Sewage-effluent phosphorus: a greater risk to river eutrophication than agricultural phosphorus?

Phosphorus (P) concentrations from water quality monitoring at 54 UK river sites across seven major lowland catchment systems are examined in relation to eutrophication risk and to the relative importance of point and diffuse sources. The over-riding evidence indicates that point (effluent) rather than diffuse (agricultural) sources of phosphorus provide the most significant risk for river eutrophication, even in rural areas with high agricultural phosphorus losses. Traditionally, the relative importance of point and diffuse sources has been assessed from annual P flux budgets, which are often dominated by diffuse inputs in storm runoff from intensively managed agricultural land. However, the ecological risk associated with nuisance algal growth in rivers is largely linked to soluble reactive phosphorus (SRP) concentrations during times of ecological sensitivity (spring/summer low-flow periods), when biological activity is at its highest. The relationships between SRP and total phosphorus (TP; total dissolved P+suspended particulate P) concentrations within UK rivers are evaluated in relation to flow and boron (B; a tracer of sewage effluent). SRP is the dominant P fraction (average 67% of TP) in all of the rivers monitored, with higher percentages at low flows. In most of the rivers the highest SRP concentrations occur under low-flow conditions and SRP concentrations are diluted as flows increase, which is indicative of point, rather than diffuse, sources. Strong positive correlations between SRP and B (also TP and B) across all the 54 river monitoring sites also confirm the primary importance of point source controls of phosphorus concentrations in these rivers, particularly during spring and summer low flows, which are times of greatest eutrophication risk. Particulate phosphorus (PP) may form a significant proportion of the phosphorus load to rivers, particularly during winter storm events, but this is of questionable relevance for river eutrophication. Although some of the agriculturally derived PP is retained as sediment on the river bed, in most cases this bed sediment showed potential for removal of SRP from the overlying river water during spring and summer low flows. Thus, bed sediments may well be helping to reduce SRP concentrations within the river at times of eutrophication risk. These findings have important implications for targeting environmental management controls for phosphorus more efficiently, in relation to the European Union Water Framework Directive requirements to maintain/improve the ecological quality of impacted lowland rivers. For the UK rivers examined here, our results demonstrate that an important starting point for reducing phosphorus concentrations to the levels approaching those required for ecological improvement, is to obtain better control over point source inputs, particularly small point sources discharging to ecologically sensitive rural/agricultural tributaries.     

Nitrate concentrations in river waters of the upper Thames and its tributaries

The spatial and temporal patterns of in-stream nitrate concentrations for the upper Thames and selected tributaries are described in relation to point and diffuse sources for these rural catchments. The rivers associated with catchments dominated by permeable (Cretaceous Chalk) bedrock show a smaller range in nitrate concentrations than those associated with clay and mixed sedimentary bedrock of lower permeability. The differences reflect the contrasting nature of water storage within the catchments and the influence of point and diffuse sources of nitrate. Nitrate concentrations often increase in a gradual way as a function of flow for the rivers draining the permeable catchments, although there is usually a minor dip in nitrate concentrations at low to intermediate flow due to (1) within-river uptake of nitrate during the spring and the summer when biological activity is particularly high and (2) a seasonal fall in the water table and a change in preferential flow-pathway in the Chalk. There is also a decrease in the average nitrate concentration downstream for the Kennet where average concentrations decrease from around 35 to 25 mg NO(3) l(-1). For the lower permeability catchments, when point source inputs are not of major significance, nitrate concentrations in the rivers increase strongly with increasing flow and level off and in some cases then decline at higher flows. When point source inputs are important, the initial increase in nitrate concentrations do not always occur and there can even be an initial dilution, since the dilution of point sources of nitrate will be lowest under low-flow conditions. For the only two tributaries of the Thames which we have monitored for over 5 years (the Pang and the Kennet), nitrate concentrations have increased over time. For the main stem of the Thames, which was also monitored for over 5 years, there is no clear increase over time. As the Pang and the Kennet river water is mainly supplied from the Chalk, the increasing nitrate concentrations over time clearly reflect increasing nitrate concentrations within the groundwater. It primarily reflects long-term trends for agricultural fertilizer inputs and significant aquifer storage and long water residence times. The results are discussed in terms of hydrogeochemical processes and the Water Framework Directive and are compared with data from other eastern UK rivers. The importance of diffuse sources of nitrate contamination is highlighted. On a flow weighted basis, the average diffuse component of nitrate is around 95% for the Thames Basin rivers draining Chalk and for the corresponding rivers draining less permeable strata, there is a more significant but not major point source component (at least in terms of flux); the average diffuse component is 79% in this case. These data fit well with earlier assessments of agricultural sources to UK surface waters. Under baseflow conditions the diffuse sources remain dominant for the Chalk fed Thames Basin rivers, but point sources can be dominant for the low permeability cases. On a proportionate basis, the Thames Basin rivers are similar to the rural rivers of the Tweed and Humber Basins in terms of percentage diffuse components although the lower intensity agriculture occurring for the rivers monitored means that the average nitrate concentrations are lower for the rural rivers of central and northern England and the borders with Scotland: the Humber and Tweed.     

River water quality of the River Cherwell: an agricultural clay-dominated catchment in the upper Thames Basin, southeastern England

The water quality of the River Cherwell and a tributary of it, the Ray, are described in terms of point and diffuse sources of pollution, for this rural area of the upper Thames Basin. Point sources of pollution dominate at the critical ecological low flow periods of high biological activity. Although the surface geology is predominantly clay, base flow is partly supplied from springs in underlying carbonate-bearing strata, which influences the water quality particularly with regards to calcium and alkalinity. The hydrogeochemistry of the river is outlined and the overall importance of urban point sources even in what would normally be considered to be rural catchments is stressed in relation to the European Unions Water Framework Directive. Issues of phosphorus stripping at sewage treatment works are also considered: such stripping on the Cherwell has reduced phosphorus concentrations by about a factor of two, but this is insufficient for the needs of the Water Framework Directive.     

