Correlates of employee lateness: Some theoretical considerations.

Using hypothesis-driven meta-analytic procedures on 30 samples containing 118 correlations, researchers examined competing models of the relationship between lateness and assorted work-related variables. Consistent with a progression withdrawal model, the mean corrected lateness-absence correlation, .40, was found to be higher than the lateness-turnover correlation, .27. Hypotheses regarding the relationships between lateness and attitudes, performance, and demographics were generally supported. Methodological issues, including the need for longitudinal designs in the field and the inclusion of other moderators such as organizational and personality variables, were discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Thermal energy storage in columns packed with crosslinked polyethylene tubes

An energy storage system based on solid-solid phase transition of crosslinked polyethylene was constructed and tested. The energy storage unit consisted of a column packed with crosslinked polyethylene tubes. The solid-solid phase transition enables heat transfer by direct contact between the form-stable polymer and the hot (cold) fluid. A theoretical model for the simulation of this system was developed. The heating-cooling characteristics of the energy storage system were simulated by the model, using measured thermodynamic properties of the crosslinked polyethylene. The potential of various crosslinked polyethylene materials for energy storage applications will depend on sufficient high-temperature stability.     

The relation between limb dominance, acceptance of disability, and the phantom limb phenomenon.

Examined 2 hypotheses regarding the phantom limb sensation (PLS). One predicted that the frequency of PLS would be greater for the dominant than the nondominant limb. The 2nd hypothesized that there is an inverse relation between acceptance of the disability and frequency of PLS. 18 double-amputees who had lost 2 homologous limbs while in military service were administered questionnaires examining limb dominance, frequency of the PLS, and acceptance of disability. Results confirm only the 1st hypothesis. The PLS is discussed in light of the present findings, and it is concluded that the role of physiological factors seems to be clearer than that of psychological ones. (21 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Water binding and irreversible dehydration processes in cellulose acetate membranes

The relative amounts of freezing and nonfreezing water in various water-wet cellulose acetate (CA) membranes were determined by NMR techniques, from the initial heights of the water component in the free induction decay (MNR intensity). The results suggest that (1) a significant fraction of the water in various wet CA membranes does not freeze, probably because of strong interaction with the polymer; (2) the relaxation times T₂ of the nonfreezing water are of the order of milliseconds indicating that they are still highly mobile compared with ice; (3) all the water contained in dense CA films or in membranes equilibrated at relative humidity of 0.93 does not freeze upon cooling the membranes from room temperature to ?60°C; (4) the amounts of nonfreezing bound water in membranes is higher than the total amount of water absorbed from liquid water by a dense film of the same polymer. However, the amounts of nonfreezing water in various CA membranes as calculated from the “relative NMR intensities” is substantially lower than those calculated from DSC melting endotherms by assuming the heat of fusion of water in membranes to be identical to that of pure water. Various possible reasons for this discrepancy are discussed. Measurements on the first desorption-adsorption cycle of wet CA membranes have also been performed. They suggest that during the first dehydration process, irreversible changes are induced in the structure of the membrane which result in a significantly lower accessibility of the polymer to interact with water. The extent of these irreversible changes in membrane structure is dependent on the details of the dehydration process being more pronounced at higher temperatures.     

Explicit stiffness matrices for non-prismatic members

Explicit terms for the stiffness matrices of several common non-prismatic members are derived. The stiffnesses are formulated from the flexibilities of the element. Fortran subroutines which generate the stiffness matrices for use with analysis programs are given. Comparison fo the values derived by the suggested formulation with known results is made. The formulation is highly recommended for small in-house computers which are short on memory.     

Magnetic resonance imaging (MRI) and relaxation spectrum analysis as methods to investigate swelling in whey protein gels

