Transient electroluminescence determination of carrier mobility and charge trapping effects in heavily doped phosphorescent organic light-emitting diodes

Transient electroluminescence (EL) was used to measure the delay between the excitation pulse and onset of emission in OLEDs based on phosphorescent bis[3,5-bis(2-pyridyl)-1,2,4-triazolato] platinum(ΙΙ) doped into 4,4′-bis(carbazol-9-yl) triphenylamine (CBP), from which an electron mobility of 3.2 × 10⁻⁶ cm²/V s was approximated. Delayed recombination was observed after the drive pulse had been removed and based on its dependence on frequency and duty cycle, ascribed to trapping and de-trapping processes associated with disorder-induced carrier localization at the interface between the emissive layer and electron blocker. The data suggests that the exciton recombination zone is at, or close to the interface between the emissive layer and electron blocker. Despite the charge trapping effects, a peak power efficiency of 24 lm/W and peak external quantum efficiency of 10.64% were obtained. Mechanisms for the electroluminescence and delayed recombination are proposed.     

Immobilization of a human epidermal growth factor receptor 2 mimotope-derived synthetic peptide on Au and its potential application for detection of herceptin in human serum by quartz crystal microbalance

Therapeutic antibodies are antigenically similar to human antibodies and are difficult to detect in assays of human serum samples without the use of the therapeutic antibody's complementary antigen. Herein for the first time, we established a platform to detect Herceptin in solutions by using a small (<2.2 kDa), inexpensive, highly stable human epidermal growth factor receptor (HER2) mimotope-derived synthetic peptide immobilized on the surface of a Au quartz electrode. We used the HER2 mimotope as a substitute for the HER2 receptor protein in piezoimmunosensor or quartz crystal microbalance (QCM) assays to detect Herceptin in human serum. We demonstrated that assay sensitivity was dependent upon the amino acids used to tether and link the peptide to the sensor surface and the buffers used to carry out the assays. The detection limit of the piezoimmunosensor assay was 0.038 nM with a linear operating range of 0.038-0.859 nM. Little nonspecific binding to other therapeutic antibodies (Avastin and Rituxan) was observed. Levels of Herceptin in serum samples obtained from treated patients, as ascertained using the synthetic peptide-based QCM assay, were typical for those treated with Herceptin. The findings of this study are significant in that low-cost synthetic peptides could be used in a QCM assay, in lieu of native or recombinant antigens or capture antibodies, to rapidly detect a therapeutic antibody in human serum. The results suggested that a synthetic peptide bearing a particular functional sequence could be applied for developing a new generation of affinity-based immunosensors to detect a broad range of clinical biomarkers.     

Dynamic analysis of an inclined Timoshenko beam traveled by successive moving masses/forces with inclusion of geometric nonlinearities

In the first part of this paper, the nonlinear coupled governing partial differential equations of vibrations by including the bending rotation of cross section, longitudinal and transverse displacements of an inclined pinned?Cpinned Timoshenko beam made of linear, homogenous and isotropic material with a constant cross section and finite length subjected to a traveling mass/force with constant velocity are derived. To do this, the energy method (Hamilton??s principle) based on the large deflection theory in conjuncture with the von-Karman strain-displacement relations is used. These equations are solved using the Galerkin??s approach via numerical integration methods to obtain dynamic responses of the beam under act of a moving mass/force. In the second part, the nonlinear coupled vibrations of the beam traveled by an arbitrary number of successive moving masses/forces are investigated. To do a thorough study on the subject at hand, a parametric sensitivity analysis by taking into account the effects of the magnitude of the traveling mass or equivalent concentrated force, the velocity of the traveling mass/force, beam??s inclination angle, length of the beam, height of the beam and spacing between successive moving masses/forces are carried out. Furthermore, the dynamic magnification factor and normalized time histories of the mid-point of the beam are obtained for various load velocity ratios, and the results are illustrated and compared to the results obtained from traditional linear solution. The influence of the large deflections caused by a stretching effect due to the beam??s immovable end supports is captured. It is seen that the existence of quadratic?Ccubic nonlinear terms in the coupled governing PDEs of motion renders stiffening (hardening) behavior of the dynamic responses of the beam under the action of a moving mass/force.     

