Fully Solution‐Processed Photonic Structures from Inorganic/Organic Molecular Hybrid Materials and Commodity Polymers

Managing the interference effects from thin (multi‐)layers allows for the control of the optical transmittance/reflectance of widely used and technologically significant structures such as antireflection coatings (ARCs) and distributed Bragg reflectors (DBRs). These rely on the destructive/constructive interference between incident, reflected, and transmitted radiation. While known for over a century and having been extremely well investigated, the emergence of printable and large‐area electronics brings a new emphasis: the development of materials capable of transferring well‐established ideas to a solution‐based production. Here, demonstrated is the solution‐fabrication of ARCs and DBRs utilizing alternating layers of commodity plastics and recently developed organic/inorganic hybrid materials comprised of poly(vinyl alcohol) (PVAl), cross‐linked with titanium oxide hydrates. Dip‐coated ARCs exhibit an 88% reduction in reflectance across the visible compared to uncoated glass, and fully solution‐coated DBRs provide a reflection of >99% across a 100 nm spectral band in the visible region. Detailed comparisons with transfermatrix methods (TMM) highlight their excellent optical quality including extremely low optical losses. Beneficially, when exposed to elevated temperatures, the hybrid material can display a notable, reproducible, and irreversible change in refractive index and film thickness while maintaining excellent optical performance allowing postdeposition tuning, e.g., for thermo‐responsive applications, including security features and product‐storage environment monitoring.     

Revisiting Ghoshal and Bartlett’s Theory of the Multinational Corporation as an Interorganizational Network

More than 25 years after its appearance, Ghoshal and Bartlett’s seminal paper ‘The Multinational Corporation as an Interorganizational Network’ stands as a widely recognized but insufficiently understood contribution to the international management literature. This paper reviews related literature, celebrates and critically discusses Ghoshal and Bartlett’s work and proposes ways to address its main limitations, which are a lack of a defined set of parameters describing networks and the delineation of network boundaries. We then translate their theory into concrete propositions and thereby bring it closer to empirical testing. Taking a subsidiary-network perspective, we expand the authors’ work by combining network and entrepreneurship literature and theoretically deducting positive effects of networks on subsidiary entrepreneurial orientation. This yields entirely new insights and a more holistic view of the effects of subsidiary networks.     

Scanning Tunneling Microscopy and Spectroscopy of Novel Silver–Containing DNA Molecules

The quest for a suitable molecule to pave the way to molecular nanoelectronics has been met with obstacles for over a decade. Candidate molecules such as carbon nanotubes lack the appealing trait of self‐assembly, while DNA seems to lack the desirable feature of conductivity. Silver‐containing poly(dG)–poly(dC) DNA (E‐DNA) molecules have recently been reported as promising candidates for molecular electronics, owing to the selectivity of their metallization, their thin and uniform structure, their resistance to deformation, and their maximum possible high conductivity. Ultrahigh vacuum (UHV) scanning tunneling microscopy (STM) of E‐DNA presents an elaborate high‐resolution morphology characterization of these unique molecules, along with a detailed depiction of their electronic level structure. The energy levels found for E‐DNA indicate a novel truly hybrid metal–molecule structure, potentially more conductive than other DNA‐based alternatives.     

Seasonal patterns in hydrochemical mixing in three Great Lakes rivermouth ecosystems

Rivermouth ecosystems in the Laurentian Great Lakes represent complex hydrologic mixing zones where lake and river water combine to form biologically productive areas that are functionally similar to marine estuaries. As urban, industrial, shipping, and recreational centers, rivermouths are the focus of human interactions with the Great Lakes and, likewise, may represent critical habitat for larval fish and other biota. The hydrology and related geomorphology in these deltaic systems form the basis for ecosystem processes and wetland habitat structure but are poorly understood. To this end, we examined hydrogeomorphic structure and lake-tributary mixing in three rivermouths of intermediate size using water chemistry, stable isotopes, and current profiling over a five-month period. In rivermouths of this size, the maximum depth of the rivermouth ecosystem influenced water mixing, with temperature-related, density-dependent wedging and layering that isolated lake water below river water occurring in deeper systems. The inherent size of the rivermouth ecosystem, local geomorphology, and human modifications such as shoreline armoring and dredging influenced mixing by altering the propensity for density differences to occur. The improved scientific understanding and framework for characterizing hydrogeomorphic processes in Great Lakes rivermouths across a disturbance gradient is useful for conservation, management, restoration, and protection of critical habitats needed by native species.     

The Effect of Network Characteristics on Online Identity Management Practices

As online social networking permeates all aspects of personal and professional lives, users of social networking sites (SNSs) are more motivated than ever to manage their online identities to project a favorable impression of themselves to online audiences. This research builds on the boundary management perspective to gain a better understanding of online identity management practices by examining the relationship between characteristics of the online social network, including cognitive homogeneity and social tie variety and the use of identity management practices such as segmentation and self-enhancement. The proposed research model is tested using survey data. The findings suggest cognitive homogeneity is positively related to the use of both identity management practices, segmentation and self-enhancement, whereas social tie variety is positively related to segmentation, but not self-enhancement practices. We conclude with implications of the study results for research and practice, as well as a discussion of directions for future research.     

Carbon coating of Ti-6Al-4V for reduced wear in combined impact and sliding applications

A range of carbon coatings with different hardness and modulus was compared for wear and frictional behaviours using one-side-carbon-coated Ti-6Al-4V alloy couples tested under conditions of combined impact and sliding contact. Carbon films with hardness over 10 GPa were found to cause far greater volume loss of the uncoated counterpart, and the volume loss was approximately proportional to the extent of hardness deviation above 10 GPa. The coefficient of friction was shown to correlate positively with coating hardness. The tendency of a softer coating to possess a greater sp² or graphite-like content provides more effective solid lubrication in a wet environment, hence minimising both wear and friction. The corresponding low film modulus also provides an optimal structural integrity of the composite system by minimising the elastic modulus mismatch between the film and the underlying substrate.     

Toward Stretchable Self‐Powered Sensors Based on the Thermoelectric Response of PEDOT:PSS/Polyurethane Blends

The development of new flexible and stretchable sensors addresses the demands of upcoming application fields like internet‐of‐things, soft robotics, and health/structure monitoring. However, finding a reliable and robust power source to operate these devices, particularly in off‐the‐grid, maintenance‐free applications, still poses a great challenge. The exploitation of ubiquitous temperature gradients, as the source of energy, can become a practical solution, since the recent discovery of the outstanding thermoelectric properties of a conductive polymer, poly(3,4‐ethylenedioxythiophene)‐poly(styrenesulfonate) (PEDOT:PSS). Unfortunately the use of PEDOT:PSS is currently constrained by its brittleness and limited processability. Herein, PEDOT:PSS is blended with a commercial elastomeric polyurethane (Lycra), to obtain tough and processable self‐standing films. A remarkable strain‐at‐break of ≈700% is achieved for blends with 90 wt% Lycra, after ethylene glycol treatment, without affecting the Seebeck voltage. For the first time the viability of these novel blends as stretchable self‐powered sensors is demonstrated.