Preparation of monodisperse polystyrene particles using thiol-ended polyethylene oxide stabilizer in dispersion polymerization

Summary Radical dispersion polymerization of styrene in aqueous ethanol solutions was performed in the presence of a new reactive polyethylene oxide stabilizer with thiol end groups. This reactive stabilizer was compared to the more conventional poly (N-vinylpyrrolidone). Particles size distribution, molecular weights and kinetics were investigated. We demonstrate that the thiol ended dispersant displays a high stabilizing efficiency. Particles size, molecular weights and conversions are strongly influenced by the amount of stabilizer used.     

Universal portfolios with side information

We present a sequential investment algorithm, the μ-weighted universal portfolio with side information, which achieves, to first order in the exponent, the same wealth as the best side-information dependent investment strategy (the best state-constant rebalanced portfolio) determined in hindsight from observed market and side-information outcomes. This is an individual sequence result which shows the difference between the exponential growth wealth of the best state-constant rebalanced portfolio and the universal portfolio with side information is uniformly less than (d/(2n))log (n+1)+(k/n)log 2 for every stock market and side-information sequence and for all time n. Here d=k(m-1) is the number of degrees of freedom in the state-constant rebalanced portfolio with k states of side information and m stocks. The proof of this result establishes a close connection between universal investment and universal data compression     

Laser ablation of diamond fibres and a diamond fibre metal matrix composite

Continuous chemical vapour-deposited diamond-coated fibres with tungsten wire or SiC fibre cores are attractive for reinforcing metals and ceramics. The fibres have been embedded in Ti-6A1-4V alloy to produce a diamond fibre-reinforced composite. Both the fibres and the composite material are extremely difficult to cut without damage by conventional mechanical methods. The use of a Nd-YAG laser to cut these materials is described.     

Models for the elastic deformation of honeycombs

A theoretical model has been developed for predicting the elastic constants of honeycombs based on the deformation of the honeycomb cells by flexure, stretching and hinging. This is an extension of earlier work based on flexure alone. The model has been used to derive expressions for the tensile moduli, shear moduli and Poisson's ratios. Examples are given of structures with a negative Poisson's ratio. It is shown how the properties can be tailored by varying the relative magnitudes of the force constants for the different deformation mechanisms. Off-axis elastic constants are also calculated and it is shown how the moduli and Poisson's ratios vary with applied loading direction. Depending on the geometry of the honeycomb the properties may be isotropie (for regular hexagons) or extremely anisotropic. Again, the degree of anisotropy is also affected by the relative magnitude of the force constants for the three deformation mechanisms.     

Extending typestate checking using conditional liveness analysis

The authors present a practical extension to typestate checking, which is capable of proving programs free of uninitialized variable errors even when these programs contain conditionally initialized variables where the initialization of a variable depends upon the equality of one or more tag variables to a constant. The user need not predeclare the relationship between a conditionally initialized variable and its tags, and this relationship may change from one point in the program to another. The technique generalizes liveness analysis to conditional liveness analysis. Like typestate checking, this technique incorporates a dataflow analysis algorithm in which each point in a program is labeled with a lattice point describing statically tracked information, including the initialization of variables. The labeling is then used to check for programming errors such as referencing a variable which may be uninitialized     

Continuous stimulated emission at T=293 K from separate-confinement heterostructure diode lasers with one layer of InAs quantum dots grown on vicinal GaAs(bd001) surfaces misoriented in the [010] direction in the active region

The electroluminescence and stimulated emission of lasers with one layer of InAs quantum dots (QD’s) grown in a single molecular-beam epitaxial process on vicinal GaAs(001) surfaces misoriented in the direction [010] by 2, 4 and 6° are investigated. It is discovered that an increase in the misorientation angle leads to a blue shift and a decrease in the full width at half maximum (FWHM) of the electroluminescence spectrum. This effect is attributed to a decrease in the size of the quantum dots and improvement in their size uniformity. A strong dependence of the threshold current density on the width of the spontaneous luminescence spectrum is discovered. The room-temperature threshold current density of the lasers with one layer of quantum dots and the spontaneous luminescence spectrum having the smallest FWHM (54 meV) equals 210 A/cm². Fiz. Tekh. Poluprovodn. 32, 1482–1486 (December 1998)     

On solving constrained optimization problems with neural networks:a penalty method approach

Deals with the use of neural networks to solve linear and nonlinear programming problems. The dynamics of these networks are analyzed. In particular, the dynamics of the canonical nonlinear programming circuit are analyzed. The circuit is shown to be a gradient system that seeks to minimize an unconstrained energy function that can be viewed as a penalty method approximation of the original problem. Next, the implementations that correspond to the dynamical canonical nonlinear programming circuit are examined. It is shown that the energy function that the system seeks to minimize is different than that of the canonical circuit, due to the saturation limits of op-amps in the circuit. It is also noted that this difference can cause the circuit to converge to a different state than the dynamical canonical circuit. To remedy this problem, a new circuit implementation is proposed.