Broadband coupling into a single-mode,electroactive integrated optical waveguide for spectroelectrochemical analysis of surface-confined redox couples

A single-mode, electroactive waveguiding platform capable of measuring spectroelectrochemical responses of surface-adsorbed redox-active molecules over a broad spectral bandwidth has been created. This new planar waveguide spectrometer is a combination of the previously developed electroactive integrated optical waveguide (EA-IOW; Dunphy, D. R.; Mendes, S. B.; Saavedra, S. S.; Armstrong, N. R. Anal. Chem. 1997, 69, 3086-3094) with a recently reported simplified approach to broadband coupling (Bradshaw, J. T.; Mendes, S. B.; Saavedra, S. S. Anal. Chem. 2002, 74, 1751-1759). With the use of a commercially available prism as an incoupling element, the EA-IOW can now guide visible light from at least 500 to 700 nm, improving upon its previously demonstrated monochromatic nature. Coupling profiles of various laser lines along with transmission spectra of narrow band-pass filters at various potentials are used to demonstrate the optical characteristics of this broadband EA-IOW and to compare its response to that of a conventional transmission instrument. Assessment of spectral resolution, performed by measuring the fwhm of various laser lines, ranges from 0.6 to 0.8. To demonstrate the capabilities of this technology, we show the acquisition of absorbance spectra of two different adsorbates, cytochrome c and ferrocenedicarboxylic acid, as a function of applied potential. Subtleties in the redox chemistries of adsorbed molecules, which were difficult to monitor with a monochromatic waveguide, are readily apparent when using the broadband coupling scheme.     

Use of continuous water quality records for hydrograph separation and to assess short-term variability and extremes in acidity and dissolved carbon dioxide for the River Dee, Scotland

A combination of continuous (15-min) pH, conductivity and temperature measurements and fortnightly spot-sampled water quality data were used to examine temporal variability and extremes in river water quality in an upland Scottish river: the River Dee at Mar Lodge. An empirical relationship was established for Gran-alkalinity by multiple regression against flow and conductivity for the fortnightly data. Applying this relationship to the continuous data, an estimate of continuous Gran-alkalinity was calculated. The continuous Gran-alkalinity record was used as (1) a conservative tracer in a simple two-component mixing model to determine the relative proportions of near-surface runoff and deeper groundwater contributing to stream flow; (2) to deconvolute the contribution of weathering and sea-salt contributions to stream conductivity; and (3) to calculate the excess partial pressure of carbon dioxide in stream water. The episodic variations in pH, weathering and sea-salt conductivity and excess partial pressures of carbon dioxide (EpCO2) associated with high flow events in the River Dee suggest that hydrological pathways play an important role in determining stream chemistry. The results of the hydrograph separation indicate that groundwater provides an important contribution to stream flow, and that there are large and hydrologically active stores of groundwater within the upper River Dee catchment. Sea-salts have an important influence on stream conductivity, particularly with the onset of storm runoff following summer drought periods. This suggests that sea-salts are concentrated in the upper soil horizons by dry deposition and/or evapotranspiration. EpCO2 behaves non-conservatively and shows marked diurnal variability under low-flow conditions during summer, inducing diurnal pH variations, and indicating the importance of within-river biological processes. This study emphasises the very intermittent nature of water quality extremes with stream spates and the diurnal nature of biologically-induced responses. Fortnightly sampling programmes do not capture the range of high flow extremes, and with sampling undertaken during the working day, biological extremes occurring at night are also missed, introducing bias. This study shows the value of continuous measurements for infilling aspects of these intermittent extremes. However, it is also noted that the relatively simple patterns of response observed from the continuous measurements may well belie a much more varied response at the sub-catchment and hillslope scales, as local chemical and hydrological heterogeneities do occur. Thus, the two-component mixing model used is, in practice, based on catchment integrated values for a range of soil water and groundwater endmembers.     

Biomechanical performance of cutting edge surgical needles

The purpose of this study was to compare the biomechanical performance of cutting edge needles made of S45500 stainless steel alloy to Surgalloy stainless steel. The new high-nickel stainless steel alloy, Surgalloy, has superior performance characteristics over that of the other high-nickel stainless steel alloy, S45500. The Surgalloy needle is produced from a stronger stainless steel alloy than the S45500 needle. The Surgalloy needle has considerably greater resistance to bending than the needle produced from S45500 alloy. In addition, Surgalloy stainless steel has almost a twofold greater resistance to fracture than the S45500 stainless steel alloy.     

Counterfactual thinking.

Counterfactuals are mental representations of alternatives to the past and produce consequences that are both beneficial and aversive to the individual. These apparently contradictory effects are integrated into a functionalist model of counterfactual thinking. The author reviews research in support of the assertions that (a) counterfactual thinking is activated automatically in response to negative affect, (b) the content of counterfactuals targets particularly likely causes of misfortune, (c) counterfactuals produce negative affective consequences through a contrast-effect mechanism and positive inferential consequences through a causal-inference mechanism, and (d) the net effect of counterfactual thinking is beneficial. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Utilization of prior flaw information in ultrasonic NDE: An analysis of flaw scattering amplitude as a random variable

Probabilistic approaches to flaw detection, classification, or characterization often assume prior knowledge of the flaw distribution. It is implicit that there is a scattering amplitude distribution associated with the flaw distribution. In a number of previously published probabilistic analyses, it has been assumed that scattering amplitude is an uncorrelated, Gaussian random variable with zero mean and known variance. In the work reported here, these assumptions are evaluated for the case of a lognormal distribution of spherical flaws. The correlation, mean, variance, and nature of the scattering amplitude distribution are considered as a function of frequency and as a function of the breadth of the assumed flaw distribution. It is shown for the assumed flaw distributions that scattering amplitude is not uncorrelated and does not have zero mean. It is shown that errors in estimating the flaw distribution variance affect both the scattering amplitude mean and variance. Using both analytical and numerical procedures, the scattering amplitude distribution is shown to be lognormal at long wavelength for a lognormal distribution of spherical scatterers. At high frequency, the distribution is shown to have a bimodal character.     

Analytical studies of drive and reward.

An attempt was made to analyze some of the fundamental mechanisms involved in drive and reward. Topics covered are: the effect of drive on reward and learning, brain electrolytes and thirst, and a new conception of the brain. "The brain is an active organ which exerts considerable control over its own sensory input. The brain is a device for sorting, processing, and analyzing information. The brain contains sense organs which respond to states of the internal environment, such as osmotic pressure, temperature, and many others. The brain is a gland which secretes chemical messengers, and it also responds to such messengers as well as to various types of feedback, both central and peripheral." (21 fig., 36 ref.) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Some problems concerning the non-adiabatic tubular reactor a-priori bounds,qualitative behavior,preliminary uniqueness and stability considerations

An investigation of the non-adiabatic tubular reactor, in which a single chemical reaction occurs, is presented. The steady state mass and heat balance equations are shown to be a pair of coupled, nonlinear differential equations, and are shown to uncouple into a single functional-differential equation for the case Le = 1. A-priori bounds on the steady state concentration and temperature are developed, and some remarks about the shape of the steady state profiles made. Sufficient conditions ensuring uniqueness of steady states and their asymptotic stability are derived.