A light refractory concrete for thermal insulation

Compositions have been developed for nonshrinking vibrocast thermally insulating light refractory concretes with densities of 1.0, 1.3, 1.5, and 1.8 g/cm³ for temperatures of use up to 1400°C. The structure and properties have been examined for the concrete of density 1.3 g/cm³. __________ Translated from Novye Ogneupory, No. 4, pp. 29–32, April, 2008.     

Total and Fractional Performance of Granular Dust Traps in Refractory Production

Methods are proposed for designing interpolation models for the preliminary determination and subsequent forecasting of general and fractional breakthrough coefficients for dust used with granular filters, as employed in energy-saving and high-performance dust trapping from technological gases and ventilation discharges in refractory production. The models are supplied with nomograms, which makes them widely suitable for experts working in environmental protection at refractory-producing organizations. The main factors are identified that influence the performance. The results are of interest to experts in related areas of industry such as building materials and engineering ceramics and so on. Translated from Novye Ogneupory, No. 4, pp. 64–67, April, 2008.     

Optimizing the selective flocculation of coal by means of a selective reagent

The need to improve coal enrichment stems from the sharp deterioration in the coal being enriched (increasing ash and moisture content, content of small classes, rock content, etc.), which results from the widespread mechanization of mining operations, the development of high-ash deposits, and dust suppression [1].     

Granular-structure chromium-bearing refractories: Properties and uses

Results are presented on the corrosion resistance of chromium-bearing refractories of granular structure acted on by corrosive molten slags, metals, and glasses. It is possible to recommend these refractories to customers for particular conditions of use. Chromium-bearing refractories increase the working lives of furnaces considerably. __________ Translated from Novye Ogneupory, No. 1, pp. 55–61, January, 2008.     

Formation of the complex oxide NaNdTiO<Subscript>4</Subscript>

The processes of phase formation in the Na₂CO₃-TiO₂ and Na₂CO₃-TiO₂-Nd₂O₃ systems are investigated in the temperature range 600–900°C. The high-temperature solid-phase reactions underlying the process of formation of complex oxide NaNdTiO4 are studied. It is established that the synthesis of the NaNdTiO₄ compound occurs through the reaction of the intermediate product Na₈Ti₅O₁₄ with neodymium oxide in the temperature range 720–780°C. The optimum method is proposed for synthesizing NaNdTiO₄, which makes it possible to reduce the temperature of the synthesis, to avoid the formation of impurities, and to obtain the product in a finely dispersed state.     

Features of phase transitions in electrolyzer hearth block material between joints

Phase transitions are considered for silicon oxycarbide material between joints in hearth blocks under aluminum electrolyzer operating conditions. It is established that in the electrolyzer there is formation of aluminum subcarbide, and also there is conversion of silicon carbide polytypes as a result of impurities of aluminum, sodium, magnesium, copper and iron. Due to phase transitions there is a reduction in joint strength, and therefore it is undesirable to use material based on corundum and black silicon carbide in hearth joints between blocks for aluminum electrolyzers. Use of pure α-SiO₂ free from impurities is recommended for this purpose. Translated from Novye Ogneupory, No. 4, pp. 47–52, April 2008.     

Synthesis of nanocrystalline solid solutions based on zirconia and hafnia

Nanosized (2–8 nm) amorphous powders of the solid solution based on zirconia and hafnia are synthesized through back coprecipitation upon treatment of gels at temperatures from +20 to −77°C. Heat treatment of these powders at temperatures up to 1000 and above 1100°C leads to the formation of cubic (fluorite type, O _h ⁵ = Fm3m) and tetragonal phases of the Zr₈₂Hf₁₀Y₃Ce₅O _x composition, respectively. It is revealed that a decrease in the synthesis temperature (from +20°C to −6°C) results in a decrease in the size of gel agglomerates from 30 to 1 μm. Recrystallization processes in the gels prepared using cryochemical treatment are developed very slowly in the temperature range 500–1200°C (the crystallite size does not exceed 25 nm). Original Russian Text ? T.I. Panova, V.B. Glushkova, A.E. Lapshin, 2008, published in Fizika i Khimiya Stekla.     

Dynamic modes of Ti combustion in a coflow of N<Subscript>2</Subscript>-Ar mixture

Combustion of bulk density Ti powder (containing 20 wt % TiN as a diluent) in a coflow of N₂-Ar mixture was investigated upon variation in the nitrogen content of the gaseous mixture. The obtained data are believed to open up new horizons for fabrication of layered and composite ceramics by infiltration-mediated combustion.