Ag-ZnO catalysts for UV-photodegradation of methylene blue

High surface area Ag-ZnO catalysts have been made by flame spray pyrolysis (FSP) and characterized by X-ray diffraction (XRD), nitrogen adsorption, UV–vis spectroscopy and electron microscopy (SEM and transmission electron microscopy (TEM)) combined with energy dispersive X-ray spectroscopy (EDXS) for elemental mapping. Silver metal clusters deposited directly on ZnO nanocrystals were obtained from this process. The Ag loading (1–5 at.%) controlled the Ag cluster size from 5 to 25 nm but did not influence the ZnO crystal size. Photodegradation of 10 ppm methylene blue (MB) solution was used to evaluate the performance of these FSP-made Ag-ZnO and was compared to wet-made Ag-ZnO and reference titania photocatalysts. The rate of photodegradation was optimal for Ag loading around 3 at.%. The best photocatalytic performance was exhibited by flame-made Ag-ZnO produced at the longest high-temperature residence times having high crystallinity as determined by XRD and UV–vis.     

Diterpene resin acids: Major active principles in tall oil against Variegated cutworm,Peridroma saucia (Lepidoptera: Noctuidae)

Tall oil, a by-product of the kraft process for pulping softwood, has been shown to have insecticidal properties. In the present study, the active principles in tall oil against the variegated cutworm,Peridroma saucia Hübner, were investigated. GC-MS analysis showed that abietic, dehydroabietic, and isopimaric acids were major resin acid components of crude tall oil and depitched tall oil. When crude tall oil samples of differing resin acid composition were incorporated into artificial diet at a concentration of 2.0% fresh weight, they suppressed larval growth by 45–60% compared to controls. This suppression was significantly (P0.05) correlated with the equivalent contents of abietic, dehydroabietic, isopimaric, and total resin acids. These results were also evident from a diet choice test, showing that the second-instar larvae obviously selected diets with low levels of resin acids when different diets were randomly arranged in a Petri dish. Bioassays with pure resin acids (abietic, dehydroabietic, and isopimaric acids) demonstrated that all individual chemicals have similar bioactivity against this insect. Comparison of the bioactivities of depitched tall oil and an equivalent mixture of pure resin acids in thePeridroma chronic growth bioassay indicated that pure resin acids and depitched tall oil share a common mode of action to this insect. This study confirms that resin acids are major active principles in tall oil against the variegated cutworm, but other chemicals likely also contribute to the bioactivity of tall oil.     

The role of fats and oils in cosmetics

The earliest emollients in the history of cosmetics were the naturally occurring animal fats and vegetable oils. These provided soothing and smoothing action on the skin and grooming effects on head and beard hair. For the most part, odor problems limited the interest in oils derived from fish. With the increasing sophistication of users and increasing understanding of the technology of these materials, the short-comings of natural fats and oils were overcome in several ways: (a) increased stability through use of antioxidants; (b) reduced odor through improved processing; (c) improved stability and diversification through chemical modification; (d) increased diversity through preparation of derivatives, and (e) substitution of mineral oil. Today the most important single cosmetic use of an unmodified natural fat or oil is that of castor oil as the base for lipsticks. Other unmodified oils have largely minor specialty uses, particularly in higher-priced cosmetics. These include almond oil, apricot kernel oil, sesame oil, safflower oil, wheat germ oil, avocado oil, turtle oil and mink oil. Cocoa butter is used to some extent in suntan products. Reconstituted fractionated coconut oil is widely used. Polyglycerol esters of fatty acids are increasing in importance. Hydrogenation has produced stable oils useful in cosmetics. Alkyl esters and monoglycerol esters of fatty acids offer a wider range of properties than the original oils. Improvements in the naturally occurring fats and oils have made it possible for them to compete in some characteristics, and current interest in “natural” cosmetics may turn the attention of the cosmetic chemist back to improved versions of the classical raw materials. One of five papers in the symposium “Fats and Oils in Cosmetics and Pharmaceuticals,” presented at the AOCS Meeting, Atlantic City, October 1971.     