A theory and model of conflict detection in air traffic control: Incorporating environmental constraints.

A performance theory for conflict detection in air traffic control is presented that specifies how controllers adapt decisions to compensate for environmental constraints. This theory is then used as a framework for a model that can fit controller intervention decisions. The performance theory proposes that controllers apply safety margins to ensure separation between aircraft. These safety margins are formed through experience and reflect the biasing of decisions to favor safety over accuracy, as well as expectations regarding uncertainty in aircraft trajectory. In 2 experiments, controllers indicated whether they would intervene to ensure separation between pairs of aircraft. The model closely predicted the probability of controller intervention across the geometry of problems and as a function of controller experience. When controller safety margins were manipulated via task instructions, the parameters of the model changed in the predicted direction. The strength of the model over existing and alternative models is that it better captures the uncertainty and decision biases involved in the process of conflict detection. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

An empirical analysis of farm vehicle crash injury severities on Iowa's public road system

Farm vehicle crashes are a major safety concern for farmers as well as all other users of the public road system in agricultural states. Using data on farm vehicle crashes that occurred on Iowa's public roads between 2004 and 2006, we estimate a multinomial logit model to identify crash-, farm vehicle-, and driver-specific factors that determine farm vehicle crash injury severity outcomes. Estimation findings indicate that there are crash patterns (rear-end manner of collision; single-vehicle crash; farm vehicle crossed the centerline or median) and conditions (obstructed vision and crash in rural area; dry road, dark lighting, speed limit 55 mph or higher, and harvesting season), as well as farm vehicle and driver-contributing characteristics (old farm vehicle, young farm vehicle driver), where targeted intervention can help reduce the severity of crash outcomes. Determining these contributing factors and their effect is the first step to identifying countermeasures and safety strategies in a bid to improve transportation safety for all users on the public road system in Iowa as well as other agricultural states.     

Automatic restart control system for electrochemical machining

This paper describes the development of a microprocessor-based automatic restart control system (arcs) capable of eliminating flaws caused by restarts during the electrochemical machining (ecm) process. This makes ecm a viable cost-effective technique for producing precision parts previously handled by conventional methods.     

Financial strain, economic values, and somatic symptoms in later life.

Evaluated whether the impact of financial strain on psychological distress depends on the value that older adults place on economic success. Feelings of personal control were specified as an intervening variable in this process. The data came from a nationwide survey of 819 people in Canada who were 55 yrs of age and older. The findings reveal that financial problems are associated with diminished feelings of control and that these effects are stronger when elderly people value economic achievement highly. In addition, financial strain and diminished feelings of control are related to increased distress regardless of how highly economic success is valued. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Studies of fear as an acquirable drive: I. Fear as motivation and fear-reduction as reinforcement in the learning of new responses.

(This reprinted article originally appeared in the Journal of Experimental Psychology, 1948, Vol 38, 89–201. The following abstract of the original article appeared in PA, Vol 22:2945.) Albino rats were trained to go from a white compartment through an open door into a black compartment in order to escape from electric shock. To demonstrate that an acquired drive (fear of anxiety) had been established, the animals were taught a new habit without further shocks. The door (previously always open) was closed. The only way that the door could be opened was by rotating a little wheel, which was above the door, a fraction of a turn. Under these conditions, the animals exhibited trial-and-error behavior and gradually learned to escape from the white compartment by rotating the wheel. If conditions were changed so that only pressing a bar would open the door, wheel turning extinguished, and a 2nd new habit (bar pressing) was learned. Control experiments demonstrated that the learning of the new habits was dependent on having received moderately strong electric shocks during the 1st stages of training. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Maximal and minimal solutions,effectiveness factors for chemical reaction in porous catalysts

A chemical reaction in a porous catalyst particle is considered. It is shown that in both the isothermal and non-isothermal cases, with either Dirichlet or third kind boundary conditions, two sequences of functions can be obtained, one of which converges to the maximal solution and the other to the minimal solution. Corresponding to these two sequences of functions, two sequences of numbers, which converge to the maximal and the minimal effectiveness factors, can be obtained. It is shown that in the isothermal case, the maximal (minimal) solution has the minimal (maximal) effectiveness factor while in the non-isothermal case, the maximal (minimal) temperature solution has the maximal (minimal) effectiveness factor. Two numerical examples are given to illustrate the results.     

Frustules to fragments, diatoms to dust: how degradation of microfossil shape and microstructures can teach us how ice sheets work

In a laboratory experiment we investigated micro- and nanoscale changes in fossil diatom valves and in the texture of diatomaceous sediments that result from ice sheet overburden and subglacial shearing. Our experiment included compression and shearing of Antarctic diatom-rich sediments in a ring shear device and comparison of experimental samples with natural glacial sediments from the Antarctic continental shelf. The purpose of the experiment is to establish objective criteria for analyzing subglacial processes and interpreting the origin of glacial-geologic features on the Antarctic continental shelf. We find distinct changes resulting from different glacial settings, with respect to whole diatom frustules, diatom micromorphology, and microtextural properties of sedimentary units. By providing constraints on subglacial shearing, these observations of genetically controlled micro- and nanoscale diatom structures and architecture are contributing to the understanding of large-scale glacial processes, aiding the development of models of modern ice sheet processes, and guiding interpretation of past ice sheet configurations.