Morphological,thermal, rheological,and mechanical properties of polypropylene-nanoclay composites prepared from masterbatch in a twin screw extruder

A commercial homopolymer polypropylene was melt blended with commercial nanoclay masterbatch at different concentrations of nanoclay using twin screw extruder (TSE). The influence of three different concentrations (5, 10, and 15 wt%) of the nanoclay on the morphological, thermal, rheological, and mechanical properties was investigated. The morphology of the nanocomposites was characterized using Scanning Electron Microscope (SEM), whereas, the thermal behavior (e.g., melting and crystallization) was characterized using Differential Scanning Calorimetry (DSC). The melt rheology and dynamic mechanical properties were analyzed using a torsional rheometer. Additionally, the tensile properties were characterized as well. The morphological analysis showed that the nanoclay was well distributed in the PP matrix as indicated by the SEM micrographs. The DSC results showed that the presence of nanoclay in the PP matrix increased the degree of crystallinity of PP-nanoclay composites, which reached a maximum at 5 wt% of nanoclay concentration. However, the melting temperature of the PP-nanoclay composites was not affected by the presence of nanoclay particles. In addition, rheological analysis showed that the melt response gradually changed from pseudo-liquid like to pseudo-solid like as the nanoclay concentration increased. Moreover, the storage modulus (G′) increased by increasing nanoclay content. Furthermore, tensile test results showed that the addition of nanoclay leads to a significant enhancement in the mechanical properties of the PP nanocomposites.     

Geometrical effect on SCF distribution in uni-planar tubular DKT-joints under axial loads

Despite the frequent use of DKT-joints in offshore structures, no parametric equation is available for determining the distribution of stress concentration factors (SCFs) along the brace-to-chord intersection of this type of tubular joints. In the present paper, the effect of non-dimensional geometrical parameters and brace-to-chord inclination angle on the distribution of SCFs and DKT-/KT-joint SCF ratios (SRs) along the weld toe of tubular DKT-joints under the balanced axial loads is studied. Thereafter, a parametric equation is proposed for predicting the distribution of SCFs along the 360° spatial curve of the weld toe. The proposed equation satisfies the acceptance criteria recommended by the UK Department of Energy (DoE), and consequently can reliably be used for design purposes.     

Recycling value of building materials in building assessment systems

The selection of green building materials and products is by far the most controversial task in sustainable construction. Determining the merits of building materials and products in terms of their recycling value, which seems to be a simple matter, is a very controversial topic in building assessment systems. This paper suggests a method to assess energy savings by recycling building materials, which can be a potential indicator of recycling worth. The method takes account of material selection, construction and deconstruction technologies, and the frequency of recycling. The result of this study can be used in assessment tools as a factor separate from the embodied energy. Since embodied energy affects the potential recycling energy, another factor is defined, based on these two factors, in order to make it possible to compare and select materials correctly, based on their embodied energy and recycling potential.     

Leaching of a zinc ore and concentrate using the Geocoat™ technology

In this study, the Geocoat™ technology was used for the extraction of zinc from a mineral concentrate obtained from the Kooshk mine (Yazd, Iran) by a culture dominated by the mesophilic bacterium Acidithiobacillusferrooxidans in a packed column bioreactor. A low grade sphalerite ore was used as support for the concentrate coating. During the 100 days of leaching pH, Fe³⁺, Fe^total, microbial population density and zinc extraction were measured. The final zinc extraction from concentrate and low grade support was 97% and 78%, respectively, and it was found that leaching from the support does not proceed significantly before leaching from the coating is completed.     

The S-transform using a new window to improve frequency and time resolutions

The S-transform presents arbitrary time series as localized invertible time–frequency spectra. This transformation improves the short-time Fourier transform and the wavelet transform by merging the multiresolution and frequency-dependent analysis properties of wavelet transform with the absolute phase retaining of Fourier transform. The generalized S-transform utilizes a combination of a Fourier transform kernel and a scalable-sliding window. The common S-transform applies a Gaussian window to provide appropriate time and frequency resolution and minimizes the product of these resolutions. However, the Gaussian S-transform is unable to obtain uniform time and frequency resolution for all frequency components. In this paper, a novel window based on the $t$ student distribution is proposed for the S-transform to achieve a more uniform resolution. Simulation results show that the S-transform with the proposed window provides in comparison with the Gaussian window a more uniform resolution for the entire time and frequency range. The result is suitable for applications such as spectrum sensing.     

Efficient and practical resource block allocation for LTE-based D2D network via graph coloring

In this paper, we construct a practical framework for efficiently allocating long term evolution (LTE) resource blocks (RB) among the users in a device-to-device (D2D) network. For such network that presumably operates under the LTE cellular network, our aim is to improve the overall throughput of D2D connections using opportunistic or fairness-based approach. Taking the practical considerations into account, our proposed framework allows a number of connections to share a single RB whenever possible, thus utilizing the radio resources. To do so, our solution first identifies a superior set of the interference-free D2D reuse groups via graph modeling and graph coloring approach. In particular, we model a D2D network with a two-overlapping disk graph for which a suitable coloring algorithm is proposed and its performance bound is calculated. Once the reuse groups are known, our solution optimizes the RB allocation among these groups based on their reported channel condition as well as the scheduling criterion, whether it is fairness-based or opportunistic. Through numerical experiments, we show that our solution can significantly improve the throughput performance of a D2D network.