Topographic characterization of unworn contact lenses assessed by atomic force microscopy and wavelet transform

This paper analyses the three‐dimensional (3‐D) surface morphology of optic surface of unworn contact lenses (CLs) using atomic force microscopy (AFM) and wavelet transform. Refractive powers of all lens samples were 2.50 diopters. Topographic images were acquired in contact mode in air‐conditioned medium (35% RH, 23°C). Topographic measurements were taken over a 5 µm × 5 µm area with 512 pixel resolution. Resonance frequency of the tip was 65 kHz. The 3‐D surface morphology of CL unworn samples revealed (3‐D) micro‐textured surfaces that can be analyzed using (AFM) and wavelet transform. AFM and wavelet transform are accurate and sensitive tools that may assist CL manufacturers in developing CLs with optimal surface characteristics. Microsc. Res. Tech. 78:1026–1031, 2015. © 2015 Wiley Periodicals, Inc.     

Microstructure and wear properties of plasma‐sprayed aluminum–silicon–polyester coatings

Powder coatings, which are made by plasma‐spraying processes, are being used in industrial applications because of their wear resistance, chemical resistance, and high impact strength even at low service temperatures. These factors increase the importance of plastic and plastic‐based coatings in industrial applications. In this study, an aluminum–silicon–polyester‐based composite coating was applied by plasma‐spraying processes with and without an intermediate bond coat (Ni–Al). The effects of the coating thickness, intermediate bond coat, and processes parameters on the microstructure and wear properties of the coating were studied experimentally. The wear properties of the coatings were determined according to ball‐on‐disk procedure. The microstructures of the coating were examined by optical microscopy and scanning electron microscopy. The results indicated that the plasma‐spraying current and thickness had a strong influence on the wear resistance and microstructural properties of the aluminum–silicon–polyester coating. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3609–3614, 2006     

APPLICATION OF MULTIVARIABLE NONLINEAR ADAPTIVE GENERIC MODEL CONTROL TO A PACKED DISTILLATION COLUMN

Nonlinear adaptive generic model control and self-tuning PID control systems were applied to control the top and bottom product temperature of a packed distillation column separating methanol-water mixture. In the first control algorithm, an adaptive generic model control (AGMC) structure was proposed for dual temperature control of the system. In the second control algorithm, nonlinear self tuning PID (NLSTPID) control based on pole-placement technique was used to control the same system. For NLSTPID control purposes pseudo random binary sequence (PRBS) signal and recursive identification algorithm were used to estimate the relevant parameters of a polynomial NARMAX model. In this work, real-time application has been carried out. In both dynamic and control studies, perturbations in feed composition were utilized as the disturbance, and the reboiler heat duty and the reflux ratio were selected as the manipulated variables. The control performances have been obtained by using ISE and, in general, AGMC results were better than those of the STPID control algorithm.     

Investigations of friction stir welding process using finite element method

The aim of this study is to investigate the process of friction stir welding (FSW) by using finite element method (FEM). Currently, the materials that are difficult to be joined with conventional fusion methods can now be easily joined with the method of friction stir welding. In this paper, the welding capability of many different materials with this method has been investigated by using analytical and numeric methods. In this study, a finite element (FE) model was developed for welding process with friction stir welding of AZ31 magnesium alloy. This model was performed by the software of DEFORM 3D finite element in 960, 1,964, and 2,880 rpm rotational speeds and in 10 and 20 mm?min^?1 transverse speeds. The temperature values taken from experiments and the temperature values with FEM are compared, and according to these results, it can be stated that the FE model gives reasonable results with experimental results based on temperatures values. Hence, the FE model can be used to predict other parameters of FSW process in future studies.     

Dissolution kinetics of WO3 in acidic solutions

Potentiostatic polarization and rotating disk electrode techniques were used to obtain the rate constant for the dissolution of electrochemically-formed (at 1 V) WO₃ on tungsten (W) in acidic solutions. The corresponding rate constant for the chemical dissolution of WO₃(s) powder was found by measuring the dissolved tungsten concentration as a function of time and pH. The chemical dissolution experiments supported the view that the rate-determining step in the anodic reaction of W in acidic solution is the chemical dissolution of WO₃(s) formed on the metal surface. Zeta potential measurements gave the isoelectric point (iep) of the WO₃(s) powder as pH 1.5, a value that was somewhat smaller than the point of zero charge (pzc) of WO₃(s) formed on W metal (pH 2.5). This difference was attributed to the highly hydrated nature of the oxide film formed on W metal in aqueous systems.     

