Ag-Ni复合材料界面的第一性原理研究

采用第一性原理方法分析了Ag(110)、(211)与Ni(110)、(211)的界面结合情况。通过对界面结合能、电荷布居以及界面处的电子结构等研究分析发现,在Ag与Ni界面的结合形式中,以Ag(110)/Ni(211)的界面结合能最高,界面处的电子杂化最为剧烈,其界面结合也是最稳定的     

ZDC-Ⅰ组合仪的改进及其在水平井中的应用

文章针对实际生产中，ZDC—I型多参数组合仪与Sondex的新型拖拉器及地面配接方面表现出的诸多问题，提出了可行性的解决方法，模拟实验效果良好。塔里木油田现场的水平井测井数据表明，该方法在水平井中取得了良好应用效果。     

30.4 nm Si/C多层膜反射镜的制备与测量

采用离子束溅射镀膜装置制备了一种新的材料组合Si/C多层膜 ,用于 30 4nm波段的正入射多层膜反射镜。并用软X射线反射率计测得其反射比最大值为 0 14。有效地抑制了 15 0nm处的二级衍射峰。     

用核糖体工程技术二次开发海洋微生物菌株资源的研究

经对无活性的海洋来源放线菌B3054进行链霉素抗性筛选,获得了一株具有抗肿瘤活性的链霉素抗性突变株SY-1.从该突变株的发酵物中分离得到了4个活性化合物,其中1个为新天然产物.对该菌株突变前后的rpsL基因(编码核糖体蛋白S12)进行分析未发现发生突变,提示突变位点可能在核糖体的另外亚基上.实验结果表明,核糖体工程技术可用于无活性菌株资源的二次开发利用.     

基于JMS异步消息的心跳监听设计与实现

阐述了如何利用Java消息服务和心跳技术实现对分散模块状态的监控，以及保证模块间通信无阻。通过收发消息的形式，集中监控关键模块，并准确定位故障所在，尽可能保证系统长时间的无故障运作。     

Biological analysis of woodpecker’s brain after impact experiments

Woodpeckers can withstand a fierce impact during pecking. Previous studies have focused on the biomechanical analysis of the pecking process, the properties of the beak and hyoid bone of woodpecker; however, the biological characteristics of the woodpecker brain are also important in resisting impact injuries. We employed impact experiments and biological analysis in normal and injured brains to reveal the impact-resistant biological characteristics of woodpecker brains, as well as the impact energy's biological effects on the woodpecker brain. The hoopoe, which has a similar size but only a slight pecking behavior, was selected as the control group to compare brain morphology and neuronal cells differences in normal brains between woodpecker and hoopoe by sectioning and staining. A loading device was designed to conduct a quantifiable impact energy to the woodpeckers' head. Four groups of woodpeckers were impacted with the same energy on the forehead, beak, tempus and occiput,respectively. Biological changes in the injured brains were evaluated by Nissl staining and enzyme-linked immunosorbent assay.The results showed that:(1) woodpeckers had a larger cerebellum and a higher density of Nissl bodies than hoopoe;(2) Nissl apoptosis appeared in the brain samples after the forehead and the occiput impact experiments, but no obvious Nissl body apoptosis was observed after impact on the tempus and the beak;(3) β-amyloid protein accumulated in the normal status woodpecker brain. This study reveals that: woodpecker brain morphology is well-adapted to impact, woodpecker heads display location-dependent protective performance, with beak and tempus regions having a better protective performance than the forehead and occiput, Nissl apoptosis appears in injured woodpecker brains, and that the accumulation of β-amyloid protein does not show a direct relationship with the injury state of woodpecker's brain tissue in our study.     

基于LPC2478的网络型电能质量监测装置人机交互功能研发

基于网络型电能质量监测装置的硬件结构和功能,给出了在RealViewMDK开发环境下向LPC2478微处理器移植μC/OS-Ⅱ嵌入式实时操作系统的过程,阐述了集成μC/GUI图形接口的实现步骤。给出了LPC2478微处理器针对液晶屏AT056TN52的驱动程序及利用GPIO中断实现键盘功能的方法。根据所提出的人机交互界面设计思路以及优先级的合理分配完成了具体程序的编写,最终实现了界面友好、功能强大的人机交互功能。     

Organosoluble semi-alicyclic polyimides derived from 3,4-dicarboxy-1,2,3,4-tetrahydro-6-tert-butyl-1-naphthalene succinic dianhydride and aromatic diamines: Synthesis,characterization and thermal degradation investigation

Semi-alicyclic polyimides (PI-1–PI-4) have been prepared from a newly-developed alicyclic dianhydride, 3,4-dicarboxy-1,2,3,4-tetrahydro-6-tert-butyl-1-naphthalene succinic dianhydride (TTDA) and various aromatic diamines. The asymmetrical alicyclic tetralin structure in TTDA endowed the derived PI resins good solubility in various organic solvents. They were soluble not only in polar aprotic solvents but also in solvents with low boiling points including dichloromethane and tetrahydrofuran. Flexible and tough PI films were successfully cast from their N-methyl-2-pyrrolidone (NMP) solution except PI-1 derived from TTDA and 4,4′-oxydianiline (ODA). The PI films exhibited good optical transparency in the ultraviolet and visible light region with optical transmittances around 80% at a wavelength of 400 nm. The PI films showed good thermal stability up to 400 °C in nitrogen, after that they thermally decomposed rapidly. The thermal degradation behaviors of the PIs were investigated by means of thermogravimetric analysis-mass spectrometry (TG-MS), thermogravimetric analysis-Fourier transform infrared spectrometry (TG-FTIR) and the real time FTIR spectra (RT-FTIR) analysis techniques. The results revealed that the decomposition of PI-1 (as a representative) took place mainly in the range of 450–550 °C. The major degradative fragments at 500 °C were clearly identified as the tert-butyl-substituted tetralin moiety and its dealkylation products. Therefore, it can be deduced that for the TTDA-PIs, the single bond bridge attached the maleic anhydride and tetralin anhydride units in TTDA moiety might break first during the heating; thus producing the tetralin fragments.     

Synthesis and properties of a novel hyperbranched polyphosphoramidate using an A2 + CB2 approach

The synthesis of hyperbranched polyphosphoramidate (HPPAE) has been successfully achieved via a facial A₂ + CB₂ approach. First, an AB₂ type intermediate is generated by the reaction between the phosphorus chloride group of ethyldichlorophosphate and the secondary amine group of diethanolamine. Second, the above intermediate can further self‐condense to produce the hyperbranched polymer. The molecular weight and the structural characterization of HPPAE were checked by gel permeation chromatography and Fourier transform infrared and NMR (¹³C and ³¹P) spectroscopy. The degradation study of HPPAE indicated that phosphate and phosphoramide bonds between the branch points are responsible for its complete hydrolysis in an aqueous phosphate buffer (pH 7.4) after 6 days. In addition, HPPAE presents a strong fluorescence peak at 450 nm, exhibiting the potential to track drug transport and distribution in real time. © 2012 Society of Chemical Industry     

精脱硫工序积碳与结焦的对策

介绍了甲醇生产中焦炉煤气精脱硫系统积碳与结焦的危害以及应对方法。通过设备改造及工艺调整等措施,减少各种杂质进入精脱硫系统,使加氢催化剂保持良好效果,实现设备长周期运行。