Effective means for controlled delivery of nutrients and nutraceuticals are needed. Whey protein-based gels, as a model system and as a potential delivery system, exhibit pH-dependent swelling when placed in aqueous solutions. Understanding the physics that govern gel swelling is thus important when designing gel-based delivery platforms. The extent of swelling over time was monitored gravimetrically. In addition to gravimetric measurements, magnetic resonance imaging (MRI) a real-time noninvasive imaging technique that quantified changes in geometry and water content of these gels was utilized. Heat-set whey protein gels were prepared at pH 7 and swelling was monitored in aqueous solutions with pH values of 2.5, 7, and 10. Changes in dimension over time, as characterized by the number of voxels in an image, were correlated to gravimetric measurements. Excellent correlations between mass uptake and volume change (R(2)= 0.99) were obtained for the gels in aqueous solutions at pH 7 and 10, but not for gels in the aqueous solution at pH 2.5. To provide insight into the mechanisms for water uptake, nuclear magnetic resonance (NMR) relaxation times were measured in independent experiments. The relaxation spectrum for the spin-spin relaxation time (T(2)) showed the presence of 3 proton pools for pH 7 and 10 trials and 4 proton pools for pH 2.5 trials. Results demonstrate that MRI and NMR relaxation measurements provided information about swelling in whey protein gels that can constitute a new means for investigating and developing effective delivery systems for foods.     

Monitoring the effects of divalent ions (Mn and Ca) in heat-set whey protein gels

Exploring the effects of cations in whey protein-based gels (WPG) is of importance when these gels are used for controlled release applications in food systems. The objective of this study was to evaluate both water uptake and cation release from heat-set WPGs. Magnetic Resonance Imaging and NMR relaxometry were employed to study the uptake and release. A non-paramagnetic (Ca⁺²) and a paramagnetic cation (Mn⁺²) were incorporated into the WPG as model divalent cations. Cylindrical pieces of WPGs with manganese were immersed in water (pH 2.40, 7.00, 10.40) or in EDTA solution whereas WPGs with calcium were immersed in water at pH 2.40. Water uptake by the gels was influenced by both ionic environment and pH. The release of Mn⁺² from WPG was enhanced by the presence of EDTA. Relaxation spectra of Mn⁺²-loaded gels were significantly influenced by pH of the suspending fluid and by the presence of EDTA. Results of relaxometry experiments, obtained with Ca⁺²-loaded gels immersed in water at pH 2.40, indicated a strong correlation (R² > 0.99) between relative areas of the proton pools and the amount of calcium released to the medium. Results support the use of MRI and NMR to monitor cation release and water uptake in WPG, non-destructively.     

Effect of Radio-Frequency and Low-Frequency Bias Voltage on the Formation of Amorphous Carbon Films Deposited by Plasma Enhanced Chemical Vapor Deposition

The effect of radio-frequency （RF） or low-frequency （LF） bias voltage on the for- mation of amorphous hydrogenated carbon （a-C：H） films was studied on silicon substrates with a low methane （CH4） concentration （2-10 vol.%） in CH4＋Ar mixtures. The bias substrate was applied either by RF （13.56 MHz） or by LF （150 kHz） power supply. The highest hardness values （~18-22 GPa） with lower hydrogen content in the fihns （~20 at.%） deposited at 10 vol.% CH4, was achieved by using the RF bias, However, the films deposited using the LF bias, under similar RF plasma generation power and CH4 concentration （50 W and 10 vol.%, respectively）, displayed lower hardness （~6-12 GPa） with high hydrogen content （~40 at.%）. The structures analyzed by Fourier Transform Infrared （FTIR） and Raman scattering measurements provide an indication of trans-polyacetylene structure formation. However, its excessive formation in the films deposited by the LF bias method is consistent with its higher bonded hydrogen concentration and low level of hardness, as compared to the film prepared by the RF bias method. It was found that the effect of RF bias on the film structure and properties is stronger than the effect of the low-frequency （LF） bias under identical radio-frequency （RF） powered electrode and identical PECVD （plasma enhanced chemical vapor deposition） system configuration.     

THE SHAPE OF A GAS/LIQUID INTERFACE IN A RECTANGULAR CAVITY ALLOWING FOR AN ARBITRARY DIRECTION OF THE BODY FORCE

A method to calculate the shape of the gas/liquid interface in a rectangular cavity is presented. This article is an expansion of investigations carried out in the 1960s, where the direction of the body force was assumed to be parallel to the side walls of the cavity. In the present work this assumption is eliminated, thus introducing the tilt angle as an additional variable affecting the interface shape. The shape of the interface for several values of Bond number, contact angle, and tilt angle is calculated. A critical Bond number below which the interface shape does not change is identified. The implications to liquid-phase processing in micromachining and microelectronics fabrication are discussed.