Mechanical anisotropy and grain interaction in recrystallized aluminum

Axial compression tests up to 50 pct deformation were performed on rolled and fully recrystallized aluminum sheet stock (AA5754, AA5182, and AA6016) in the direction perpendicular to the sheet. Textures were measured using both X-rays and orientation imaging microscopy (OIM). In all three cases, a systematic in-plane anisotropy was observed, with more strain taking place in the transverse than in the rolling direction. Previous attempts to simulate this in-plane anisotropy for AA5754, starting from the X-ray initial textures and using a one-site polycrystal model, resulted in predictions of more deformation along the rolling than along the transverse direction. An analysis of the OIM textures indicates that there is a nonrandom spatial correlation of the recrystallization and retained rolling components. As a consequence, we implemented grain interaction and co-rotation in a viscoplastic self-consistent (VPSC) polycrystal model, in order to be able to account for orientation correlations. Such an approach allows us to describe the large- and small-angle misorientation distributions, as a function of deformation and to compare them with the available experimental evidence. Concerning the in-plane anisotropy, we conclude that it is very sensitive to details in the texture representation, rather than on grain interactions. Grain-interaction and co-rotation effects, however, have the effect of inducing less severe deformation textures, which is in better agreement with the experimental evidence.     

Development of Ni–Fe–Al-based alloys precipitating cubic γ′ for fabrication of nanoporous membranes

During this study, new Ni-base alloys precipitating cubic γ′ were developed which shall be used for the production of polycrystalline nanoporous membranes. The polycrystalline nanoporous membranes are produced through a combination of cold rolling and heat treatment in order to get directional coarsening of the γ′-phase which is selectively dissolved afterwards. Conventional Ni-based superalloys have a γ/γ′ -microstructure with cubic γ′-precipitates and show the needed etching behaviour but their high strength and limited ductility at room temperature do not allow to produce the polycrystalline nanoporous membranes by means of the before mentioned method. Thus, the new alloys with simpler composition were developed which have a γ/γ′ microstructure. The alloy Ni–13Fe–8Al–4Ti (composition in atomic percent) which was produced by Schmitz (Cullivier, ISBN 978-3-86955-523-2, 16) served as basis and showed the promising characteristics. To obtain cubic γ′-precipitates, the misfit was estimated to values of at least |0.2| % by a method presented by Mishima (Acta Metall 33:1161–1169, 23). Further, the phase compositions as well as phase volume fractions of γ-matrix and γ′-phase were calculated by means of Thermocalc^® simulations (database: TTNi7). The etching behaviour of the new alloys was adjusted by adding chromium and molybdenum which passivate the γ-matrix so that the γ′-precipitates dissolve during the leaching process. The well-aligned cubic γ′-precipitates were obtained by partially replacing titanium by niobium. Furthermore, the hardness could be significantly lowered compared to conventional superalloys by reduction of alloying elements. Hence, the promising alloys were found to get directional coarsening of the γ′-precipitates in a combined process of cold rolling and heat treatment.