Simultaneous microbial reduction of iron(III) and arsenic(V) in suspensions of hydrous ferric oxide

Bacterial reduction of arsenic(V) and iron(III) oxides influences the redox cycling and partitioning of arsenic (As) between solid and aqueous phases in sediment-porewater systems. Two types of anaerobic bacterial incubations were designed to probe the relative order of As(V) and Fe(III) oxide reduction and to measure the effect of adsorbed As species on the rate of iron reduction, using hydrous ferric oxide (HFO) as the iron substrate. In one set of experiments, HFO was pre-equilibrated with As(V) and inoculated with fresh sediment from Haiwee Reservoir (Olancha, CA), an As-impacted field site. The second set of incubations consisted of HFO (without As) and As(III)- and As(V)- equilibrated HFO incubated with Shewanella sp. ANA-3 wild-type (WT) and ANA-3deltaarrA, a mutant unable to produce the respiratory As(V) reductase. Of the two pathways for microbial As(V) reduction (respiration and detoxification), the respiratory pathway was dominant under these experimental conditions. In addition, As(III) adsorbed onto the surface of HFO enhanced the rate of microbial Fe(III) reduction. In the sediment and ANA-3 incubations, As(V) was reduced simultaneously or prior to Fe(III), consistent with thermodynamic calculations based on the chemical conditions of the ANA-3 WT incubations.     

Quantum-Dot Infrared Photodetectors

We present a study of a series of n-i-n InAs quantum-dot infrared photodetectors (QDIPs) with unintentionally doped active regions. Different quantum-dot capping layer materials (GaAs, InGaAs, and AlGaAs) are utilized to tune the operating wavelength and modify the QDIP performance. Normal-incidence operation with high detectivity in the mid (3-5 ) and long (8-12 ) wavelength regimes and the potential for multicolor operation is demonstrated.     

High quantum efficiency, long wavelength InP/InGaAs microcavity photodiode

There is a inherent tradeoff between the quantum efficiency and bandwidth of conventional PIN photodiodes. In the case of devices based on III-V semiconductors, an absorption region thickness of approximately 2 mu m is required to achieve quantum efficiencies greater than 80%, although this limits the transit-time-limited bandwidth to less than 15 GHz. It has recently been shown that a microcavity photodiode can circumvent this performance tradeoff and achieve both high quantum efficiency and large bandwidths. The fabrication of a microcavity PIN photodiode with a high quantum efficiency near 1.55 mu m is described. An external quantum efficiency of 82% at 1480 nm has been achieved with an InGaAs absorption layer only 2000 AA thick embedded in a resonant cavity grown by metal organic vapor phase epitaxy (MOVPE).<>     

Ultra-low noise avalanche photodiodes with a "centered-well" multiplication region

We report avalanche photodiodes with a "centered-well" multiplication region that have achieved high gain, low noise, and low dark current. The multiplication region consists of an /spl sim/80 nm-thick Al/sub 0.2/Ga/sub 0.8/As layer sandwiched between two thin (10/spl sim/20 nm) layers of Al/sub 0.6/Ga/sub 0.4/As. Monte Carlo simulation shows the beneficial effect of spatial modulation of the ionization rates in this structure compared to homojunctions.     

Dynamic core provisioning for quantitative differentiated services

Efficient network provisioning mechanisms that support service differentiation are essential to the realization of the Differentiated Services (DiffServ) Internet. Building on our prior work on edge provisioning, we propose a set of efficient dynamic node and core provisioning algorithms for interior nodes and core networks, respectively. The node provisioning algorithm prevents transient violations of service level agreements (SLA) by predicting the onset of service level violations based on a multiclass virtual queue measurement technique, and by automatically adjusting the service weights of weighted fair queueing schedulers at core routers. Persistent service level violations are reported to the core provisioning algorithm, which dimensions traffic aggregates at the network ingress edge. The core provisioning algorithm is designed to address the difficult problem of provisioning DiffServ traffic aggregates (i.e., rate-control can only be exerted at the root of any traffic distribution tree) by taking into account fairness issues not only across different traffic aggregates but also within the same aggregate whose packets take different routes through a core IP network. We demonstrate through analysis and simulation that the proposed dynamic provisioning model is superior to static provisioning for DiffServ in providing quantitative delay bounds with differentiated loss across per-aggregate service classes under persistent congestion and device failure conditions when observed in core networks.     

Internal gain from an erbium-doped oxyfluoride-silicate glass waveguide fabricated using femtosecond waveguide inscription

A channel waveguide is fabricated inside an erbium-doped oxyfluoride silicate glass sample using femtosecond pulses in the low repetition rate regime. The waveguide cross section is controlled using the multiscan fabrication technique. The 1.85-cm-long waveguide exhibits a total background insertion loss of 4.3 dB when coupled to Corning SMF-28 fibers. Under the maximum available pump power, the device exhibits an internal gain of 1.7 dB at 1537 nm.     