Seawater effect on pin-loaded laminated composites with two parallel holes

The aim of this study was to investigate the effects of seawater on the failure mode, first failure load and bearing strength behaviour of the pinned joint of fibreglass-reinforced woven epoxy composite prepregs. The specimens were kept in seawater for 3- and 6-month periods. After each period, their mechanical properties were examined. The edge distance-to-upper hole diameter (E/D), the two hole-tohole centre diameter (K/D), the distance from the upper or the lower edge of the specimen to the centre of the hole-to-hole diameter (M/D), and the width of the specimen-to-hole diameter (W/D) ratios were selected as parameters. Moreover, the finite element models of the specimens were developed using ANSYS software, and the Tsai-Wu criterion was used to obtain the first failure load. The numerical and experimental results were compared and were found to be in good agreement for the first failure load.     

Role of pretreatment with potassium permanganate and urea on mechanical and degradable properties of photocured coir (Cocos nucifera) fiber with 1,6‐hexanediol diacrylate

Coir fibers were modified with 1,6‐hexanediol diacrylate (HDDA) using ultraviolet (UV) radiation. Concentration of HDDA, soaking time, and radiation dose were optimized and found to be 30% HDDA in methanol along with photoinitiator Irgacure‐500 (2%) and 120 min of soaking time registered as the better performance (polymer loading (PL) 7%, tensile strength factor, T_f = 1.50). Urea of different concentrations (0.5–2%) were incorporated with 30% HDDA to monitor its effect on the properties and 1% urea produced the best results (PL = 25%, T_f = 1.82). For the improvement of the properties, the fibers were subjected to surface treatment with potassium permanganate (KMnO₄) of different concentrations at various treating times. Enhanced properties (PL = 86%. T_f = 4.42) of the fibers treated with KMnO₄ (0.05%) were obtained. The KMnO₄ treated fibers were again treated with HDDA (30%) solution along with urea (1%) and found to produce the best results (PL = 100%, T_f = 4.5). Water uptake and degradable properties of the treated and virgin fibers were obtained. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 4361–4368, 2006     

Drilling of a hybrid Al/SiC/Gr metal matrix composites

The present study investigates the influence of cutting parameters on cutting force and surface roughness in drilling of Al/20%SiC/5%Gr and Al/20%SiC/10%Gr hybrid composites fabricated by vortex method. The drilling tests are conducted with diamond-like carbon-coated cutting tools. This paper is an attempt to understand the machining characteristics of the new hybrid metal matrix composites. The results indicate that inclusion of graphite as an additional reinforcement in Al/SiCp reinforced composite reduces the cutting force. The cutting speed and its interactions with feed rate are minimum. Feed rate is the main factor influencing the cutting force in both composites. The surface roughness value is proportional with the increase in feed rate while inversely proportional with cutting speed in both composites. For all cutting conditions, Al/20%SiC/10%Gr composite has lower surface roughness values than Al/20%SiC/5%Gr composite. The surface is analyzed using scanning electron microscope.     

Analysis of the electrochemical reaction behavior of alloy AZ91 by EIS technique in H3PO4/KOH buffered K2SO4 solutions

The EIS technique was used to analyze the electrochemical reaction behavior of Alloy AZ91 in H₃PO₄/KOH buffered K₂SO₄ solution at pH 7. The corrosion resistance of Alloy AZ91 was directly related with the stability of Al₂O₃ · xH₂O rich part of the composite oxide/hydroxide layer on the alloy surface. The break down of the oxide layer was estimated to occur mainly on the matrix solid solution phase in Alloy AZ91. The mf capacitive loop arose from the relaxation of mass transport in the solid oxide phase in the presence of Al₂O₃ · xH₂O rich part and from Mg⁺ ion concentration within the broken area in the absence of Al₂O₃ · xH₂O rich part in the composite oxide structure on the alloy surface. The lf inductive loop had tendency of disappear when the dissolution rate of the alloy decreased as a result of the formation of the protective oxide layer.     

A study of the Taguchi optimization method for surface roughness in finish milling of mold surfaces

The objective of this paper is to develop a Taguchi optimization method for low surface roughness in terms of process parameters when milling the mold surfaces of 7075-T6 aluminum material. Considering the process parameters of feed, cutting speed, axial-radial depth of cut, and machining tolerance, a series of milling experiments were performed to measure the roughness data. A regression analysis was applied to determine the fitness of data used in the Taguchi optimization method using milling experiments based on a full factorial design. Taguchi orthogonal arrays, signal-to-noise (S/N) ratio, and analysis of variance (ANOVA) are used to find the optimal levels and the effect of the process parameters on surface roughness. A confirmation experiment with the optimal levels of process parameters was carried out in order to demonstrate the effectiveness of the Taguchi method. It can be concluded that Taguchi method is very suitable in solving the surface quality problem of mold surfaces.