Fundamentals of bitumen coking processes analogous to granulations: A critical review

A number of coking processes use hot particles to heat liquid bitumen or petroleum residue to cause cracking reactions. These particles may be mineral or coke solids. Interactions of these particles, in fluid beds, moving beds and other types of contactors, are governed by the liquid films on the particle surfaces. This paper explores the analogy between granulation and coking, and suggests that the key relationships that will govern the behavior of wet particles in coking processes are the Stokes number of the particles, the thickness or the liquid films, and the diameter and surface roughness of the particles. The implications for distribution of liquid feed in the reactor, fouling, and defluidization or bogging are discussed. This analysis suggests experiments that can be performed under non‐reactive conditions with scaled variables in order to study phenomena that cannot be observed in situ in high‐temperature cracking processes.     

THE QUEST FOR WORLD CLASS IT CAPABILITY IT Is Key to Achieving Quality Goals

Abstract

In today's competitive world, many organizations are pursuing total quality improvement programs, and as a result of these initiatives, are seeking to define world class capabilities. The organizations with these aspirations are trying to improve product and service quality, business process quality, or delivered quality, and are becoming aware that information technology is playing a more substantial role in realizing these quality goals.     

Involving the user Through Library 2.0

Libraries, as we know them today, can be defined by the term Library 1.0. This defines the way resources are kept on shelves or at a computer behind a login. These resources can be taken from a shelf, checked out by the library staff, taken home for a certain length of time and absorbed, and then returned to the library for someone else to avail of. Library 1.0 is a one-directional service that takes people to the information they require. Library 2.0 – or L2 as it is now more commonly addressed as – aims to take the information to the people by bringing the library service to the Internet and getting the users more involved by encouraging feedback participation. This paper presents an overview of Library 2.0 and introduces web 2.0 concepts.     

Development and Deployment of an Intelligent Kite Aerial Photography Platform (iKAPP) for Site Surveying and Image Acquisition

Aerial photographs and images are used by a variety of industries, including farming, landscaping, surveying, and agriculture, as well as academic researchers including archaeologists and geologists. Aerial imagery can provide a valuable resource for analyzing sites of interest and gaining information about the structure, layout, and composition of large areas of land that would be unavailable otherwise. Current methods of acquiring aerial images rely on techniques such as satellite imagery, manned aircraft, or more recently unmanned aerial vehicles (UAVs) and micro‐UAV technologies. These solutions, while accurate and reliable, have several drawbacks. Using satellite imagery or UAVs can prove to be very expensive, costing tens of thousands for images. They can also prove to be time‐consuming and in some cases have constraints on use, such as no‐fly zones. In this paper, we present an alternative low‐cost, versatile solution to these methods, an intelligent kite aerial photography platform (iKAPP), for the purpose of acquiring aerial images and monitoring sites of interest. We show how this system provides flexibility in application, and we detail the system's design, mechanical operation, and initial flight experiments for a low‐cost, lightweight, intelligent platform capable of acquiring high‐resolution images. Finally, we demonstrate the system by acquiring images of a local site, showing how the system functions and the quality of images it can capture. The application of the system and its capabilities in terms of capture rates, image quality, and limitations are also presented. The system offers several improvements over traditional KAP systems, including onboard “intelligent” processing and communications. The intelligent aspect of this system stems from the use of self‐image stabilization of the camera, the advantage being that one is able to configure the system to capture large areas of a site automatically, and one can see the site acquisition in real time, all of which are not possible with previous methods of AP. © 2013 Wiley Periodicals, Inc.     

Siting park-and-ride facilities using a multi-objective spatial optimization model

Park-and-ride services are an important component of many public transportation systems in the United States. Locating park-and-ride facilities is an essential step when planning for these services. In this research we focus on three major siting/modeling concerns that need to be addressed when siting park-and-ride facilities: covering as much potential demand as possible, locating park-and-ride facilities as close as possible to major roadways, and siting such facilities in the context of an existing system. Unfortunately, existing models do not enable each of these concerns to be simultaneously addressed. This paper presents a multi-objective spatial optimization model for integrating these considerations. This model is applied for siting park-and-ride facilities in Columbus, Ohio. Application results show the usefulness of the developed model in supporting transit planning in an urban region.