茶多酚对生长育肥猪生长性能和肉质的影响研究

添加0.1%茶多酚复合添加剂能显著提高生长育肥猪的平均日增重、猪肉pH值;添加0.3%时能极显著提高平均日增重、pH值,极显著降低失水率;当添加水平继续增大时作用不大.荼多酚的添加对背膘厚度、瘦肉率和肉色影响不显著,但对猪肉VE和肌苷酸(IMP)的含量极显著增加.茶多酚复合添加剂的适宜水平为0.3%.     

催化剂的大分子裂化性能与渣油裂化

以渣油的催化裂化反应化学为基础,详细论述催化剂孔结构及其酸性、基质活性、沸石晶粒度、基质与沸石的相互作用等因素对重油催化裂化催化剂大分子裂化性能的影响。重油特别是渣油的组成特征要求催化剂必须具有合适的大、中、小孔比例及适度的酸性分布,以解决大分子烃在沸石催化剂中的活性可接近性问题,其中大、中孔尤其是中孔及其活性起着十分关键的作用;活性基质不但能大幅度提高催化剂的重油裂化能力,且对催化剂的抗重金属、抗碱氮、脱硫、脱氮等性能及产品质量产生重要影响;此外,针对不同装置催化剂的设计要求,提高沸石外表面、充分利用沸石与基质的相互作用等因素在大分子的催化裂解中也起着非常重要的作用。     

苯酚氧化反应中溶剂选择及催化剂再生方法的研究

考察了水作溶剂对苯酚转化率及产品选择性的影响，并且对催化剂的再生方法进行了改进。研究发现，水及丙酮分别作溶剂时，通过控制反应参数，苯酚转化率可达到相近的水平；水作溶剂时，通过调整反应温度、水量、Ｈ２Ｏ２用量及其加入方式可以得到最大的苯酚转化率及Ｈ２Ｏ２利用率；高温水处理积炭催化剂的方法，可以减少催化剂的焙烧次数，简化原有的再生工艺。     

原油乳状液稳定性研究 Ⅱ.原油成分对原油乳状液稳定性的影响

原血成分的表面活性物质及其细微固体颗粒,在油水界面上相互作用是原油乳状液其有稳定性的主要原因。本文采用简单的方法将原油中众多的物质分成两大类,并根椐它们单独时或混合后对癸烷/水乳状液稳定性作用的特征,将其分别称为原油乳化剂和原油破乳剂。试验表明,原油乳状液稳定性的高低主要取决于所含的这两大类物质的多少和相对比例,其相对重要性可由界面张力定性地反映出来;并且由原油/水界面张力的大小可以定性地评估原油乳状液的稳定性。     

肥城盆地地下水水化学演变规律研究

基于肥城盆地1999—2013年地下水水质实测数据,选取钙、镁、硫酸根、氯、重碳酸根、钠和钾等离子作为主要研究对象,利用Aqua Chem软件分析了主要离子的时空分布情况、总硬度和矿化度的变化趋势,揭示了近年来该区地下水水质变化规律并分析了水质变化驱动力。结果表明:肥城盆地地下水主要离子浓度呈上升趋势,总硬度和矿化度在空间上由东北向西南盆地出水口方向逐渐升高,水化学类型由HCO3-Ca型、HCO3-Ca-Mg型向HCO3-SO4-Ca-Mg型、HCO3-SO4-Ca型转变。肥城盆地地下水水质变化与降水入渗、地下水超采、工业废水及城市污水排放、农业污水灌溉、生活垃圾随意堆放等有关,据此提出了相应的地下水保护措施。     

无皂型乳液聚合的研究进展

综述了无皂型乳液聚合反应机理及影响乳液稳定性的因素。对无皂型乳液聚合制备方法进行了论述,并介绍了无皂型乳液聚合的研究动态、应用和发展前景。     

Atomic Insights into the Enhanced Surface Stability in High Voltage Cathode Materials by Ultrathin Coating

Surface properties of electrode materials play a critical role in the function of batteries. Therefore, surface modifications, such as coatings, have been widely used to improve battery performance. Understanding how these coatings function to improve battery performance is crucial for both scientific research and applications. In this study the electrochemical performance of coated and uncoated LiNi_0.5Mn_1.5O₄ (LNMO) electrodes is correlated with ensemble‐averaged soft X‐ray absorption spectroscopy (XAS) and spatially resolved scanning transmission electron microscopy‐electron energy loss spectroscopy (STEM‐EELS) to illustrate the mechanism of how ultrathin layer Al₂O₃ coatings improve the cycle life of LiNi_0.5Mn_1.5O₄. Mn²⁺ evolution on the surface is clearly observed in the uncoated sample, which results from the reaction between the electrolytic solution and the surfaces of LiNi_0.5Mn_1.5O₄ particles, and also possibly atomic structure reconstructions and oxygen loss from the surface region in LiNi_0.5Mn_1.5O₄. The coating effectively suppresses Mn²⁺ evolution and improves the battery performance by decelerating the impedance buildup from the surface passivation. This study demonstrates the importance of combining ensemble‐averaged techniques (e.g., XAS) with localized techniques (e.g., STEM‐EELS), as the latter may yield unrepresentative information due to the limited number of studied particles, and sheds light on the design of future coating processes and materials.     

Hydrothermal synthesis of mesoporous titanosilicate with the aid of amphiphilic organosilane

Mesoporous MFI-type titanosilicates (TS-1) were hydrothermally synthesized with the aid of amphiphilic organosilane and the effects of the amphiphilic organosilane on the structural and textural properties of the resultant materials were investigated. The physicochemical properties of the samples were characterized by various techniques and their catalytic performance was investigated by the epoxidation of cyclohexene with hydrogen peroxide. The content of organosilane added was essential for the formation of uniform mesopore in TS-1, and greatly influenced the crystallinity. Highly crystallined TS-1 with uniform mesopores of 3.7 nm diameter was successfully synthesized. The mesoporous TS-1 preserved tetrahedrally coordinated Ti ions in the framework, but it was featured with more hydrophobic surface and less defect sites in comparison to conventional TS-1. Mesoporous TS-1 showed a higher conversion for the epoxidation of cyclohexene owing to an easier access of bulky molecules to the catalytic active sites. Mesoporous TS-1’s higher hydrophobicity made its epoxide selectivity two times as much as that of conventional TS-1.     

科技统计的抽样方案设计

分析了科技统计抽样模型的特点，设计了抽样方案，并对抽样返回数据进行回数据进行回归估计与放大，较好地解决了科技统计中相关资料不全、花费时间较多的矛盾，实现了快速科技统计的目标。     

风洞动力PLC监控系统的研制

结合 8 m× 6 m风洞动力系统的改造 ,充分利用动力系统的设备、部件 ,采用 PL C控制器 ,基于 S7-STEP7和 FIX32编程环境 ,开发研制出动力监控系统 ,从而实现了 8m× 6 m风洞动力系统的智能监控。文章系统地叙述了 8m× 6 m风洞动力监控系统的硬件结构 ,软件设计原理和方法 ,系统的功能以及达到的效果