell with displacement plunger for on-line NMR experiments on compressible fluids which can be used in conjunction with commercially available SCF NMR flow probes. The on-line technique offers advantages compared to stopped flow techniques such as enhanced control of mixture composition and reaction parameters as well as the facility of engagement into the reaction. The new apparatus is used for NMR studies on hydrogen bonding of methanol in near critical and supercritical carbon dioxide up to 403 K and 35 MPa for which data on the chemical shift of the hydroxyl group and methyl group are reported and interpreted.     

Design criteria for the crystallization of an organic salt from an aqueous solutionAuslegungsunterlagen zur kristallisation eines organischen salzes aus wässriger Lösung

Results from laboratory experiments and a 500 tonnes per month pilot plant have been used to draw up criteria for designing the crystallization of an organic salt from its aqueous solution. The crystallization kinetics were determined in a continuous forced circulation crystallizer. The experiments in the forced circulation evaporative crystallizer were carried out and evaluated in accordance with the MSMPR (mixed suspension mixed product removal) concept.The residence time was varied between 0.8 and 10 hours, and the density of the suspension between 180 and 870 kg m^?3. It was found that, within the residence time and suspension density ranges studied, growth and nucleation rates have the same dependence on the supersaturation. On the other hand, the nucleation rate decreases with increasing suspension density. If the crystallization kinetics and other design criteria, such as vapour velocity, i.e. supersaturation ratio in the vicinity of the evaporative surface, or height of liquid above the heat exchangers, are taken into account, it is possible to obtain a space—time yield which is five times higher than in the pilot plant, so that the plant to be built can be designed to be correspondingly smaller.     

Context and lexical access: Implications of nonword interference for lexical ambiguity resolution.

To eliminate potential "backward" priming effects, S. Glucksberg et al (see record 1986-29080-001) introduced a variant of the cross-modal lexical priming task in which subjects made lexical decisions to nonword targets that were modeled on a word related to either the contextually biased or unbiased sense of an ambiguous word. Lexical decisions to nonwords were longer than controls only when the nonword was related to the contextually biased sense of the ambiguous word, leading Glucksberg et al to conclude that context does constrain lexical access and that the multiple access pattern observed in previous studies was probably an artifact of backward priming. We did not find nonword interference when the nonword targets used by Glucksberg et al were preceded by semantically related ambiguous or unambiguous word primes. However, we did replicate their sentence context results when the ambiguous words were removed from the sentences. We conclude that the interference obtained by Glucksberg et al is due to postlexical judgments of the congruence of the sentence context and the target, not to context constraining lexical access. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

A circuit model for the inductive strip in homogeneous finline

This article describes a circuit model for infinitesimally thin inductive strips centered in homogeneous finline. The model is valid for 0.1 ≤ W/b ≤ 1.0, 0.01 ≤ T/a, and 0.4 ≤ b/a ≤ 0.5 when frequency is in the normal operating band for the rectangular waveguide shield. The error is less than 2.5%.     

A time aggregation approach to Markov decision processes

We propose a time aggregation approach for the solution of infinite horizon average cost Markov decision processes via policy iteration. In this approach, policy update is only carried out when the process visits a subset of the state space. As in state aggregation, this approach leads to a reduced state space, which may lead to a substantial reduction in computational and storage requirements, especially for problems with certain structural properties. However, in contrast to state aggregation, which generally results in an approximate model due to the loss of Markov property, time aggregation suffers no loss of accuracy, because the Markov property is preserved. Single sample path-based estimation algorithms are developed that allow the time aggregation approach to be implemented on-line for practical systems. Some numerical and simulation examples are presented to illustrate the ideas and potential computational savings.     

The effects of degree of mixing and concentration of carbon black on the tensile properties of filled elastomers

Based on the concept of entropy of mixing, a new method for determining the degree of mixing of the filler in a polymer matrix has been established. The measurement used in this method is based on a new variable, the effective volume fraction of the filler, ?′, which is a function of the mixing index, A, and the volume fraction of the filler, ?. The mixing index can be determined from the tensile modulus data of filled elastomers. Excellent agreement is obtained between the mixing index and the dispersion of the filler as determined by a morphological study of cryogenically fractured surfaces of filled elastomers. Using the new variable, the effective volume fraction of the filler, useful relationships for the tensile modulus and the ultimate stretch ratio of filled elastomer have been established. Experimental data confirm that these relationships can well describe the effects of concentration and degree of mixing on the two tensile properties of filled elastomers.     

Memory scanning: Are fixed and varied sets scanned concurrently or successively?

Subjects were timed as they decided whether individually presented probe letters were or were not contained in pairs of memorized sets of one, two, or four letters. One set was fixed in advance of a block of trials, while the other varied from trial to trial. In Experiments 1 and 2, subjects responded positively if the probe was in either set and negatively otherwise; in Experiment 3 they made different responses to fixed-set, varied-set, and negative probes. In all three experiments, reaction time (RT) to varied-set probes depended more on the size of the varied set than of the fixed set, whereas RT to fixed-set and negative probes depended more on the size of the fixed set. These results were generally consistent with the hypothesis that scanning of the two sets was at least to some extent concurrent rather than successive, with the fixed set scanned more slowly than the varied set. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Efficient Management of Persistent Knowledge

Although computer speed has steadily increased and memory is getting cheaper, the need for storage managers to deal efficiently with applications that cannot be held into main memory is vital. Dealing with large quantities of clauses implies the use of persistent knowledge and thus, indexing methods are essential to access efficiently the subset of clauses relevant to answering a query. We introduce PerKMan, a storage manager that uses G-trees, and aims at efficient manipulation of large amounts of persistent knowledge. PerKMan may be connected to Prolog systems that offer an external C language interface. As well as the fact that the storage manager allows different arguments of a predicate to share a common index dimension in a novel manner, it indexes rules and facts in the same manner. PerKMan handles compound terms efficiently and its data structures adapt their shape to large dynamic volumes of clauses, no matter what the distribution. The storage manager achieves fast clause retrieval and reasonable use of disk space.     

CALCE/RAMCAD for Electronics

The University of Maryland's Computer Aided Life Cycle Engineering (CALCE) research effort is aimed at developing techniques for design, analysis, prediction, and optimization of electronics with respect to a variety of design goals. Performance, producibility, reliability, maintainability, life-cycle cost, safety, etc., are the design criteria which are being integrated through the application of interactive heuristic and algorithmic design optimization techniques. The University of Maryland Reliability and Maintainability Computer-Aided Design (RAMCAD) research is CALCE and is focused on second- and third-level electronic package design with respect to interfacing thermal, mechanical, and reliability analysis. The goal is to make reliability and maintainability an integral, real-time, and upfront part of the design process, such that the need to resubmit designs will be eliminated. The motivation behind this project was the fact that schedule constraints are often compromising the effectiveness and efficiency of the design process. To achieve the goal of CALCE/RAMCAD, a cohesive and extensible design environment for analysis and tradeoff tools was developed. A system executive controller that integrates tools for analysis while providing system transparency, design data management, and process management was developed to guide the user through the design process and provide direct access to the design tools. These developments required the integration of computer-aided design (CAD), artificial intelligence (AI), and decision support (DS) techniques. Attention to human factors and the use of interactive graphics were also instrumental in the development.