Laboratory study of impacts of concrete fragment sizes on wetland water chemistry

This study investigated the effects of urban concrete materials, of different particle sizes, immersed in water through a laboratory-based experiment. Water was sourced from a high conservation-value wetland (Blue Mountains upland swamp). Prior to the experiment, wetland water was dilute (32.5 μS/cm), acidic (pH 5.3) and had detectable major ion concentrations of only sodium and chloride. Water was exposed to three treatments of different concrete fragment sizes (whole, crushed and fine). All treatments increased conductivity and pH and also resulted in modified ionic composition where calcium, potassium, hydroxide, carbonate and sulphate were recorded at much high levels. The extent and speed of water chemistry changes was linked to the particle size of the concrete. The results of this study support the hypothesis that concrete can be an environmentally hazardous material influencing water quality in urban catchments.     

Insights into the physics of spray coating of SWNT films

Spray coating is a scalable and high-throughput process for fabrication of transparent and conducting coatings (TCCs) composed of single-walled carbon nanotubes (SWNTs). Presently the fundamentals of this process are not well understood. We show that suppression of coalescence of spray droplets by sufficiently rapid heat- and mass-transfer yields homogeneous SWNT films by preventing the formation of ‘coffee stains’ of larger length scale. Such heat and mass transfer is driven by differential evaporation between the top and edges of the drops, whereas thermal and compositional effects on surface tension and buoyancy are weak. Ultrasonic spraying ensures that the droplets are deposited without significant splashing, and delayed splashing at higher Weber number is evidenced. We find that the performance of spray-coated TCCs made from HiPCO SWNTs is limited by bundle diameter rather than length of the constituent SWNTs and bundes. Vapor acid doping with concentrated sulfuric acid roughly doubles the conductivity of the TCCs.     

Abiotic transformation of hexahydro-1,3,5-trinitro-1,3,5-triazine by Fe(II) bound to magnetite

RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine), a nitramine explosive, is often found as a subsurface contaminant at military installations. Though biological transformations of RDX are often reported, abiotic studies in a defined medium are uncommon. The work reported here was initiated to investigate the transformation of RDX by ferrous iron (Fe(II)) associated with a mineral surface. RDX is transformed by Fe(II) in aqueous suspensions of magnetite (Fe3O4). Negligible transformation of RDX occurred when it was exposed to Fe(II) or magnetite alone. The sequential nitroso reduction products (MNX, DNX, and TNX) were observed as intermediates. NH4+, N2O, and HCHO were stable products of the transformation. Experiments with radiolabeled RDX indicate that 90% of the carbon end products remained in solution and that negligible mineralization occurred. Rates of RDX transformation measured for a range of initial Fe(II) concentrations and solution pH values indicate that greater amounts of adsorbed Fe(II) result in faster transformation rates. As pH increases, more Fe(II) adsorbs and k(obs) increases. The degradation of RDX by Fe(II)-magnetite suspensions indicates a possible remedial option that could be employed in natural and engineered environments where iron oxides are abundant and ferrous iron is present.     

Book reviews

Australian Environmental Policy 2: Studies in Decline and Devolution

Ken Walker and Kate Crowley (eds) UNSW Press, Sydney, 1999 ISBN 0868406732 (paperback) 323 pp.; bibliography and index RRP $35.00

Beyond Meltdown: The Global Battle for Sustained Growth.

Peter Brain. Scribe, Melbourne, 1999 ISBN 0908011369 (paperback) 273 pp.; bibliography and index RRP $26.95

Cities Back from the Edge: New Life for Downtown

Roberta Brandes Gratz with Norman Mintz John Wiley & Sons, New York, 1998 ISBN 0471144177 (hardback) 347 pp.; index RRP $59.95

Evaluation in Planning: Facing the Challenge of Complexity

Nathaniel Lichfield, Angela Barbanente, Dino Bori, Abdul Khakee and Anna. Prat (eds). Kluwer, Dordrecht, 1998. ISBN 0792351770 (hardback). 383 pp.; index. RRP $254.00

Gritty Cities: Images of the Urban

Lyaranette Finch and Chris McConville (eds). Pluto, Sydney, 1999. ISBN 1864030631 (paperback). 250 pp.; bibliography and index. RRP $24.95

Setting the Stage for Systainability: A Citizen's Handbook

Chris Maser, Russ Beaton and Kevin Smith Lewis Publishers, Boca Raton, 1998 ISBN 1574441876 (hardback) 269 pp.; index RRP $47.50

The Australian Metropolis: A Planning History

Stephen Hamnett and Robert Freestone (eds) Allen & Unwin, Sydney, 1999 ISBN 1865080535 (paperback) 229 pp.; index RRP $35.00     

No Effect of Omega-3 Fatty Acid Supplementation on Cognition and Mood in Individuals with Cognitive Impairment and Probable Alzheimer’s Disease: A Randomised Controlled Trial

Findings from epidemiological and observational studies have indicated that diets high in omega-3 polyunsaturated fatty acids (PUFAs) such as docosahexaenoic acid (DHA) and eicosapentaenoic acid (EPA) may reduce the risk of cognitive decline and Alzheimer’s disease (AD). To determine if increasing intake of DHA and EPA through supplementation is beneficial to cognition and mood in individuals with cognitive impairment no dementia (CIND) or Alzheimer’s disease (AD) a four month, randomised, double-blind, placebo controlled study was conducted. Fifty-seven participants with CIND and nineteen with AD were randomised to receive either omega-3 PUFAs (600 mg EPA and 625 mg DHA per day) or placebo (olive oil) over a four month period. Elevating depleted levels of EPA and DHA through supplementation in individuals with CIND or AD was found to have negligible beneficial effect on their cognition or mood. These findings confirm an overall negligible benefit of omega-3 PUFA supplementation for those with cognitive impairment and dementia. More intervention studies need to be undertaken with longer study durations and larger sample sizes. It may prove fruitful to examine effects of different doses as well as effects in other dementia subtypes.     

A Murine Oral‐Exposure Model for Nano‐ and Micro‐Particulates: Demonstrating Human Relevance with Food‐Grade Titanium Dioxide

Human exposure to persistent, nonbiological nanoparticles and microparticles via the oral route is continuous and large scale (10¹²–10¹³ particles per day per adult in Europe). Whether this matters or not is unknown but confirmed health risks with airborne particle exposure warns against complacency. Murine models of oral exposure will help to identify risk but, to date, lack validation or relevance to humans. This work addresses that gap. It reports i) on a murine diet, modified with differing concentrations of the common dietary particle, food grade titanium dioxide (fgTiO₂), an additive of polydisperse form that contains micro‐ and nano‐particles, ii) that these diets deliver particles to basal cells of intestinal lymphoid follicles, exactly as is reported as a “normal occurrence” in humans, iii) that confocal reflectance microscopy is the method of analytical choice to determine this, and iv) that food intake, weight gain, and Peyer's patch immune cell profiles, up to 18 weeks of feeding, do not differ between fgTiO₂‐fed groups or controls. These findings afford a human‐relevant and validated oral dosing protocol for fgTiO₂ risk assessment as well as provide a generalized platform for application to oral exposure studies with nano‐ and micro‐particles.     

Role taking and moral judgment in five- and seven-year-olds.

Studied 3 dimensions of role taking (perceptual, cognitive, and affective) and 2 dimensions of moral judgment (intentionality and restitution) in 34 kindergartners and 38 2nd graders. Results show that there was a significant correlation between moral judgment and role taking and indicate the need for precise definitions of these concepts and the use of common instruments if research in this area is to make any progress. (PsycINFO Database Record (c) 2010 APA, all rights reserved)