Layer 1 virtual private network management by users

The layer 1 virtual private network (LlVPN) technology supports multiple user networks over a common carrier transport network. Emerging L1VPN services allow: L1VPNs to be built over multiple carrier networks; L1VPNs to lease or trade resources with each other; and users to reconfigure an L1VPN topology, and add or remove bandwidth. The trend is to offer increased flexibility and provide management functions as close to users as possible, while maintaining proper resource access right control. In this article two aspects of the L1VPN service and management architectures are discussed: management of carrier network partitions for L1VPNs, and L1VPN management by users. We present the carrier network partitioning at the network element (NE) and L1VPN levels. As an example, a transaction language one (TL1) proxy is developed to achieve carrier network partitioning at the NE level. The TL1 proxy is implemented without any modifications to the existing NE management system. On top of the TL1 proxy, a Web services (WS)-based L1VPN management tool is implemented. Carriers use the tool to partition resources at the L1VPN level by assigning resources, together with the WS-based management services for the resources, to L1VPNs. L1VPN administrators use the tool to receive resource partitions from multiple carriers and partner L1VPNs. Further resource partitioning or regrouping can be conducted on the received resources, and leasing or trading resources with partner LlVPNs is supported. These services offer a potential business model for a physical network broker. After the L1VPN administrators compose the use scenarios of resources, and make the use scenarios available to the L1VPN end users as WS, the end users reconfigure the L1VPN without intervention from the administrator. The tool accomplishes LlVPN management by users     

Study of reverse dark current in 4H-SiC avalanche photodiodes

Temperature-dependent current-voltage (I-V) measurements have been used to determine the reverse dark current mechanisms in 4H-SiC avalanche photodiodes (APDs). A pn junction vertical mesa structure, passivated with SiO/sub 2/ grown by plasma enhanced chemical vapor deposition, exhibits predominate leakage current along the mesa sidewall. Similar APDs, passivated by thermal oxide, exhibit lower dark current before breakdown; however, when the temperature is higher than 146/spl deg/C, an anomalous dark current, which increases rapidly with temperature, is observed. This current component appears to be eliminated by the removal of the thermal oxide. Near breakdown, tunneling is the dominant dark current mechanism for these pn devices. APDs fabricated from a pp/sup -/n structure show reduced tunneling current. At room temperature, the dark current at 95% of breakdown voltage is 140 fA (1.8 nA/cm/sup 2/) for a 100-/spl mu/m diameter APD. At a gain of 1000, the dark current is 35 pA (0.44 /spl mu/A/cm/sup 2/).     

Recent Advances in Sensing Applications of Graphene Assemblies and Their Composites

Development of next‐generation sensor devices is gaining tremendous attention in both academia and industry because of their broad applications in manufacturing processes, food and environment control, medicine, disease diagnostics, security and defense, aerospace, and so forth. Current challenges include the development of low‐cost, ultrahigh, and user‐friendly sensors, which have high selectivity, fast response and recovery times, and small dimensions. The critical demands of these new sensors are typically associated with advanced nanoscale sensing materials. Among them, graphene and its derivatives have demonstrated the ideal properties to overcome these challenges and have merged as one of the most popular sensing platforms for diverse applications. A broad range of graphene assemblies with different architectures, morphologies, and scales (from nano‐, micro‐, to macrosize) have been explored in recent years for designing new high‐performing sensing devices. Herein, this study presents and discusses recent advances in synthesis strategies of assembled graphene‐based superstructures of 1D, 2D, and 3D macroscopic shapes in the forms of fibers, thin films, and foams/aerogels. The fabricated state‐of‐the‐art applications of these materials in gas and vapor, biomedical, piezoresistive strain and pressure, heavy metal ion, and temperature sensors are also systematically reviewed and discussed, and their sensing performance is compared.     

Evaluation of low ash impact sorbent injection technologies for mercury control at a Texas lignite/PRB fired power plant

A sorbent injection test program was carried out at NRG Texas Power LLC's (NRG) Limestone Electric Generating Station (LMS). LMS fires a 30/70 blend of Powder River Basin (PRB) and Texas Lignite, and is equipped with a cold-side electrostatic precipitator (ESP) and wet scrubber. The plant markets its fly ash for beneficial use, so development of a low ash impact mercury control technology is important to the economics of implementing a mercury control system. In addition to standard activated carbon injection, two different low ash impact mercury control technologies were evaluated in parametric tests: low ash impact sorbents and Toxecon™ II. The parametric ACI test program conducted at LMS demonstrated that high (>90%) levels of mercury removal could be achieved with carbon sorbents. The Toxecon™ II design used at LMS did not provide for as high a mercury removal as injection upstream of the ESP, likely due to poor coverage of the cross-sectional area of the ESP. Limited concrete testing was performed with simulated ash/carbon mixtures. As expected, the amount of air-entraining additive required increased with increasing carbon content in the ash. However, it appeared that small amounts of non-passivated carbon may be acceptable in fly ash for concrete use.