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51.
Over the past five years or so, pervasive computing has emerged as a new computing paradigm with a great deal of appeal. Enterprises are increasingly showing interest in deploying pervasive information technology (IT) infrastructures to realise the perceived benefits offered by this new computing paradigm. However, a return on the investment and considerations of the currently deployed infrastructure is a constraint for businesses to invest in a pervasive IT infrastructure. Realising that the economics of an investment in a new infrastructure can affect the embracing of pervasive IT, we suggest an approach that shows how the existing technology solutions available in the market and deployed in an enterprise can be used to develop a pervasive IT infrastructure, thereby protecting investments and maximising returns. We present an evolution model to systematically and incrementally achieve a pervasive IT environment, and present guidelines for evaluating which services to develop first based on evolving the existing infrastructure point of view. This work provides practical implications for enterprises as well as pointers for research.
Deependra MoitraEmail: Phone: +91-80-8520261Fax: +91-80-8520740
  相似文献   
52.
    
Direct air capture (DAC) of CO2 has emerged as the most promising “negative carbon emission” technologies. Despite being state-of-the-art, sorbents deploying alkali hydroxides/amine solutions or amine-modified materials still suffer from unsolved high energy consumption and stability issues. In this work, composite sorbents are crafted by hybridizing a robust metal-organic framework (Ni-MOF) with superbase-derived ionic liquid (SIL), possessing well maintained crystallinity and chemical structures. The low-pressure (0.4 mbar) volumetric CO2 capture assessment and a fixed-bed breakthrough examination with 400 ppm CO2 gas flow reveal high-performance DAC of CO2 (CO2 uptake capacity of up to 0.58 mmol g−1 at 298 K) and exceptional cycling stability. Operando spectroscopy analysis reveals the rapid (400 ppm) CO2 capture kinetics and energy-efficient/fast CO2 releasing behaviors. The theoretical calculation and small-angle X-ray scattering demonstrate that the confinement effect of the MOF cavity enhances the interaction strength of reactive sites in SIL with CO2, indicating great efficacy of the hybridization. The achievements in this study showcase the exceptional capabilities of SIL-derived sorbents in carbon capture from ambient air in terms of rapid carbon capture kinetics, facile CO2 releasing, and good cycling performance.  相似文献   
53.
PVC has been modified by chlorine displacement reaction with m-aminophenol, bisphenol A, and phenophthalein. Sulfonation of these condensates yields bifunctional weak acid resins which do not exhibit ? SO3H ionogenic group. Reaction of PVC with presulfonated bisphenol A, phenolphthalein, and phenol yields strong acid resins. Thermal stability characteristics of these various resins have been determined and the results indicate that such modifications improve the overall thermal stability of PVC.  相似文献   
54.
    
A facile synthesis of a new class of reactive porous materials is reported: hierarchically porous hydrogen silsesquioxane (HSiO1.5, HSQ) monoliths with well‐defined macropores and mesopores. The HSQ monoliths are prepared via sol‐gel accompanied by phase separation in a mild condition, and contain micrometer‐sized co‐continuous macropores and high specific surface area reaching up to 800 m2 g?1 because of the small mesopores. A total preservation of Si–H, which is always an issue of HSQ materials, is confirmed by 29Si solid‐state NMR. The HSQ monolith has then been subjected to reduction of noble metal ions to their corresponding metal nanoparticles in simple aqueous solutions under an ambient condition. The nanoparticles produced in this manner are immobilized on the HSQ monolith and are characterized by X‐ray diffraction (XRD) and high angle annular dark‐field scanning transmission electron microscopy (HAADF‐STEM). Both the bare HSQ and nanoparticles‐embedded HSQ are promising as heterogeneous catalysts, exhibiting reusability and recyclability.  相似文献   
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